Tetraamminepalladium(2+) dinitrate

Guidance on Safe Use

First-aid measures

EYE CONTACT

Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention.

INHALATION

Remove victim to fresh air and keep at rest in a position comfortable for breathing. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention if adverse health effects persist or are severe. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as collar, tie, belt or waistband. In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours.

SKIN CONTACT

Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Continue to rinse for at least 10 minutes. Get medical attention. In the event of any complaints or symptoms, avoid further exposure. Clean shoes thoroughly before reuse.

INGESTION

Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention if adverse health effects persist or are severe. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain open airway. Loosen tight clothing such as a collar, tie, belt or waistband.

PROTECTION OF FIRST-AIDERS

No action shall be taken involving any personal risk or without suitable training. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves.

POTENTIAL ACUTE HEALTH EFFECTS

- Eye contact: causes serious eye irritation

- Inhalation: Exposure to decomposition products may cause a health hazard. Serious effects may be delayed following exposure.

- Skin contact: Causes skin irritation. May cause an allergic skin reaction.

- Ingestion: Irritating to mouth, throat and stomach.

OVER-EXPRESSION SIGNS/SYMPTOMS

- Eye contact: Adverse symptoms may include pain or irritation, watering and redness

- Inhalation: No specific data

- Skin contact: Adverse symptoms may include irritation and redness.

- Ingestion: No specific data.

Fire-fighting measures

EXTINGUISHING MEDIA

Suitable extinguishing media: Use an extinguishing agent suitable for the surrounding fire

Unsuitable extinguishing media: None known

SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE

Hazards from the substance or mixture: Oxidising material. Risk of explosion if heated under confinement. May intensify fire. In a fire or if heated, a pressure increase will occur and the container may burst. This material is toxic to aquatic life with long lasting effects. Fire water contaminated with this material must be contained and prevented from being discharged to any waterway, sewer or drain.

Hazardous thermal decomposition products: Decomposition products may include nitrogen oxides and metal oxide/oxides.

ADVICE FOR FIREFIGHTERS

Special protective actions for fire-fighters: Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. First move people out of line-of-sight of the scene and away from windows. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. Fight fire from protected location or maximum possible distance. Do not fight fire when it reaches the material. Withdraw from fire and let it burn.

Special protective equipment for fire-fighters: Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Clothing from fire-fighters (including helmets, protective boots and gloves) conforming to European standard EN 469 will provide a basic level of protection for chemical incidents. Fire-fighters’ protective clothing will only provide limited protection.

The residue, ash or char left after a fire may have catalytic properties and may promote the re-ignition of flammable materials and vapours.

Accidental release measures

PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES

For non-emergency personnel: No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel form entering. Do not touch or walk through split material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapour or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment.

For emergency responders: If specialised clothing is required to deal with spillage, take note of any suitable and unsuitable materials.

ENVIRONMENTAL PRECAUTIONS

Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Water polluting material. May be harmful to the environment if released in large quantities. Collect spillage.

METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP

Small spill: Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble. Do not absorb in sawdust or other combustible material. It may lead to a fire risk when it dries out. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor.

Large spill: Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach the release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Do not absorb in sawdust or other combustible material. It may lead to a fire risk when it dries out. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations. Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilt product.

Handling and storage

PRECAUTIONS FOR SAFE HANDLING

Protective measures: Put on appropriate personal protective equipment. Persons with a history of skin sensitisation problems should not be employed in any process in which this product is used. Do not get in eyes or on skin or clothing. Do not ingest. Avoid breathing vapour or mist. Avoid release to the environment. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Keep away from clothing, incompatible materials and combustible materials. Keep away from heat. Empty containers retain product residue and can be hazardous. Do not reuse container.

Advice on general occupational hygiene: Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas.

CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES

Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials and food and drink. Keep away from heat. Separate from reducing agents and combustible materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabelled containers. Use appropriate containment to avoid environmental contamination.

Transport information

Land transport (UN RTDG/ADR/RID)

UN number:

UN 3139

Shipping information

Proper shipping name and description:

OXIDIZING LIQUID, N.O.S. (tetraamminepalladium (2+) dinitrate, solution)

Chemical name:

tetraamminepalladium (2+) dinitrate, solution

Language:

English

Special provisions / remarks

Special provisions:

274

Remarks:

The environmentally hazardous substance mark is not required when transported in sizes of ≤ 5L or ≤ 5kg.
Limited quantity: 1L
Tunnel code: (E)

Inland waterway transport (UN RTDG/ADN(R))

UN number:

UN 3139

Shipping

Special provisions / remarks

Remarks:

The environmentally hazardous substance mark is not required when transported in sizes of ≤ 5L or ≤ 5kg.

Marine transport (UN RTDG/IMDG)

UN number:

UN 3139

Shipping information

Proper shipping name and description:

OXIDIZING LIQUID, N.O.S. (tetraamminepalladium(2+) dinitrate, solution)

Chemical name:

tetraamminepalladium(2+) dinitrate, solution

Marine pollutant

Special provisions / remarks

Remarks:

This marine pollutant mark is not required when transported in sizes of ≤ 5L or ≤ 5kg.
Special provisions: 274.

Air transport (UN RTDG/ICAO/IATA)

UN number:

UN 3139

Shipping information

Proper shipping name and description:

Oxidizing liquid, n.o.s. (tetraamminepalladium (2+) dinitrate, solution)

Chemical name:

tetraamminepalladium (2+) dinitrate, solution

Special provisions / remarks

Remarks:

This environmentally hazardous substance mark may appear if required by other transportation regulations.
Passenger and cargo aircraft: Quantity limitation: 1L; Packaging instructions: 550.
Cargo aircraft only: Quantity limitation: 5L; Packaging instructions: 554.
Limited Quantities - passenger aircraft: Quantity limitation: 0.5L; Packaging instructions: Y540.

Special provisions: A3

SpecialProvisions

Exposure controls / personal protection

RECOMMENDED MONITORING PROCEDURES

If this product contains ingredients with exposure limits, personal, workplace atmosphere or biological monitoring may be required to determine the effectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective equipment. Reference should be made to monitoring standards, such as the following: European Standard EN 689 (Workplace atmospheres - Guidance for the assessment of exposure by inhalation to chemical agents for comparison with limit values and measurement strategy) European Standard EN 14042 (Workplace atmospheres - Guide for the application and use of procedures for the assessment of exposure to chemical and biological agents) European Standard EN 482 (Workplace atmospheres - General requirements for the performance of procedures for the measurement of chemical agents). Reference to national guidance documents for methods for the determination of hazardous substances will also be required.

DNELS/DMELS: No DNELs/DMELs available.

PNECs: No PNECs available.

EXPOSURE CONTROLS

Appropriate engineering controls: Good general ventilation should be sufficient to control worker exposure to airborne contaminants.

HYGIENE MEASURES

Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Contaminated work clothing should not be allowed out of the workplace. Ensure that eyewash stations and safety showers are close to the workstation location.

EYE/FACE PROTECTION

Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protections: chemical splash goggles.

HAND PROTECTION

Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated.

BODY PROTECTION

Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.

OTHER SKIN PROTECTION

Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.

RESPIRATORY PROTECTION

Use a properly fitted, air-purifying or air-feed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazard of the product and safe working limits of he selected respirator.

ENVIRONMENTAL EXPOSURE CONTROLS

Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers’ filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.

Stability and reactivity

REACTIVITY

No specific test data related to reactivity available for this product or its ingredients.

CHEMICAL STABILITY

The catalytic properties of this material may give it a low ignition temperature (except when supplied as a paste). The catalytic properties will also promote the oxidation and possible ignition of flammable liquids and vapours. A used, filtered catalyse should, therefore, be kept wet and out of contact with combustible vapours and liquids. The material is supplied in a stable condition and other than the previously mentioned catalytic hazards of this material, no specific reactive hazards are known.

POSSIBILITY OF HAZARDOUS REACTIONS

Hazardous reactions or instability may occur under certain conditions of storage or use. Conditions may include contact with combustible materials, heating under confinement. Reactions may include risk of explosion.

CONDITIONS TO AVOID

Drying on clothing or other combustible materials may cause fire

INCOMPATIBLE MATERIALS

Reactive or incompatible materials include combustible materials and reducing materials.

Disposal considerations

PRODUCT

Methods of disposal: The generation of waste should be avoided or minimised wherever possible. Avoid dispersal of split material and runoff and contact with soil, waterways, drains and sewers. Empty containers or liners may retain some product residues. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Return accumulated waste material to the refinery for metal recovery, or dispose of in accordance with local and national regulations.

Hazardous waste: The classification of the product may meet the criteria for a hazardous waste.

PACKAGING

Methods of disposal: The generation of waste should be avoided or minimised wherever possible. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible.

Special precautions: This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Avoid dispersal of split material and runoff and contact with soil, waterways, drains and sewers.