Registration Dossier
Registration Dossier
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EC number: 457-680-0 | CAS number: -
Guidance on Safe Use
Guidance on Safe Use
Administrative data
First-aid measures
General information:
Take persons to a safe place. Observe self-protection for first aid.
After inhalation
Keep the patient calm. If unconscious place in stable sideways position. Protect against loss
of body heat. In cases of sickness seek medical advice (show label or SDS if possible).
After contact with the skin
Remove contaminated or soaked clothing. Immediately rinse with plenty of soap and water. In the
event of a visible skin change or other complaints, seek medical advice (show label or SDS
where possible).
After contact with the eyes
Rinse immediately with plenty of water for 10-15 minutes. Seek medical advice in case of
continuous irritation.
After swallowing
If conscious, give several small portions of water to drink. Do not induce vomiting. Seek
medical advice immediately and clearly identify substance.
Advice for the physician
In case of contact with water material splits off (also in gastrointestinal tract) methanol in
larger amounts; therefore consider poisoning on methanol and also observe known period of
latency of several days!
Take persons to a safe place. Observe self-protection for first aid.
After inhalation
Keep the patient calm. If unconscious place in stable sideways position. Protect against loss
of body heat. In cases of sickness seek medical advice (show label or SDS if possible).
After contact with the skin
Remove contaminated or soaked clothing. Immediately rinse with plenty of soap and water. In the
event of a visible skin change or other complaints, seek medical advice (show label or SDS
where possible).
After contact with the eyes
Rinse immediately with plenty of water for 10-15 minutes. Seek medical advice in case of
continuous irritation.
After swallowing
If conscious, give several small portions of water to drink. Do not induce vomiting. Seek
medical advice immediately and clearly identify substance.
Advice for the physician
In case of contact with water material splits off (also in gastrointestinal tract) methanol in
larger amounts; therefore consider poisoning on methanol and also observe known period of
latency of several days!
Fire-fighting measures
Suitable extinguishing media
water mist , extinguishing powder , alcohol-resistant foam , carbon dioxide , sand .
Extinguishing media which must not be used for safety reasons
water spray , water jet .
Special exposure hazards arising from the substance or preparation itself, combustion products,
resulting gases
Hazardous combustion products: nitrous gases .
Special protective equipment for fire fighting
Use respiratory protection independent of recirculated air.
water mist , extinguishing powder , alcohol-resistant foam , carbon dioxide , sand .
Extinguishing media which must not be used for safety reasons
water spray , water jet .
Special exposure hazards arising from the substance or preparation itself, combustion products,
resulting gases
Hazardous combustion products: nitrous gases .
Special protective equipment for fire fighting
Use respiratory protection independent of recirculated air.
Accidental release measures
Personal precautions
Wear personal protection equipment (see section 8). Keep unprotected persons away. Avoid
contact with eyes and skin. Avoid inhaling mists and vapours. If material is released indicate
risk of slipping.
Environmental precautions
Prevent material from entering surface waters, drains or sewers and soil. Contain any fluid
that runs out using suitable material (e.g. earth). Retain contaminated water/extinguishing
water. Dispose of in prescribed marked containers.
Methods for cleaning up
Do not flush away with water. For small amounts: Absorb with a liquid binding material such as
diatomaceous earth and dispose of according to local/state/federal regulations. Contain larger
amounts and pump up into suitable containers. Clean any slippery coating that remains using a
detergent / soap solution or another biodegradable cleaner. Exhaust vapours.
Further information:
Eliminate all sources of ignition.
Wear personal protection equipment (see section 8). Keep unprotected persons away. Avoid
contact with eyes and skin. Avoid inhaling mists and vapours. If material is released indicate
risk of slipping.
Environmental precautions
Prevent material from entering surface waters, drains or sewers and soil. Contain any fluid
that runs out using suitable material (e.g. earth). Retain contaminated water/extinguishing
water. Dispose of in prescribed marked containers.
Methods for cleaning up
Do not flush away with water. For small amounts: Absorb with a liquid binding material such as
diatomaceous earth and dispose of according to local/state/federal regulations. Contain larger
amounts and pump up into suitable containers. Clean any slippery coating that remains using a
detergent / soap solution or another biodegradable cleaner. Exhaust vapours.
Further information:
Eliminate all sources of ignition.
Handling and storage
General information:
Avoid exposure by technical measures or personal protective equipment.
Handling
Precautions for safe handling:
Avoid formation of aerosols. In case of aerosol formation special protective measures are
required (exhausting by suction, respiratory protection). Ensure adequate ventilation. Keep
away from incompatible substances in accordance with section 10.2. Spilled substance increases
risk of slipping. Avoid remainders of content at/on the container.
Precautions against fire and explosion:
Product can separate methanol. Flammable vapors may accumulate and form explosive mixtures with
air in containers, process vessels, including partial, empty and uncleaned containers and
vessels, or other enclosed spaces. Keep away from sources of ignition and do not smoke. Take
precautionary measures against electrostatic charging. Cool endangered containers with water.
Storage
Conditions for storage rooms and vessels:
Use unbreakable and prescribed labelled containers.
Advice for storage of incompatible materials:
Avoid contact with acids.
Further information for storage:
Protect against moisture. Keep container tightly closed and store in a cool, well ventilated
place. Secure container against falling over. Store in original container only.
Avoid exposure by technical measures or personal protective equipment.
Handling
Precautions for safe handling:
Avoid formation of aerosols. In case of aerosol formation special protective measures are
required (exhausting by suction, respiratory protection). Ensure adequate ventilation. Keep
away from incompatible substances in accordance with section 10.2. Spilled substance increases
risk of slipping. Avoid remainders of content at/on the container.
Precautions against fire and explosion:
Product can separate methanol. Flammable vapors may accumulate and form explosive mixtures with
air in containers, process vessels, including partial, empty and uncleaned containers and
vessels, or other enclosed spaces. Keep away from sources of ignition and do not smoke. Take
precautionary measures against electrostatic charging. Cool endangered containers with water.
Storage
Conditions for storage rooms and vessels:
Use unbreakable and prescribed labelled containers.
Advice for storage of incompatible materials:
Avoid contact with acids.
Further information for storage:
Protect against moisture. Keep container tightly closed and store in a cool, well ventilated
place. Secure container against falling over. Store in original container only.
Transport information
Land transport (UN RTDG/ADR/RID)
- UN number:
- 3082
Shipping information
- Proper shipping name and description:
- Umweltgefährdender Stoff, flüssig, n.a.g.
- Chemical name:
- Dimethoxy(methyl)[phenylamino(methyl)]silan
- Language:
- German
- Labels:
- 9; Miscellaneous dangerous substances and articles
SpecialProvisionsopen allclose all
Inland waterway transport (UN RTDG/ADN(R))
- UN number:
- 3082
Shipping information
- Proper shipping name and description:
- Umweltgefährdender Stoff, flüssig, n.a.g.
- Chemical name:
- Dimethoxy(methyl)[phenylamino(methyl)]silan
- Language:
- German
- Labels:
- 9; Miscellaneous dangerous substances and articles
Remarksopen allclose all
Marine transport (UN RTDG/IMDG)
- UN number:
- 3082
Shipping information
- Proper shipping name and description:
- Environmentally hazardous substance, liquid, n.o.s.
- Chemical name:
- Dimethoxy(methyl)[phenylamino(methyl)]silane
- Labels:
- 9; Miscellaneous dangerous substances and articles
Special provisions / remarks
- Remarks:
- Marine Pollutant: yes
Air transport (UN RTDG/ICAO/IATA)
- UN number:
- 3082
Shipping information
- Proper shipping name and description:
- Environmentally hazardous substance, liquid, n.o.s.
- Chemical name:
- Dimethoxy(methyl)[phenylamino(methyl)]silane
- Labels:
- 9; Miscellaneous dangerous substances and articles
Remarksopen allclose all
SpecialProvisionsopen allclose all
Exposure controls / personal protection
Exposure limits
-
Exposure limited and controlled
Exposure in the work place limited and controlled
General protection and hygiene measures:
Avoid contact with eyes and skin. Do not inhale gases/vapours/aerosols. Do not eat, drink or
smoke when handling.
Personal protection equipment
Respiratory protection
In case of long or strong exposure: gas mask filter ABEK .
Hand protection
Protective gloves made of butyl rubber . Gloves suitable for up to 60 minutes' use.
Eye protection
tight fitting protective goggles . Provide work station with eye bathing equipment.
Skin protection
protective clothing .
Exposure to the environment limited and controlled
Prevent material from entering surface waters, drains or sewers and soil.
Further information for system design and engineering measures
Observe information in section handling and storage.
-
Exposure limited and controlled
Exposure in the work place limited and controlled
General protection and hygiene measures:
Avoid contact with eyes and skin. Do not inhale gases/vapours/aerosols. Do not eat, drink or
smoke when handling.
Personal protection equipment
Respiratory protection
In case of long or strong exposure: gas mask filter ABEK .
Hand protection
Protective gloves made of butyl rubber . Gloves suitable for up to 60 minutes' use.
Eye protection
tight fitting protective goggles . Provide work station with eye bathing equipment.
Skin protection
protective clothing .
Exposure to the environment limited and controlled
Prevent material from entering surface waters, drains or sewers and soil.
Further information for system design and engineering measures
Observe information in section handling and storage.
Stability and reactivity
General information:
If stored and handled in accordance with standard industrial practices no hazardous reactions
are known.
Conditions to avoid
moisture
Materials to avoid
Reacts with: water , basic substances and acids . Reaction causes the formation of: methanol .
Hazardous decomposition products
methylaniline . Under the effect of humidity, water and protic agents: methanol .
If stored and handled in accordance with standard industrial practices no hazardous reactions
are known.
Conditions to avoid
moisture
Materials to avoid
Reacts with: water , basic substances and acids . Reaction causes the formation of: methanol .
Hazardous decomposition products
methylaniline . Under the effect of humidity, water and protic agents: methanol .
Disposal considerations
Material
Recommendation:
Dispose of according to regulations by incineration in a special waste incinerator. Observe
local/state/federal regulations.
Uncleaned packaging
Recommendation:
Completely discharge containers (no tear drops, no powder rest, scraped carefully). Containers
may be recycled or re-used. Observe local/state/federal regulations.
Recommendation:
Dispose of according to regulations by incineration in a special waste incinerator. Observe
local/state/federal regulations.
Uncleaned packaging
Recommendation:
Completely discharge containers (no tear drops, no powder rest, scraped carefully). Containers
may be recycled or re-used. Observe local/state/federal regulations.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
