Registration Dossier
Registration Dossier
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EC number: 233-514-0 | CAS number: 10210-68-1
Auto flammability
Administrative data
- Endpoint:
- relative self-ignition temperature (solids)
- Type of information:
- experimental study
- Adequacy of study:
- key study
- Reliability:
- 2 (reliable with restrictions)
- Rationale for reliability incl. deficiencies:
- test procedure in accordance with national standard methods with acceptable restrictions
- Remarks:
- no GLP
Data source
Reference
- Reference Type:
- study report
- Title:
- Unnamed
- Year:
- 2 016
- Report date:
- 2016
Materials and methods
Test guideline
- Qualifier:
- according to guideline
- Guideline:
- other: VDI 2263, Sheet 1
- Deviations:
- no
- GLP compliance:
- no
Test material
- Reference substance name:
- Octacarbonyldicobalt
- EC Number:
- 233-514-0
- EC Name:
- Octacarbonyldicobalt
- Cas Number:
- 10210-68-1
- Molecular formula:
- C8O8Co2
- IUPAC Name:
- 1,1,1,3,3,3-hexakis(oxidaniumylidynemethyl)-2,4-dioxo-1,3-dicobaltabicyclo[1.1.0]butane-1,1,3,3-tetrakis(ylium)
- Test material form:
- solid: particulate/powder
- Remarks:
- crystalline powder
Constituent 1
Results and discussion
Relative self-ignition temperature (solids)
- Key result
- Relative self-ignition temperature:
- < 25 °C
Applicant's summary and conclusion
- Conclusions:
- The study was performed according to VDI 2263, Sheet 1 without deviations and therefore reliability of Klimisch 2 has been assigned. The self-ignition temperature has been determined at < 25°C
- Executive summary:
The relative self-ignition temperature was determined according to VDI 2263, Sheet 1 (Dust fires and dust explosions; hazards, assessment, protective measures; test methods for the determination of the safety characteristic of dusts) using a Grewer oven.
Self-ignition did occur at a temperature of <25°C and led to a max. temperature of 147°C for the test substance.
Similarly, a mulistep self-ignition has been detected for the mixture of test substance and kieselguhr (1:1) at <25°C, which led to a max. temperature of 260°C for the test mixture.
This temperature is the basis for the determination of the temperature for safe handling (100°C substracted from result: -75°C) under normal atmospheric conditions.
The substance has to be regarded as self-heating and handling at ambient temperature should only be done under the absence of air.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
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