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EC number: 268-440-8 | CAS number: 68084-49-1
- Life Cycle description
- Uses advised against
- Endpoint summary
- Appearance / physical state / colour
- Melting point / freezing point
- Boiling point
- Density
- Particle size distribution (Granulometry)
- Vapour pressure
- Partition coefficient
- Water solubility
- Solubility in organic solvents / fat solubility
- Surface tension
- Flash point
- Auto flammability
- Flammability
- Explosiveness
- Oxidising properties
- Oxidation reduction potential
- Stability in organic solvents and identity of relevant degradation products
- Storage stability and reactivity towards container material
- Stability: thermal, sunlight, metals
- pH
- Dissociation constant
- Viscosity
- Additional physico-chemical information
- Additional physico-chemical properties of nanomaterials
- Nanomaterial agglomeration / aggregation
- Nanomaterial crystalline phase
- Nanomaterial crystallite and grain size
- Nanomaterial aspect ratio / shape
- Nanomaterial specific surface area
- Nanomaterial Zeta potential
- Nanomaterial surface chemistry
- Nanomaterial dustiness
- Nanomaterial porosity
- Nanomaterial pour density
- Nanomaterial photocatalytic activity
- Nanomaterial radical formation potential
- Nanomaterial catalytic activity
- Endpoint summary
- Stability
- Biodegradation
- Bioaccumulation
- Transport and distribution
- Environmental data
- Additional information on environmental fate and behaviour
- Ecotoxicological Summary
- Aquatic toxicity
- Endpoint summary
- Short-term toxicity to fish
- Long-term toxicity to fish
- Short-term toxicity to aquatic invertebrates
- Long-term toxicity to aquatic invertebrates
- Toxicity to aquatic algae and cyanobacteria
- Toxicity to aquatic plants other than algae
- Toxicity to microorganisms
- Endocrine disrupter testing in aquatic vertebrates – in vivo
- Toxicity to other aquatic organisms
- Sediment toxicity
- Terrestrial toxicity
- Biological effects monitoring
- Biotransformation and kinetics
- Additional ecotoxological information
- Toxicological Summary
- Toxicokinetics, metabolism and distribution
- Acute Toxicity
- Irritation / corrosion
- Sensitisation
- Repeated dose toxicity
- Genetic toxicity
- Carcinogenicity
- Toxicity to reproduction
- Specific investigations
- Exposure related observations in humans
- Toxic effects on livestock and pets
- Additional toxicological data
Endpoint summary
Administrative data
Description of key information
The fate of cerium neodecanoate in the environment is most accurately evaluated by separately assessing the fate of its constituents cerium cations and neodecanoate anions.
Cerium:
Biotic degradation is not relevant for inorganic substances, including metals. Cerium as an element is not considered to be (bio)degradable.
Neodecanoic acid: Neodecanoic acid is not readily biodegradable (11% biodegradation in 28 d) based on results from a standard OECD ready biodegradation test.
Additional information
Read-across
Metal carboxylates are substances consisting of a metal cation and a carboxylic acid anion. In a water solubility test according to OECD TG 105, a solubility of 157 µg/L cerium neodecanoate was determined. Thus, cerium neodecanoate is expected to dissociate in environmental media resulting in cerium and neodecanoate ions. The respective dissociation is reversible, and the ratio of the salt /dissociated ions is dependent on the metal-ligand dissociation constant of the salt, the composition of the solution and its pH. Based on an analysis by Carbonaro et al. (2007) of monodentate binding of cerium to negatively-charged oxygen donor atoms, including carboxylic functional groups, monodentate ligands such as neodecanoate anions are not expected to bind strongly with cerium.
The analysis by Carbonaro & Di Toro (2007) suggests that the following equation models monodentate binding to negatively-charged oxygen donor atoms of carboxylic functional groups:
log KML= αO* log KHL+ βO; where
KML is the metal-ligand formation constant, KHL is the corresponding proton–ligand formation constant, and αO and βO are termed the slope and intercept, respectively. Applying the equation and parameters derived by Carbonaro & Di Toro (2007) and the pKa of neodecanoic acid of 4.69 results in:
log KML= 0.356 * 4.69 + 0.739
log KML= 2.41 (estimated cerium-neodecanoate formation constant).
Thus, it may reasonably be assumed that based on the estimated cerium-neodecanoate formation constant, the respective behaviour of the dissociated cerium cations and neodecanoic acid anions in the environment determine the fate of cerium neodecanoate upon dissolution with regard to (bio)degradation, bioaccumulation, partitioning resulting in a different relative distribution in environmental compartments (water, air, sediment and soil) and subsequently its ecotoxicological potential.
In the assessment of environmental toxicity of cerium neodecanoate, read-across to the assessment entities soluble cerium substances and neodecanoic acid is applied since the ions of cerium neodecanoate determine its ecotoxicologic potential. Since cerium cations and neodecanoate anions behave differently in the environment, including processes such as stability, degradation, transport and distribution, a separate assessment of each assessment entity is performed. Please refer to the data as submitted for each individual assessment entity.
In order to evaluate the environmental fate of the substance cerium neodecanoate, information on the assessment entities cerium cations and neodecanoate anions were considered. For a documentation and justification of that approach, please refer to the separate document attached to section 13, namely Read Across Assessment Report for cerium neodecanoate.
Reference:
Carbonaro RF & Di Toro DM (2007) Linear free energy relationships for metal–ligand complexation: Monodentate binding to negatively-charged oxygen donor atoms. Geochimica et Cosmochimica Acta 71: 3958–3968.
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