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EC number: 293-766-2 | CAS number: 91082-52-9
- Life Cycle description
- Uses advised against
- Endpoint summary
- Appearance / physical state / colour
- Melting point / freezing point
- Boiling point
- Density
- Particle size distribution (Granulometry)
- Vapour pressure
- Partition coefficient
- Water solubility
- Solubility in organic solvents / fat solubility
- Surface tension
- Flash point
- Auto flammability
- Flammability
- Explosiveness
- Oxidising properties
- Oxidation reduction potential
- Stability in organic solvents and identity of relevant degradation products
- Storage stability and reactivity towards container material
- Stability: thermal, sunlight, metals
- pH
- Dissociation constant
- Viscosity
- Additional physico-chemical information
- Additional physico-chemical properties of nanomaterials
- Nanomaterial agglomeration / aggregation
- Nanomaterial crystalline phase
- Nanomaterial crystallite and grain size
- Nanomaterial aspect ratio / shape
- Nanomaterial specific surface area
- Nanomaterial Zeta potential
- Nanomaterial surface chemistry
- Nanomaterial dustiness
- Nanomaterial porosity
- Nanomaterial pour density
- Nanomaterial photocatalytic activity
- Nanomaterial radical formation potential
- Nanomaterial catalytic activity
- Endpoint summary
- Stability
- Biodegradation
- Bioaccumulation
- Transport and distribution
- Environmental data
- Additional information on environmental fate and behaviour
- Ecotoxicological Summary
- Aquatic toxicity
- Endpoint summary
- Short-term toxicity to fish
- Long-term toxicity to fish
- Short-term toxicity to aquatic invertebrates
- Long-term toxicity to aquatic invertebrates
- Toxicity to aquatic algae and cyanobacteria
- Toxicity to aquatic plants other than algae
- Toxicity to microorganisms
- Endocrine disrupter testing in aquatic vertebrates – in vivo
- Toxicity to other aquatic organisms
- Sediment toxicity
- Terrestrial toxicity
- Biological effects monitoring
- Biotransformation and kinetics
- Additional ecotoxological information
- Toxicological Summary
- Toxicokinetics, metabolism and distribution
- Acute Toxicity
- Irritation / corrosion
- Sensitisation
- Repeated dose toxicity
- Genetic toxicity
- Carcinogenicity
- Toxicity to reproduction
- Specific investigations
- Exposure related observations in humans
- Toxic effects on livestock and pets
- Additional toxicological data
Explosiveness
Administrative data
Link to relevant study record(s)
- Endpoint:
- explosive properties of explosives
- Type of information:
- experimental study
- Adequacy of study:
- key study
- Study period:
- Experimental start: 14 January 2016, Experimental end data: 22 February 2016
- Reliability:
- 1 (reliable without restriction)
- Rationale for reliability incl. deficiencies:
- guideline study
- Qualifier:
- according to guideline
- Guideline:
- UN Manual of Tests and Criteria: Part I: Classification procedures, test methods and criteria relating to explosives of Class 1
- Version / remarks:
- 2009
- Deviations:
- no
- GLP compliance:
- yes
- Key result
- Parameter:
- other: heat of decomposition
- Remarks:
- J/g
- Value:
- 90
- Remarks on result:
- other: Different Scanning Calorimetry
- Remarks:
- Suitable technique for measuring the exothermic decomposition energy as required for screening potential explosive or self-reactive substances
- Interpretation of results:
- GHS criteria not met
- Conclusions:
- The heat of decomposition was 90 J/g according to the DSC method. This is below the threshold value of 500 J/g, in which case no further testing will be required to establish the explosive properties of the test substance.
- Executive summary:
The explosive properties of the test substance were studied under GLP in accordance with UN Test Series 2 in a screening procedure applying differential scanning calorimetry following Appendix 6 of the UN Test Manual. The experiment is considered relevant, adequate and conclusive. The heat of decomposition was 90 J/g according to the DSC method. This is below the threshold value of 500 J/g, in which case no further testing will be required to establish the explosive properties of the test substance. Consequently, the classification scheme need not be applied if the heat of decomposition is less than 500 J/g.
- Endpoint:
- explosiveness, other
- Type of information:
- experimental study
- Adequacy of study:
- key study
- Study period:
- Experimental start: 14 January 2016, Experimental end data: 22 February 2016
- Reliability:
- 1 (reliable without restriction)
- Rationale for reliability incl. deficiencies:
- guideline study
- Qualifier:
- according to guideline
- Guideline:
- UN Manual of Tests and Criteria: Part I: Classification procedures, test methods and criteria relating to explosives of Class 1
- Version / remarks:
- 2009
- Deviations:
- no
- GLP compliance:
- yes
- Key result
- Parameter:
- other: heat of decomposition
- Remarks:
- J/g
- Value:
- 90
- Remarks on result:
- other: Differential Scanning Calorimetry
- Remarks:
- Suitable technique for measuring the exothermic decomposition energy as required for screening potential explosive or self-reactive substances
- Interpretation of results:
- GHS criteria not met
- Conclusions:
- The heat of decomposition was 90 J/g according to the DSC method. This is below the threshold value of 300 J/g, in which case no further testing will be required to establish the self-reaction properties of the test substance.
- Executive summary:
The self-reaction properties of the test substance were studied under GLP in accordance with UN Test Series 2 in a screening procedure applying differential scanning calorimetry following Appendix 6 of the UN Test Manual. The experiment is considered relevant, adequate and conclusive. The heat of decomposition was 90 J/g according to the DSC method. This is below the threshold value of 300 J/g, in which case no further testing will be required to establish the self-reaction properties of the test substance. Consequently, the classification scheme need not be applied if the heat of decomposition is less than 300 J/g.
Referenceopen allclose all
Description of key information
In a valid, reliable and conclusive study according to UN Manual of Tests and Criteria, Part I, the heat of decomposition, as determined with an appropriate DSC method, was 90 J/g.
Key value for chemical safety assessment
- Explosiveness:
- non explosive
Additional information
Justification for classification or non-classification
The heat of decomposition, as determined with an appropriate DSC method in accordance with the UN Test Series 2, was 90 J/g. This value is clearly below the cut-off values for self-reaction (300 J/g) and explosive properties (500 J/g). The substance does not fulfil the criteria for classification und the CLP Regulation (EC) No. 1272/2008.
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