Registration Dossier

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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Administrative data

First-aid measures

General advice:
Remove contaminated clothing. If danger of loss of consciousness, place patient in recovery position and transport accordingly. Apply artificial respiration if necessary. First aid personnel should pay attention to their own safety.
If inhaled:
If difficulties occur after vapour/aerosol has been inhaled, remove to fresh air and seek medical attention.
On skin contact:
Wash thoroughly with soap and water.
On contact with eyes:
Wash affected eyes for at least 15 minutes under running water with eyelids held open. If irritation develops, seek medical attention.
On ingestion:
Rinse mouth immediately and then drink plenty of water, seek medical attention.

Fire-fighting measures

Suitable extinguishing media:
dry extinguishing media, foam, carbon dioxide, water spray
Unsuitable extinguishing media for safety reasons:
water jet
Specific hazards:
hydrocyanic acid, toxic gases/vapours
Special protective equipment:
Wear self-contained breathing apparatus and chemical-protective clothing.
Further information:
Collect contaminated extinguishing water separately, do not allow to reach sewage or effluent systems. Keep containers cool by spraying with water if exposed to fire.

Accidental release measures

Personal precautions:
Avoid inhalation. Avoid contact with the skin, eyes and clothing.
Environmental precautions:
Do not discharge into drains/surface waters/groundwater.
Methods for cleaning up or taking up:
For small amounts: Pick up with suitable appliance and dispose of.
For large amounts: Pick up with suitable appliance and dispose of.

Handling and storage

Handling
Ensure thorough ventilation of stores and work areas.
Protection against fire and explosion:
Prevent electrostatic charge - sources of ignition should be kept well clear - fire extinguishers should be kept handy.
Storage
Segregate from oxidants. Segregate from acids.
Further information on storage conditions: Keep container tightly closed in a cool, well-ventilated place

Transport information

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Marine transport (UN RTDG/IMDG)

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Exposure controls / personal protection

Personal protective equipment
Respiratory protection:
Wear respiratory protection if ventilation is inadequate. Self-contained breathing apparatus.
Hand protection:
Chemical resistant protective gloves (EN 374)
Suitable materials also with prolonged, direct contact (Recommended: Protective index 6, corresponding > 480 minutes of permeation time according to EN 374):
butyl rubber (butyl) - 0.7 mm coating thickness
polyvinylchloride (PVC) - 0.7 mm coating thickness
Manufacturer's directions for use should be observed because of great diversity of types.

Supplementary note: The specifications are based on own tests, literature data and information of glove manufacturers or are derived from similar substances by analogy. Due to many conditions (e.g. temperature) it must be considered, that the practical usage of a chemical-protective glove in practice may be much shorter than the determined permeation time.

Eye protection:
Safety glasses with side-shields (frame goggles) (e.g. EN 166)
General safety and hygiene measures:
Handle in accordance with good industrial hygiene and safety practice. Wearing of closed work clothing is required additionally to the stated personal protection equipment

Stability and reactivity

Substances to avoid:
oxidizing agents, strong alkalies, strong acids
Hazardous reactions:
Evolution of explosive gases/vapours.
Hazardous decomposition products:
methanol
The substances/substance groups mentioned are formed by hydrolysis.
Possible thermal decomposition products:
hydrocyanic acid

Disposal considerations

Incinerate in suitable incineration plant, observing local authority regulations.


Contaminated packaging:
Contaminated packaging should be emptied as far as possible; then it can be passed on for recycling after being thoroughly cleaned.