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Physical & Chemical properties

Boiling point

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Reference
Endpoint:
boiling point
Type of information:
experimental study
Adequacy of study:
key study
Study period:
July 7th, 2016.
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Qualifier:
according to guideline
Guideline:
OECD Guideline 103 (Boiling Point)
Deviations:
no
Qualifier:
according to guideline
Guideline:
EU Method A.2 (Boiling Temperature)
Deviations:
no
GLP compliance:
yes (incl. QA statement)
Type of method:
method according to Siwoloboff
Key result
Atm. press.:
1 011 hPa
Decomposition:
yes
Decomp. temp.:
277.6 °C

In the course of the study, the decomposition of the test item had been observed (sample darkening about 277.6 ± 0.3 °C) after the melting point was reached. All samples were decomposed below the boiling point. At temperature about 290 °C the colour of test item in capillary was dark brown.

Table 1. The observed values of decomposition of the test item.

Sample The boiling point value, °C Atmospheric pressure, hPa
1 277.9 1011
2 277.6
3 277.3
Average value ± standard deviation, °C 277.6 ± 0.3 -



Conclusions:
The decomposition of the test item was observed at temperature of 277.6 ± 0.3 ºC, below the boiling point (at 1011 hPa).
Executive summary:

The determination of the boiling point of the test item was carried out according to EU method A.2 (method according to Siwoloboff) / OECD 103 (GLP study). The decomposition of the test item was observed at a temperature of 277.6 ± 0.3 °C, below the boiling point.

Description of key information

Key study. Method according to OECD 103 / EU method A.2, GLP study. The test item decomposes at 277.6 ± 0.3 °C (at 1011 hPa).

Key value for chemical safety assessment

Additional information

Key study. The determination of the boiling point of the test item was carried out according to EU method A.2 (method according to Siwoloboff) / OECD 103 (GLP study). The decomposition of the test item was observed at a temperature of 277.6 ± 0.3 °C, below the boiling point (at 1011 hPa).