Registration Dossier

Administrative data

First-aid measures

INHALATION
Move the exposed person to fresh air at once. Get medical attention.

INGESTION
Wash out mouth with water, provided person is conscious. Get medical attention.


SKIN CONTACT
Remove contaminated clothing and wash skin with soap and plenty of running water. Get medical attention.

EYE CONTACT
Rinse immediately eye with plenty of low pressure water for at least 15 minutes.
Remove any contact lenses. Get medical attention.

Fire-fighting measures

EXTINGUISHING MEDIA
Flashpoint > 200 °C
To extinguish fire use water spray, dry powder, carbon dioxide, or foam.

SPECIAL FIRE FIGHTING PROCEDURES
Prevent run-off water from entering the sewer system.

UNUSUAL FIRE & EXPLOSION HAZARDS
Dust may form explosive mixture with air.

SPECIFIC HAZARDS
By fire toxic gases may be formed (Cox, NOx).

PROTECTIVE MEASURES IN FIRE
Self contained breathing apparatus and full protective clothing.

Accidental release measures

PERSONAL PRECAUTIONS
See section on exposure controls / personal protection

ENVIRONMENTAL PRECAUTIONS
Take precautionary measures against discharges into the environment.

SPILL CLEAN UP METHODS
Collect spilled material without creating dust, then place into a suitable closed container for disposal as chemical waste.

Handling and storage

USAGE PRECAUTIONS
Concentrated dust may present an explosion hazard.
Avoid contact with eyes or skin.
Wash thoroughly after handling and before eating, drinking or smoking.

STORAGE PRECAUTIONS
To protect product quality, store in sealed container in a cool place and out of direct sunlight.
Protect against static charge and keep away from source of ignition. Prevent dust formation.

Transport information

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Marine transport (IMDG)

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Exposure controls / personal protection

EXPOSURE LIMITS
None listed.



USE LIMITS
Only to be handled in an industrial or professional environment as powder coating additive (as such or in a mixture).

PNECs:
aqua-freshwater: 0.009 mg/L
aqua-marine water: 0.0009 mg/L
aqua-intermittent: 0.09 mg/L
sewage treatment plant: 14 mg/L
sediment-freshwater: 0.0214 mg/kg dw
sediment-marine water: 0.00214 mg/kg dw
soil: 10 mg/kg dw

DNELs:
The main derived long-term DNELs for systemic effects are:
Workers General population
Oral not relevant 0.272 mg/kg bw/day
Dermal 0.544 mg/kg bw/day 0.272 mg/kg bw/day
Inhalation 1.92 mg/m3/day 0.473 mg/m3/day

EXPOSURE TO INDUSTRIAL WORKERS:
The Chesar version 2.3.0 exposure model shows for this substance for indoor industrial activities taking more than 4 hours/day, with local exhaust
ventilation (LEV) present (and running), provided workers wear masks with at least 90% respiratory protection and gloves with at least 90% dermal
protection, the following exposures:

Inhalation dermal RCR RCR RCR
mg/m3 mg/kg/day inhalation dermal total
PROC5 0.035 0.137 0.018 0.252 0.270
Mixing or blending in batch processes (multistage and/or significant contact)
PROC7 0.070 0.214 0.036 0.394 0.430
Industrial spraying
PROC8a 0.035 0.137 0.018 0.252 0.270
Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at non-dedicated facilities
PROC8b 0.003 0.069 0.002 0.126 0.128
Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at dedicated facilities
PROC9 0.035 0.069 0.018 0.126 0.144
Transfer of substance or preparation into small containers (dedicated filling line, including weighing)
PROC15 0.003 0.003 0.002 0.006 0.008
Use as laboratory reagent

Notes:
• Dustiness was set at “medium”
• Good general ventilation is assumed in all cases (3-5 air exchanges per hour)
• LEV is considered for both inhalation and dermal exposures and its efficiencies are as follows:
o For PROC5, PROC8a, PROC9 and PROC15 LEV reduces both inhalation and dermal exposure with 90%
o For PROC7 and PROC8b LEV reduces both inhalation and dermal exposure with 95%

EXPOSURE TO PROFESSIONAL WORKERS:
The Chesar version 2.3.0 exposure model shows for this substance for indoor professional activities taking more than 4 hours/day, with local exhaust ventilation (LEV) present (and running), provided workers wear masks with at least 90% respiratory protection and gloves with at least 90% dermal protection, the following exposures:

Inhalation dermal RCR RCR RCR
mg/m3 mg/kg/day inhalation dermal total
PROC11 0.056 0.429 0.029 0.788 0.817
Non industrial spraying
Notes:
• Dustiness was set at “medium”
• Good general ventilation is assumed in all cases (3-5 air exchanges per hour)
• LEV is considered for both inhalation and dermal exposures and its efficiencies are as follows:
o For PROC11 LEV reduces both inhalation and dermal exposure with 80%
• The concentration of PPI in the mixture must stay below 5%

EXPOSURE TO MAN VIA THE ENVIRONMENT:
The same CHESAR tool predicts the following for the relevant ERCs (ERC2 at a level of 475 kg/day; ERC5 at a level of 18 kg/day; ERC8c at 500 t/y; ERC10a at 1000 t/y) with fraction of tonnage to region = 1:
Total daily intake man via the environment regional RCR < 0.01
ERC2 = Formulation
ERC 5: Industrial use resulting in inclusion into or onto a matrix
ERC 8c: Wide dispersive indoor use resulting in inclusion into or onto a matrix
ERC 10a: Wide dispersive outdoor use of long-life articles and materials with low release (covers also ERC11a which is indoor)

PROTECTIVE EQUIPMENT
Protective gloves, safety goggles, breathing apparatus and protective clothing. Avoid any source of ignition and/or static charge.

RESPIRATORY EQUIPMENT
Breathing apparatus: Wear positive pressure self-contained breathing apparatus classified under EN 137:2006 with at least 90% respiratory
protection and give operators basic training. Cartridges must be discarded after each working day.

HAND PROTECTION
Protective gloves: Wear appropriate protective gloves to prevent skin exposure. Use chemically resistant gloves classified under EN 374, class 6
(breakthrough time > 480 minutes). Give operators basic training. An advanced occupational health and safety management system must be in use.
Discard gloves after one working day or when they have come into direct contact with the substance.

SPECIFIC FOR A PROFESSIONAL ENVIRONMENT
The concentration of the substance in the mixture must stay below 5%.

EYE PROTECTION
Wear approved safety goggles.

HYGIENE MEASURES
Wash at the end of each work shift and before eating, drinking, smoking or using the toilet.

SKIN PROTECTION
Wear protective clothing.

Stability and reactivity

STABILITY
Stable under normal temperature conditions and recommended use.

MATERIALS TO AVOID
Strong oxidising agents

HAZARDOUS DECOMPOSITION PRODUCTS
By fire toxic gases (COx, NOx) may be formed

Disposal considerations

GENERAL INFORMATION
Place into a suitable closed container for disposal as chemical waste.


DISPOSAL METHODS
Dispose of in accordance with local and national regulations.