Morpholine, 4-[(triethoxysilyl)methyl]-

Guidance on Safe Use

First-aid measures

Description of first aid measures
General information:
In case of accident or if you feel unwell seek medical advice (show label or SDS where possible).
After contact with the eyes:
Rinse immediately with plenty of water. Seek medical advice in case of continuous irritation.
After contact with the skin:
Wash with plenty of water or water and soap. In the event of a visible skin change or other complaints, seek medical advice (show
label or SDS where possible).
After inhalation:
Provide fresh air.
After swallowing:
Give several small portions of water to drink. Do not induce vomiting.
Most important symptoms and effects, both acute and delayed
Any relevant information can be found in other parts of this section.
Indication of any immediate medical attention and special treatment needed
Further toxicology information must be observed.

Fire-fighting measures

Extinguishing media
Suitable extinguishing media:
water mist , extinguishing powder , alcohol-resistant foam , carbon dioxide , sand .
Extinguishing media which must not be used for safety reasons:
water spray , water jet .
Special hazards arising from the substance or mixture
Hazardous combustion products: nitrous gases .
Advice for firefighters
Special protective equipment for fire fighting:
Use respiratory protection independent of recirculated air.

Accidental release measures

Personal precautions, protective equipment and emergency procedures
Wear personal protection equipment. Keep unprotected persons away. Avoid contact with eyes and skin. Avoid
inhaling mists and vapours. If material is released indicate risk of slipping.

Environmental precautions
Prevent material from entering surface waters, drains or sewers and soil. Contain any fluid that runs out using suitable material
(e.g. earth). Retain contaminated water/extinguishing water. Dispose of in prescribed marked containers.

Methods and material for containment and cleaning up
Do not flush away with water. For small amounts: Absorb with a liquid binding material such as diatomaceous earth and dispose
of according to local/state/federal regulations. Contain larger amounts and pump up into suitable containers. Clean any slippery
coating that remains using a detergent / soap solution or another biodegradable cleaner. Exhaust vapours.
Further information:
Eliminate all sources of ignition.

Reference to other sections
Relevant information in other sections has to be considered. This applies in particular for information given on personal protective
equipment and on disposal.

Handling and storage

Precautions for safe handling:
Ensure adequate ventilation. Keep away from incompatible substances. Spilled substance
increases risk of slipping.
Precautions against fire and explosion:
Flammable vapors may accumulate and form explosive mixtures with air in containers, process vessels, including partial, empty
and uncleaned containers and vessels, or other enclosed spaces. Keep away from sources of ignition and do not smoke. Take
precautionary measures against electrostatic charging. Cool endangered containers with water.
Conditions for safe storage, including any incompatibilities
Conditions for storage rooms and vessels:
Make sure there is no possibility of entering the ground.
Advice for storage of incompatible materials:
not applicable
Further information for storage:
Protect against moisture. Keep container tightly closed and store in a cool, well ventilated place.
Specific end use(s)
No data available.

Transport information

Land transport (UN RTDG/ADR/RID)

Shipping

Special provisions / remarks

Remarks:

no dangerous good

Untersuchungsbericht zu N-(Morpholinomethyl)triethoxysilane. Da die Zersetzungswärme mit 34 J/g weit unter dem Grenzwert für selbstzersetzliche Stoffe der Klasse 4.1 (300 J/g) liegt, verbleibt die Einstufung bei "kein Gefahrgut"

Shipping

Remarks

Marine transport (UN RTDG/IMDG)

Shipping

Special provisions / remarks

Remarks:

no dangerous good

Air transport (UN RTDG/ICAO/IATA)

Shipping

Special provisions / remarks

Remarks:

no dangerous good

Transport: Transport in tightly sealed, unbreakable containers only.
Secure them against falling and protect them against
moisture.

SpecialProvisions

Exposure controls / personal protection

Control parameters
-
Exposure controls
Exposure in the work place limited and controlled
General protection and hygiene measures:
Avoid contact with eyes and skin. Do not inhale gases/vapours/aerosols. Do not eat, drink or smoke when handling.
Personal protection equipment:
Respiratory protection
If inhalative exposure above the occupational exposure limit cannot be excluded, adequate respiratory protection equipment must
be used. Suitable respiratory equipment: Respirator with a full face mask, according to acknowledged standards such as EN 136.
Recommended Filter type: Gas filter type ABEK (certain inorganic, organic and acidic gases and vapors; ammonia/amines),
according to acknowledged standards such as EN 14387
In case of mist, spray or aerosol exposure wear suitable personal respiratory protection and protective suit. Suitable respiratory
equipment: Respirator with a full face mask, according to acknowledged standards such as EN 136.
Recommended Filter type: Combined filter type ABEK-P2 (certain inorganic, organic and acidic gases and vapors;
ammonia/amines; particles), according to acknowledged standards such as EN 14387

Observe the equipment manufacturer's information and wear time limits for respirators.
Eye protection
tight fitting protective goggles . Provide work station with eye bathing equipment.
Hand protection
Use of protective gloves is recommended when handling the material, according to recognized standards such as EN374.
Recommended glove types: Protective gloves made of nitrile rubber
thickness of the material: > 0,1 mm
Breakthrough time: > 480 min
Recommended glove types: Protective gloves made of butyl rubber
thickness of the material: > 0,3 mm
Breakthrough time: > 480 min
Please observe the instructions regarding permeability and breakthrough time which are provided by the supplier of the gloves.
Also take into consideration the specific local conditions under which the product is used, such as the danger of cuts, abrasion,
and the contact time. Note that, due to the numerous external influences (such as temperature), a chemically resistant protective
glove in daily use may have a service life that is considerably shorter than the measured break through time.
Skin protection
protective clothing .
Exposure to the environment limited and controlled
Prevent material from entering surface waters and soil.
Further information for system design and engineering measures
Protect from oxygen admission (air). Use only in closed systems with protective gas.

Stability and reactivity

Reactivity; Chemical stability; Possibility of hazardous reactions
If stored and handled in accordance with standard industrial practices no hazardous reactions are known.
Relevant information can possibly be found in other parts of this section.
Conditions to avoid
Moisture. Protect from air.
Incompatible materials
Reacts with: water and acids . The reaction takes place with the formation of ethanol and heat. There is also a lowering of the
flash point.
Hazardous decomposition products
If stored and handled properly: none known. Ethanol under the effect of humidity, water and protic agents.

Disposal considerations

Waste treatment methods
13.1.1 Material
Recommendation:
Dispose of according to regulations by incineration in a special waste incinerator. Observe local/state/federal regulations.
Uncleaned packaging
Recommendation:
Completely discharge containers (no tear drops, no powder rest, scraped carefully). Containers may be recycled or re-used.
Observe local/state/federal regulations.