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Diss Factsheets

Physical & Chemical properties

Flash point

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Administrative data

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Reference
Endpoint:
flash point of flammable liquids
Type of information:
experimental study
Adequacy of study:
key study
Study period:
Study period December 16, 2015
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Qualifier:
according to guideline
Guideline:
EU Method A.9 (Flash-Point)
Deviations:
no
Qualifier:
according to guideline
Guideline:
ISO 3679 (Determination of flash point - Rapid equilibrium closed cup method)
Deviations:
no
GLP compliance:
no
Other quality assurance:
other: ISO 9001
Type of method:
closed cup
Flash point apparatus:
Setaflash apparatus
Specific details on test material used for the study:
Trade name: Trigonox BPIC-C75
Chemical name: tert-butylperoxy isopropyl carbonate
IUPAC name: 2-[(isopropoxycarbonyl)peroxy]-2-methylpropane
EC number: 219-143-7
CAS number: 2372-21-6
Batch number: 1203442069
Description: colourless clear liquid with a faint odour
Storage temperature: Avoid temperatures below -20 °C. For maximum quality store below: 25 °C; based on REACH test substance information.
Expiration date: April 1, 2022
Key result
Flash point:
49 °C
Atm. press.:
102 kPa

Calibration

- observed flash point : 63°C

- barometric pressure : 102.0 kPa

- corrected flash point : 63°C

The measured value of 63°C for undecane is within the acceptance limits.

The estimated accuracy of the manometer is ± 0.1 kPa.

Flash point of test substance

- observed flash point : 49°C

- barometric pressure : 102.0 kPa

- corrected flash point : 49°C

This means that the flash point of the test substance is 49°C

Interpretation of results:
Category 3 (flammable liquids) based on GHS criteria
Conclusions:
The flash point of O,O-tert-butyl isopropyl monoperoxycarbonate, CAS 2372-21-6, 75% in isododecane was determined according to EC Regulation No 440/2008, Guideline A.9, and according to ISO 3679 and in accordance with European Chemicals Agency (ECHA), Guidance on information requirements and chemical safety assessment, Chapter R.7a, Endpoint specific guidance, May 2008.

The flash point of the tested Trigonox BPIC-C75 is 49°C, consistent with the reported flash point of the isododecane (45 oC)
Executive summary:

The flash point of the tested Trigonox BPIC-C75 is 49°C, consistent with the reported flash point of the isododecane (45 oC).

Description of key information

The flash point of the tested Trigonox BPIC-C75 is 49°C, consistent with the flash point of isododecane (45 oC).

Key value for chemical safety assessment

Flash point at 101 325 Pa:
49 °C

Additional information