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Environmental fate & pathways

Adsorption / desorption

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Description of key information

The adsorption coefficient (KOC) on soil and on sewage sludge using high performance liquid chromatography (HPLC) was estimated according to OECD/OCDE 121 (2001) and Council Regulation (EC) No. 440/2008, Method C.19 for the test item Hostanox O 3 Pills.
The test was performed temperature controlled (20 °C) with a mobile phase of 75 % acetonitrile and 25 % citrate buffer. A 10 mg/L sample of the test itemHostanox O 3 Pillswas analyzed threefold via HPLC on a cyanopropyl (CN-) column with PDA‑detection. Calibration was performed using six reference items for soil and six for sewage sludge with known values of log KOC, each with a nominal concentration of 2 mg/L. Analysis of the reference items were performed once before and after analysis of test item, respectively. Dead time of the HPLC-system was determined threefold using 2 mg/L sodium nitrate.
Under test conditions the retention time of the test item Hostanox O 3 Pills was found to be 3.308 minutes
 
Under test conditions the retention time of the test item Hostanox O 3 Pills was found to be 3.3 ± 0.0004 minutes at pH 5.6–6.1. Based on the corresponding log k’ value for the test item the log Koc values for soil and sewage sludge was:
log KOC, soil :3.951
log KOC, sewage sludge: 3.969

Key value for chemical safety assessment

Koc at 20 °C:
8 940

Additional information

[LogKoc: 3.951]