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Physical & Chemical properties

Vapour pressure

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Endpoint:
vapour pressure
Type of information:
experimental study
Adequacy of study:
key study
Study period:
29 Nov 2001 - 4 Jan 2002
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Qualifier:
according to guideline
Guideline:
OECD Guideline 104 (Vapour Pressure Curve)
Qualifier:
according to guideline
Guideline:
EPA OPPTS 830.7950 (Vapor Pressure)
GLP compliance:
yes
Type of method:
spinning rotor
Specific details on test material used for the study:
- Source and lot/batch No.of test material: L-7038 Lot 2
- Purity: 97.3%
- Expiration date of the lot/batch: 17 Jan 2007
- Storage condition of test material: Ambient room temperature
Key result
Test no.:
#1
Temp.:
20 °C
Vapour pressure:
< 0 Pa

Table 1, Vapor Pressures Determined for PFBSK+ and Reference Compounds

Sample Mean Background Vapor Pressure (Pa) Mean Vapor Pressure (Pa) Literature Value (Pa) Range (Pa)³
Hexachlorobenzene 1.17E-05 1.40E-03 ¹2.6E-03
²
1.1E-03
1.6E-03 - 5.7E-04
4.1E-03 - 1.5E-03
DDT 9.61E-06 2.56E-05 2.5E-05 2.0E-05 - 3.0E-05
PFBSK+ 1.22E-05 <1.22E-05 N/A N/A

¹Literature value and range for hexachlorobenzene using the gas saturation method

² Literature value and range for hexachlorobenzene using the vapor pressure balance method

³Range defined as literature value ± 20 percent

Conclusions:
The vapor pressure of PFBSK+ was < 1.22E-05 Pa at 20°C ± 1°C determined by the spinning rotor gauge method (OECD Guideline 104 Vapor Pressure Curve and EPA OPPTS 830.7950 Vapor Pressure).
Executive summary:

The vapor pressure of PFBSK+ was examined in a spinning rotor gauge test conducted according to OECD Guideline 104 (Vapor Pressure Curve) and EPA OPPTS 830.7950 (Vapor Pressure). At 20°C ± 1°C the vapor pressure was <1.22E-05 Pascals.

The test was conducted according to internationally accepted test guidelines and was GLP compliant. It is reliable without restriction and suitable for Risk Assessment, Classification and Labeling.

Endpoint:
vapour pressure
Type of information:
experimental study
Adequacy of study:
supporting study
Study period:
22 Nov - 10 Dec 2002
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Qualifier:
according to guideline
Guideline:
other: Vapor Pressure Balance (EC-Guideline 92/69/EWGA4)
Deviations:
no
GLP compliance:
yes
Type of method:
effusion method: vapour pressure balance
Specific details on test material used for the study:
SOURCE OF TEST MATERIAL
- Batch No.of test material: K100
- Sample no./year: 1069024/2002
- Purity: 98.7%
- Expiration date of the lot/batch: August 12, 2004
Key result
Test no.:
#1
Temp.:
20 °C
Vapour pressure:
< 0 hPa
Remarks on result:
other: < LOD of the instrument
Test no.:
#2
Temp.:
25 °C
Vapour pressure:
< 0 hPa
Remarks on result:
other: < LOD of the instrument
Test no.:
#3
Temp.:
50 °C
Vapour pressure:
< 0 hPa
Remarks on result:
other: < LOD of the instrument

At temperatures up to 105°C the vapor pressure is lower than the minimum dection limit of the apparatus (1.0E-05 hPa).

Conclusions:
The vapor pressure of PFBSK+ was < 1.0E-05 hPa at 20°C, 25°C and 50°C (Vapor Pressure Balance; EC-Guideline 92/69/EWGA4).
Executive summary:

The vapor pressure of PFBSK+ was examined in a vapor pressure balance test conducted according to EC-Guideline 92/69/EWGA4. The report noted that at temperatures up to 105°C, the vapor pressure was < 1.0E-05 hPa, the minimum detection limit of the measuring apparatus. Reported results were at 20°C, 25°C and 50°C the vapor pressure was < 1.0E-05 hPa.

The test was conducted according to internationally accepted test guidelines and was GLP compliant. It is reliable without restriction and suitable for Risk Assessment, Classification and Labeling.

Description of key information

The vapor pressure of PFBSK+ was determined to be < 1.22E-05 Pa at 20°C ± 1°C, according to OECD Guideline 104.

Key value for chemical safety assessment

Additional information

The vapor pressure of PFBSK+ was determined to be < 1.22E-05 Pa at 20°C ± 1°C in the key study. The test was conducted according to OECD Guideline 104 and EPA OPPTS 830.7950, using the spinning rotor gauge test, therefore it is considered reliable without restriction. A supporting study conducted according to EC-Guideline 92/69/EWGA4 reported results of < 1.0E-05 hPa at 20°C, 25°C and 50°C and noted that at temperatures up to 105°C, the vapor pressure was < 1.0E-05 hPa, the minimum detection limit of the measuring apparatus. This study was conducted according to internationally accepted test guidelines and is considered reliable without restriction.