Registration Dossier
Registration Dossier
Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.
The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.
Use of this information is subject to copyright laws and may require the permission of the owner of the information, as described in the ECHA Legal Notice.
EC number: 263-034-7 | CAS number: 61789-12-6
Vapour pressure
Administrative data
Link to relevant study record(s)
- Endpoint:
- vapour pressure
- Type of information:
- experimental study
- Adequacy of study:
- key study
- Study period:
- 23. Jan. 2018 to 15. Mar. 2018
- Reliability:
- 1 (reliable without restriction)
- Rationale for reliability incl. deficiencies:
- guideline study
- Qualifier:
- according to guideline
- Guideline:
- OECD Guideline 104 (Vapour Pressure Curve)
- Version / remarks:
- OECD Guidelines for the Testing of Chemicals, Method No. 104, adopted 23. Mar. 2006: “Vapour Pressure“
- Deviations:
- no
- Qualifier:
- according to guideline
- Guideline:
- EU Method A.4 (Vapour Pressure)
- Version / remarks:
- Commission Regulation (EC) No 761/2009 of 23. July 2009, published on 24. Aug. 2009 Method A.4: “Vapour Pressure”
- Deviations:
- no
- GLP compliance:
- yes (incl. QA statement)
- Type of method:
- effusion method: Knudsen cell
- Specific details on test material used for the study:
- No further details specified in the study report.
- Key result
- Temp.:
- 20 °C
- Vapour pressure:
- 0.001 Pa
- Key result
- Temp.:
- 25 °C
- Vapour pressure:
- 0.001 Pa
- Conclusions:
- For the test item LUMULSE GMT-K, the following vapour pressures at 20 °C and at 25 °C were calculated from the regression equation:
Vapour pressure at 20 °C: 1.00 * 10-03Pa
Vapour pressure at 25 °C: 1.32 * 10-03Pa - Executive summary:
Determination of the Vapour Pressure of LUMULSE GMT-K according to OECD 104 resp. EU A.4 using the effusion method: Knudsen Cell.
Findings and Results:
The vapour pressure of LUMULSE GMT-K was determined according to OECD 104 resp. EU A.4 using the effusion method (weight loss).
Vapour pressure was examined at nine different temperatures. Eight temperatures could be evaluated as they showed reproducible weight loss. For these temperatures, 1/T was plotted against log (p).
Vapour Pressures (Effusion Method)
Experiment
T
Mean p
Stand. Dev. p
RSD p
No.
K
Pa
Pa
%
1
303.2
2.21E-03
5.76E-04
25.7%
2
318.2
3.55E-03
9.45E-04
26.7%
3
333.2
3.11E-03
1.10E-03
18.0%
4
348.2
1.00E-02
7.16E-04
7.1%
5
363.2
2.01E-02
5.33E-03
26.5%
6
378.2
4.62E-02
2.94E-03
6.4%
7
393.2
6.68E-02
1.47E-02
21.9%
8
408.2
1.09E-01
2.50E-02
23.0%
In this table, E-0X represents multiplication with 10-x.
Stand. Dev. = Standard Deviation; RSD = Relative Standard Deviation
The graph 1/T vs. log (p) shows a straight line with a correlation coefficient of - 0.9923.
For the test item LUMULSE GMT-K, the following vapour pressures at 20 °C and at 25 °C were calculated from the regression equation:
Vapour pressure at 20 °C: 1.00 * 10-03Pa
Vapour pressure at 25 °C: 1.32 * 10-03Pa
Reference
Sample Weights
The mass of sample in the respective cell is presented in the following table:
Sample Weights
Parameter |
Cell empty |
Cell + test item |
Cell + test item + cap |
Test item |
Unit |
g |
g |
g |
g |
Knudsen-cell 1 |
2.57193 |
4.00681 |
4.21808 |
1.43488 |
Knudsen-cell 2 |
2.55960 |
3.96862 |
4.17858 |
1.40902 |
Knudsen-cell 3 |
2.56539 |
3.85480 |
4.06788 |
1.28941 |
Knudsen-cell 4 |
2.57348 |
4.01491 |
4.22539 |
1.44143 |
Measurement Data
The data of the evaluated experiments is presented in the following tables:
Measurement Data Experiment 1
Experiment |
1 |
|
|
|
Nom. Temperature |
30 |
°C |
|
|
Date and time START |
|
23.01.2018 14:34 |
24.01.2018 12:25 |
25.01.2018 12:28 |
Date and time END |
|
24.01.2018 11:25 |
25.01.2018 11:20 |
26.01.2018 11:30* |
Parameter |
Weight m |
Weight m |
Weight m |
Weight m |
Unit |
g |
g |
g |
g |
Knudsen-cell 1 |
4.21808 |
4.21653 |
4.21624 |
4.21570 |
Knudsen-cell 2 |
4.17858 |
4.16378 |
4.16211 |
4.16038 |
Knudsen-cell 3 |
4.06788 |
4.05642 |
4.05583 |
4.05526 |
Knudsen-cell 4 |
4.22539 |
4.21599 |
4.21588 |
4.21486 |
*The samples were stored in a desiccator after the weightings until start of the next measurement series due to organisational reasons.
Measurement Data Experiment 2
Experiment |
2 |
|
|
|
Nom. Temperature |
45 |
°C |
|
|
Date and time START |
|
29.01.2018 11:44 |
30.01.2018 12:10 |
31.01.2018 12:23 |
Date and time END |
|
30.01.2018 11:10 |
31.01.2018 11:30 |
01.02.2018 11:15 |
Parameter |
Weight m |
Weight m |
Weight m |
Weight m |
Unit |
g |
g |
g |
g |
Knudsen-cell 1 |
4.21570 |
4.21479 |
4.21405 |
4.21362 |
Knudsen-cell 2 |
4.16038 |
4.15882 |
4.15755 |
4.15649 |
Knudsen-cell 3 |
4.05526 |
4.05321 |
4.05094 |
4.04981 |
Knudsen-cell 4 |
4.21486 |
4.21339 |
4.21166 |
4.21076 |
Measurement Data Experiment 3
Experiment |
3 |
|
|
|
Nom. Temperature |
60 |
°C |
|
|
Date and time START |
|
01.02.2018 12:10 |
05.02.2018 11:10 |
06.02.2018 12:40 |
Date and time END |
|
02.02.2018 10:00* |
06.02.2018 11:45 |
07.02.2018 11:45* |
Parameter |
Weight m |
Weight m |
Weight m |
Weight m |
Unit |
g |
g |
g |
g |
Knudsen-cell 1 |
4.21362 |
4.21140 |
4.20892 |
4.20675 |
Knudsen-cell 2 |
4.15649 |
4.15422 |
4.15260 |
4.15088 |
Knudsen-cell 3 |
4.04981 |
4.04751 |
4.04610 |
4.04425 |
Knudsen-cell 4 |
4.21076 |
4.20773 |
4.20537 |
4.20297 |
*The samples were stored in a desiccator after the weightings until start of the next measurement series due to organisational reasons.
Measurement Data Experiment 4
Experiment |
4 |
|
|
|
Nom. Temperature |
75 |
°C |
|
|
Date and time START |
|
12.02.2018 10:00 |
13.02.2018 12:35 |
14.02.2018 12:25 |
Date and time END |
|
13.02.2018 11:25 |
14.02.2018 11:50 |
15.02.2018 13:20 |
Parameter |
Weight m |
Weight m |
Weight m |
Weight m |
Unit |
g |
g |
g |
g |
Knudsen-cell 1 |
4.20675 |
4.20162 |
4.19661 |
4.19166 |
Knudsen-cell 2 |
4.15088 |
4.14720 |
4.14447 |
4.14197 |
Knudsen-cell 3 |
4.04425 |
4.04128 |
4.03850 |
4.03580 |
Knudsen-cell 4 |
4.20297 |
4.19843 |
4.19482 |
4.19119 |
Measurement Data Experiment 5
Experiment |
5 |
|
|
|
Nom. Temperature |
90 |
°C |
|
|
Date and time START |
|
15.02.2018 14:20 |
19.02.2018 07:45 |
20.02.2018 07:50 |
Date and time END |
|
16.02.2018 11:20* |
20.20.2018 06:48 |
21.02.2018 07:10 |
Parameter |
Weight m |
Weight m |
Weight m |
Weight m |
Unit |
g |
g |
g |
g |
Knudsen-cell 1 |
4.19166 |
4.18794 |
4.17863 |
4.17240 |
Knudsen-cell 2 |
4.14197 |
4.14110 |
4.13378 |
4.13042 |
Knudsen-cell 3 |
4.03580 |
4.03540 |
4.02904 |
4.02551 |
Knudsen-cell 4 |
4.19119 |
4.18420 |
4.17163 |
4.16179 |
*The samples were stored in a desiccator after the weightings until start of the next measurement series due to organisational reasons.
Measurement Data Experiment 6
Experiment |
6 |
|
|
|
Nom. Temperature |
105 |
°C |
|
|
Date and time START |
|
21.02.2018 08:30 |
22.02.2018 08:10 |
26.02.2018 11:30 |
Date and time END |
|
22.02.2018 06:55 |
23.02.2018 07:00* |
27.02.2018 11:45 |
Parameter |
Weight m |
Weight m |
Weight m |
Weight m |
Unit |
g |
g |
g |
g |
Knudsen-cell 1 |
4.17240 |
4.15580 |
4.14267 |
4.12842 |
Knudsen-cell 2 |
4.13042 |
4.11526 |
4.09652 |
4.07900 |
Knudsen-cell 3 |
4.02551 |
4.01225 |
3.99648 |
3.98030 |
Knudsen-cell 4 |
4.16179 |
4.14318 |
4.13090 |
4.11812 |
*The samples were stored in a desiccator after the weightings until start of the next measurement series due to organisational reasons.
Measurement Data Experiment 7
Experiment |
7 |
|
|
|
Nom. Temperature |
120 |
°C |
|
|
Date and time START |
|
27.02.2018 12:44 |
28.02.2018 12:18 |
01.03.2018 12:22 |
Date and time END |
|
28.02.2018 11:30 |
01.03.2018 11:25 |
02.03.2018 10:30* |
Parameter |
Weight m |
Weight m |
Weight m |
Weight m |
Unit |
g |
g |
g |
g |
Knudsen-cell 1 |
4.12842 |
4.10113 |
4.07798 |
4.06158 |
Knudsen-cell 2 |
4.07900 |
4.05231 |
4.03023 |
4.01440 |
Knudsen-cell 3 |
3.98030 |
3.95607 |
3.93508 |
3.91983 |
Knudsen-cell 4 |
4.11812 |
4.09243 |
4.07000 |
4.05299 |
*The samples were stored in a desiccator after the weightings until start of the next measurement series due to organisational reasons.
Measurement Data Experiment 8
Experiment |
8 |
|
|
|
Nom. Temperature |
135 |
°C |
|
|
Date and time START |
|
06.03.2018 11:30 |
06.03.2018 12:20 |
07.03.2018 12:40 |
Date and time END |
|
06.03.2018 11:30 |
07.03.2018 11:50 |
08.03.2018 11:30* |
Parameter |
Weight m |
Weight m |
Weight m |
Weight m |
Unit |
g |
g |
g |
g |
Knudsen-cell 1 |
4.06158 |
3.67684 |
3.64625 |
3.62614 |
Knudsen-cell 2 |
4.01440 |
3.97110 |
3.94127 |
3.91898 |
Knudsen-cell 3 |
3.91983 |
3.88036 |
3.85199 |
3.83161 |
Knudsen-cell 4 |
4.05299 |
4.00999 |
3.98060 |
3.95884 |
*The samples were stored in a desiccator after the weightings until start of the next measurement series due to organisational reasons.
Measurement Data Experiment 9
Experiment |
9 |
|
|
|
Nom. Temperature |
150 |
°C |
|
|
Date and time START |
|
12.03.2018 12:15 |
13.03.2018 13:55 |
14.03.2018 13:58 |
Date and time END |
|
13.03.2018 13:00 |
14.03.2018 13:00 |
15.03.2018 11:35 |
Parameter |
Weight m |
Weight m |
Weight m |
Weight m |
Unit |
g |
g |
g |
g |
Knudsen-cell 1 |
3.62614 |
3.59670 |
3.58082 |
3.56879 |
Knudsen-cell 2 |
3.91989 |
3.87730 |
3.85467 |
3.83860 |
Knudsen-cell 3 |
3.83161 |
3.79356 |
3.77254 |
3.75749 |
Knudsen-cell 4 |
3.95884 |
3.91737 |
3.89459 |
3.87900 |
Calculation Results
All calculation results are given in the table below.
In all tables, E-0X represents multiplication with 10-x. Experiment 9 (nominal temperature 150 °C) showed no reproducible weight loss. Therefore they were not used for calculation.
Calculation Results Experiment 1
Experiment |
1 |
|
|
|
|
|
|
|
|
Real Temperature in K |
303.2 |
|
|
|
|
|
|
|
|
Real Temperature in °C |
30.0 |
|
|
|
|
|
|
|
|
Date of Measurement |
24.01.2018 11:25 |
25.01.2018 11:20 |
26.01.2018 11:30 |
||||||
Elapsed Time in s |
75000 |
82500 |
82920 |
||||||
Parameter |
Weight loss |
To be used |
Vapour pressure |
Weight loss |
To be used |
Vapour pressure |
Weight loss |
To be used |
Vapour pressure |
Unit |
g |
yes/no |
Pa |
g |
yes/no |
Pa |
g |
yes/no |
Pa |
Knudsen-cell 1 |
0.00155 |
yes |
4.63E-03 |
0.00029 |
yes |
7.88E-04 |
0.00054 |
yes |
1.46E-03 |
Knudsen-cell 2 |
0.01480 |
yes |
4.42E-02 |
0.00167 |
yes |
4.54E-03 |
0.00173 |
yes |
4.68E-03 |
Knudsen-cell 3 |
0.01146 |
yes |
3.43E-02 |
0.00059 |
yes |
1.60E-03 |
0.00057 |
yes |
1.54E-03 |
Knudsen-cell 4 |
0.00940 |
yes |
2.81E-02 |
0.00011 |
yes |
2.99E-04 |
0.00102 |
yes |
2.76E-03 |
Mean |
|
no |
|
|
yes |
1.81E-03 |
|
yes |
2.61E-03 |
Standard deviation: |
|
|
|
|
|
1.90E-03 |
|
|
1.50E-03 |
Mean of measured values: |
2.208E-03 |
|
|
|
|
|
|
||
Standard deviation: |
5.670E-04 |
RSD: |
25.7% |
|
|
|
|
||
If “no” is stated the respective column: measurement was not considered for the calculation of the mean.
Calculation Results Experiment 2
Experiment |
2 |
|
|
|
|
|
|
|
|
Real Temperature in K |
318.2 |
|
|
|
|
|
|
|
|
Real Temperature in °C |
45.0 |
|
|
|
|
|
|
|
|
Date of Measurement |
30.01.2018 11:10 |
31.01.2018 11:30 |
01.02.2018 11:15 |
||||||
Elapsed Time in s |
84360 |
84000 |
82320 |
||||||
Parameter |
Weight loss |
To be used |
Vapour pressure |
Weight loss |
To be used |
Vapour pressure |
Weight loss |
To be used |
Vapour pressure |
Unit |
g |
yes/no |
Pa |
g |
yes/no |
Pa |
g |
yes/no |
Pa |
Knudsen-cell 1 |
0.00091 |
yes |
2.48E-03 |
0.00074 |
yes |
2.02E-03 |
0.00043 |
yes |
1.20E-03 |
Knudsen-cell 2 |
0.00156 |
yes |
4.25E-03 |
0.00127 |
yes |
3.47E-03 |
0.00106 |
yes |
2.96E-03 |
Knudsen-cell 3 |
0.00250 |
yes |
5.58E-03 |
0.00227 |
yes |
6.21E-03 |
0.00113 |
yes |
3.15E-03 |
Knudsen-cell 4 |
0.00147 |
yes |
4.00E-03 |
0.00173 |
yes |
4.73E-03 |
0.00090 |
yes |
2.51E-03 |
Mean |
|
yes |
4.08E-03 |
|
yes |
4.11E-03 |
|
yes |
2.45E-03 |
Standard deviation: |
|
|
1.27E-03 |
|
|
1.78E-03 |
|
|
8.79E-04 |
Mean of measured values: |
3.546E-03 |
|
|
|
|
|
|
||
Standard deviation: |
9.453E-04 |
RSD: |
26.7% |
|
|
|
|
||
Calculation Results Experiment 3
Experiment |
3 |
|
|
|
|
|
|
|
|
Real Temperature in K |
333.2 |
|
|
|
|
|
|
|
|
Real Temperature in °C |
60.0 |
|
|
|
|
|
|
|
|
Date of Measurement |
02.02.2018 10:00 |
06.02.2018 11:45 |
07.02.2018 11:45 |
||||||
Elapsed Time in s |
78600 |
88500 |
83100 |
||||||
Parameter |
Weight loss |
To be used |
Vapour pressure |
Weight loss |
To be used |
Vapour pressure |
Weight loss |
To be used |
Vapour pressure |
Unit |
g |
yes/no |
Pa |
g |
yes/no |
Pa |
g |
yes/no |
Pa |
Knudsen-cell 1 |
0.00222 |
yes |
6.64E-03 |
0.00248 |
yes |
6.58E-03 |
0.00217 |
yes |
6.14E-03 |
Knudsen-cell 2 |
0.00227 |
yes |
6.79E-03 |
0.00162 |
yes |
4.30E-03 |
0.00172 |
yes |
4.86E-03 |
Knudsen-cell 3 |
0.00230 |
yes |
6.88E-03 |
0.00141 |
yes |
3.74E-03 |
0.00185 |
yes |
5.23E-03 |
Knudsen-cell 4 |
0.00303 |
yes |
9.06E-03 |
0.00236 |
yes |
6.27E-03 |
0.00240 |
yes |
6.79E-03 |
Mean |
|
yes |
7.34E-03 |
|
yes |
5.22E-03 |
|
yes |
5.75E-03 |
Standard deviation: |
|
|
1.15E-03 |
|
|
1.41E-03 |
|
|
8.71E-04 |
Mean of measured values: |
6.106E-03 |
|
|
|
|
|
|
||
Standard deviation: |
1.101E-03 |
RSD: |
18.0% |
|
|
|
|
||
Calculation Results Experiment 4
Experiment |
4 |
|
|
|
|
|
|
|
|
Real Temperature in K |
348.2 |
|
|
|
|
|
|
|
|
Real Temperature in °C |
75.0 |
|
|
|
|
|
|
|
|
Date of Measurement |
13.02.2018 11:25 |
14.02.2018 11:50 |
15.02.2018 13:20 |
||||||
Elapsed Time in s |
91500 |
83700 |
89100 |
||||||
Parameter |
Weight loss |
To be used |
Vapour pressure |
Weight loss |
To be used |
Vapour pressure |
Weight loss |
To be used |
Vapour pressure |
Unit |
g |
yes/no |
Pa |
g |
yes/no |
Pa |
g |
yes/no |
Pa |
Knudsen-cell 1 |
0.00513 |
yes |
1.35E-02 |
0.00501 |
yes |
1.44E-02 |
0.00495 |
yes |
1.33E-02 |
Knudsen-cell 2 |
0.00368 |
yes |
9.66E-03 |
0.00273 |
yes |
7.83E-03 |
0.00250 |
yes |
6.74E-03 |
Knudsen-cell 3 |
0.00297 |
yes |
7.80E-03 |
0.00278 |
yes |
7.97E-03 |
0.00270 |
yes |
7.28E-03 |
Knudsen-cell 4 |
0.00454 |
yes |
1.19E-02 |
0.00361 |
yes |
1.04E-02 |
0.00363 |
yes |
9.79E-03 |
Mean |
|
yes |
1.07E-02 |
|
yes |
1.01E-02 |
|
yes |
9.29E-03 |
Standard deviation: |
|
|
2.49E-03 |
|
|
3.05E-03 |
|
|
3.01E-03 |
Mean of measured values: |
1.005E-02 |
|
|
|
|
|
|
||
Standard deviation: |
7.162E-04 |
RSD: |
7.1% |
|
|
|
|
||
Calculation Results Experiment 5
Experiment |
5 |
|
|
|
|
|
|
|
|
Real Temperature in K |
363.2 |
|
|
|
|
|
|
|
|
Real Temperature in °C |
90.0 |
|
|
|
|
|
|
|
|
Date of Measurement |
16.02.2018 11:20 |
20.02.2018 06:48 |
21.02.2018 07:10 |
||||||
Elapsed Time in s |
75600 |
82980 |
84000 |
||||||
Parameter |
Weight loss |
To be used |
Vapour pressure |
Weight loss |
To be used |
Vapour pressure |
Weight loss |
To be used |
Vapour pressure |
Unit |
g |
yes/no |
Pa |
g |
yes/no |
Pa |
g |
yes/no |
Pa |
Knudsen-cell 1 |
0.00372 |
yes |
1.21E-02 |
0.00931 |
yes |
2.75E-02 |
0.00623 |
yes |
1.82E-02 |
Knudsen-cell 2 |
0.00087 |
no |
|
0.00732 |
yes |
2.16E-02 |
0.00336 |
yes |
9.81E-03 |
Knudsen-cell 3 |
0.00040 |
no |
|
0.00636 |
yes |
1.88E-02 |
0.00353 |
yes |
1.03E-02 |
Knudsen-cell 4 |
0.00699 |
yes |
2.27E-02 |
0.01257 |
yes |
3.72E-02 |
0.00984 |
yes |
2.87E-02 |
Mean |
|
yes |
1.74E-02 |
|
yes |
2.63E-02 |
|
yes |
1.68E-02 |
Standard deviation: |
|
|
7.50E-03 |
|
|
8.11E-03 |
|
|
8.86E-03 |
Mean of measured values: |
2.014E-02 |
|
|
|
|
|
|
||
Standard deviation: |
5.328E-03 |
RSD: |
26.5% |
|
|
|
|
||
If “no” is stated in the respective column: measurement was not considered for the calculation of the mean.
Calculation Results Experiment 6
Experiment |
6 |
|
|
|
|
|
|
|
|
Real Temperature in K |
378.2 |
|
|
|
|
|
|
|
|
Real Temperature in °C |
105.0 |
|
|
|
|
|
|
|
|
Date of Measurement |
22.02.2018 06:55 |
23.02.2018 07:00 |
27.02.2018 11:45 |
||||||
Elapsed Time in s |
80700 |
82200 |
87300 |
||||||
Parameter |
Weight loss |
To be used |
Vapour pressure |
Weight loss |
To be used |
Vapour pressure |
Weight loss |
To be used |
Vapour pressure |
Unit |
g |
yes/no |
Pa |
g |
yes/no |
Pa |
g |
yes/no |
Pa |
Knudsen-cell 1 |
0.01660 |
yes |
5.15E-02 |
0.01313 |
yes |
4.00E-02 |
0.01425 |
yes |
4.09E-02 |
Knudsen-cell 2 |
0.01516 |
yes |
4.70E-02 |
0.01874 |
yes |
5.71E-02 |
0.01752 |
yes |
5.02E-02 |
Knudsen-cell 3 |
0.01326 |
yes |
4.11E-02 |
0.01577 |
yes |
4.80E-02 |
0.01618 |
yes |
4.64E-02 |
Knudsen-cell 4 |
0.01861 |
yes |
5.77E-02 |
0.01228 |
yes |
3.74E-02 |
0.01278 |
yes |
3.66E-02 |
Mean |
|
yes |
4.93E-02 |
|
yes |
4.56E-02 |
|
yes |
4.53E-02 |
Standard deviation: |
|
|
7.02E-03 |
|
|
8.87E-03 |
|
|
5.99E-03 |
Mean of measured values: |
4.617E-02 |
|
|
|
|
|
|
||
Standard deviation: |
2.943E-03 |
RSD: |
6.4% |
|
|
|
|
||
Calculation Results Experiment 7
Experiment |
7 |
|
|
|
|
|
|
|
|
Real Temperature in K |
393.2 |
|
|
|
|
|
|
|
|
Real Temperature in °C |
120.0 |
|
|
|
|
|
|
|
|
Date of Measurement |
28.02.2018 11:30 |
01.03.2018 11:25 |
02.03.2018 10:30 |
||||||
Elapsed Time in s |
81960 |
83220 |
79680 |
||||||
Parameter |
Weight loss |
To be used |
Vapour pressure |
Weight loss |
To be used |
Vapour pressure |
Weight loss |
To be used |
Vapour pressure |
Unit |
g |
yes/no |
Pa |
g |
yes/no |
Pa |
g |
yes/no |
Pa |
Knudsen-cell 1 |
0.02729 |
yes |
8.50E-02 |
0.02315 |
yes |
7.10E-02 |
0.01640 |
yes |
5.25E-02 |
Knudsen-cell 2 |
0.02669 |
yes |
8.31E-02 |
0.02208 |
yes |
6.77E-02 |
0.01583 |
yes |
5.07E-02 |
Knudsen-cell 3 |
0.02423 |
yes |
7.55E-02 |
0.02099 |
yes |
6.44E-02 |
0.01525 |
yes |
4.89E-02 |
Knudsen-cell 4 |
0.02569 |
yes |
8.00E-02 |
0.02243 |
yes |
6.88E-02 |
0.01701 |
yes |
5.45E-02 |
Mean |
|
yes |
8.09E-02 |
|
yes |
6.80E-02 |
|
yes |
5.17E-02 |
Standard deviation: |
|
|
4.17E-03 |
|
|
2.76E-03 |
|
|
2.42E-03 |
Mean of measured values: |
6.684E-02 |
|
|
|
|
|
|
||
Standard deviation: |
1.466E-02 |
RSD: |
21.9% |
|
|
|
|
||
Calculation Results Experiment 8
Experiment |
8 |
|
|
|
|
|
|
|
|
Real Temperature in K |
408.2 |
|
|
|
|
|
|
|
|
Real Temperature in °C |
135.0 |
|
|
|
|
|
|
|
|
Date of Measurement |
06.02.2018 11:30 |
07.03.2018 11:50 |
08.03.2018 11:30 |
||||||
Elapsed Time in s |
86400 |
84600 |
82200 |
||||||
Parameter |
Weight loss |
To be used |
Vapour pressure |
Weight loss |
To be used |
Vapour pressure |
Weight loss |
To be used |
Vapour pressure |
Unit |
g |
yes/no |
Pa |
g |
yes/no |
Pa |
g |
yes/no |
Pa |
Knudsen-cell 1 |
0.38474 |
no |
|
0.03059 |
yes |
9.40E-02 |
0.02011 |
yes |
6.36E-02 |
Knudsen-cell 2 |
0.04330 |
yes |
1.30E-01 |
0.02983 |
yes |
9.17E-02 |
0.02229 |
yes |
7.05E-02 |
Knudsen-cell 3 |
0.03947 |
yes |
1.19E-01 |
0.02837 |
yes |
8.72E-02 |
0.02038 |
yes |
6.45E-02 |
Knudsen-cell 4 |
0.04300 |
yes |
1.29E-01 |
0.02939 |
yes |
9.04E-02 |
0.02176 |
yes |
6.89E-02 |
Mean |
|
yes |
1.26E-01 |
|
yes |
9.09E-02 |
|
no |
|
Standard deviation: |
|
|
6.41E-03 |
|
|
2.85E-03 |
|
|
|
Mean of measured values: |
1.085E-01 |
|
|
|
|
|
|
||
Standard deviation: |
2.501E-02 |
RSD: |
23.0% |
|
|
|
|
||
If “no” is stated in the respective column: measurement was not considered for the calculation of the mean.
Evaluation
The measured values for temperature and vapour pressure were evaluated as follows:
Evaluation of Calculated Values
Parameter |
T |
Mean p |
1/T |
Log p |
Unit |
K |
Pa |
1/K |
Log Pa |
Values |
303.2 |
2.21E-03 |
3.2982E-03 |
-2.6561 |
318.2 |
3.55E-03 |
3.1427E-03 |
-2.4502 |
|
333.2 |
6.11E-03 |
3.0012E-03 |
-2.2142 |
|
348.2 |
1.00E-02 |
2.8719E-03 |
-1.9980 |
|
363.2 |
2.01E-02 |
2.7533E-03 |
-1.6959 |
|
378.2 |
4.62E-02 |
2.6441E-03 |
-1.3356 |
|
393.2 |
6.68E-02 |
2.5432E-03 |
-1.1749 |
|
408.2 |
1.09E-01 |
2.4498E-03 |
-0.9645 |
RESULTS
Test Item
The following vapour pressures were determined experimentally and considered as valid (mean and standard deviation given:
Experimentally Determined Vapour Pressures
T |
T |
p |
Stand. Dev. p |
RSD p |
°C |
K |
Pa |
Pa |
% |
30.0 |
303.2 |
2.21E-03 |
5.67E-04 |
25.7% |
45.0 |
318.2 |
3.55E-03 |
9.45E-04 |
26.7% |
60.0 |
333.2 |
6.11E-03 |
1.10E-03 |
18.0% |
75.0 |
348.2 |
1.00E-02 |
7.16E-04 |
7.1% |
90.0 |
363.2 |
2.01E-02 |
5.33E-03 |
25.5% |
105.0 |
378.2 |
4.62E-02 |
2.94E-03 |
6.4% |
120.0 |
393.2 |
6.68E-02 |
1.47E-02 |
21.9% |
135.0 |
408.2 |
1.09E-01 |
2.50E-02 |
23.0% |
In this table, E-0X represents multiplication with 10-x
Stand. Dev. = Standard Deviation; RSD = Relative Standard Deviation
Description of key information
For the test item LUMULSE GMT-K, the following vapour pressures at 20 °C and at 25 °C were calculated from the regression equation:
Vapour pressure at 20 °C: 1.00 * 10-03Pa
Vapour pressure at 25 °C: 1.32 * 10-03Pa
Key value for chemical safety assessment
- Vapour pressure:
- 0.001 Pa
- at the temperature of:
- 25 °C
Additional information
The vapour pressure of LUMULSE GMT-K was determined according to OECD 104 resp. EU A.4 using the effusion method (weight loss).
Vapour pressure was examined at nine different temperatures. Eight temperatures could be evaluated as they showed reproducible weight loss. For these temperatures, 1/T was plotted against log (p).
Vapour Pressures (Effusion Method)
Experiment |
T |
Mean p |
Stand. Dev. p |
RSD p |
No. |
K |
Pa |
Pa |
% |
1 |
303.2 |
2.21E-03 |
5.76E-04 |
25.7% |
2 |
318.2 |
3.55E-03 |
9.45E-04 |
26.7% |
3 |
333.2 |
3.11E-03 |
1.10E-03 |
18.0% |
4 |
348.2 |
1.00E-02 |
7.16E-04 |
7.1% |
5 |
363.2 |
2.01E-02 |
5.33E-03 |
26.5% |
6 |
378.2 |
4.62E-02 |
2.94E-03 |
6.4% |
7 |
393.2 |
6.68E-02 |
1.47E-02 |
21.9% |
8 |
408.2 |
1.09E-01 |
2.50E-02 |
23.0% |
In this table, E-0X represents multiplication with 10-x.
Stand. Dev. = Standard Deviation; RSD = Relative Standard Deviation
The graph 1/T vs. log (p) shows a straight line with a correlation coefficient of - 0.9923.
For the test item LUMULSE GMT-K, the following vapour pressures at 20 °C and at 25 °C were calculated from the regression equation:
Vapour pressure at 20 °C: 1.00 * 10-03Pa
Vapour pressure at 25 °C: 1.32 * 10-03Pa
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
