N1,N3-diallylpropane-1,3-diamine dihydrochloride

Guidance on Safe Use

First-aid measures

Description of first aid measures:

General information: Immediately remove any clothing soiled by the product.

After inhalation: In case of unconsciousness place patient stably in side position for transportation.

After skin contact: Immediately wash with water and soap and rinse thoroughly.

After eye contact: Remove contact lenses immediately!

Rinse opened eye for several minutes under running water.

Fire-fighting measures

Extinguishing media:

Suitable extinguishing agents: Water spray, Fire-extinguishing powder, Carbon dioxide

For safety reasons unsuitable extinguishing agents:

Avoid high pressure extinguishing media which could cause the formation of a potentially explosible dust-air mixture.

Special hazards arising from the substance or mixture:

Nitrogen oxides (NOx)

In case of fire, the following can be released:

The possibility of formation of explosive dust/air mixtures under certain conditions should be basically considered during handling and processing.

Carbon monoxide (CO), Hydrogen chloride (HCl)

Advice for firefighters protective equipment:

Wear self-contained respiratory protective device. Chemical resistant protective suit. Under the protective suit a fire protective suit according to EN 469 should be applied.

Accidental release measures

Personal precautions, protective equipment and emergency procedures:

Wear protective clothing.

Avoid contact with eyes and skin and clothes

Do not breathe dust.

Access only for trained personnel with personal protective equipment.

Use respiratory protective device against the effects of fumes/dust/aerosol.

Avoid spillage of product into the environment.

Avoid formation of dust.

Implementation of further measures based on existing emergency plans.

Environmental precautions:

Keep contaminated washing water and dispose of appropriately.

Inform respective authorities in case of seepage into water course or sewage system.

Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system.

Methods and material for containment and cleaning up:

Pick up mechanically. If formation of dust cannot be avoided use respiratory filter device.

Handling and storage

Precautions for safe handling:

Empty containers must not be used for other products.

Contaminated protective equipment should be cleaned before taking it off.

Any unavoidable deposit of dust must be completely removed.

Ensure good ventilation/exhaustion at the workplace.

Protect from humidity.

Fill only in dedicated and assigned containers.

Keep containers tightly sealed.

Requirements to be met by storerooms and receptacles:

Store in a dry location, keep away from humidity.

Store in a cool location.

Corrosion of metals:

Test method according to CLP is not applicable (solid material at 55°C).

It should generally be borne in mind that there is a possibility of corrosion on contact with this material. Resistance should be checked in each individual case.

In presence of water or humidity a corrosive action on metals cannot be excluded.

Information about storage in one common storage facility:

Do not store together with alkalis (caustic solutions).

Store away from oxidising agents.

Further information about storage conditions:

Protect from humidity and water.

Recommended storage temperature:

Room temperature

Transport information

Land transport (UN RTDG/ADR/RID)

UN number:

UN number: Not classified as dangerous for transport

Shipping

SpecialProvisions

Inland waterway transport (UN RTDG/ADN(R))

UN number:

UN number: Not classified as dangerous for transport

Shipping

Remarks

Marine transport (UN RTDG/IMDG)

UN number:

UN number: Not classified as dangerous for transport

Shipping

Remarks

Air transport (UN RTDG/ICAO/IATA)

UN number:

UN number: Not classified as dangerous for transport

Shipping

Remarks

SpecialProvisions

Exposure controls / personal protection

Additional information about design of technical facilities:

Take care of sufficient ventilation. Avoid formation of dust.

Handle this material under exclusion of humidity.

Waste gases should be led into the atmosphere only via appropriate separators, scrubbers or incinerators.

Exposure controls:

This product has to be handled under strictly controlled conditions.

General protective and hygienic measures:

Contaminated protective suit shall be cleaned before taking it off.

Keep away from foodstuffs, beverages and feed.

Immediately remove all soiled and contaminated clothing.

Wash hands before breaks and at the end of work.

Store protective clothing separately.

Avoid contact with the eyes and skin.

Respiratory protection: Particle filter. The filter grade (P1 - P3) has to be established depending on work-place related limit values and the actual exposition.

Protection of hands:

Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation.

For the permanent contact gloves made of the following materials are suitable:

The following materials are known from experience to be suitable for protection against undissolved solids: rubber.

Check for tightness before use.

Replace damaged gloves.

Eye protection:

Safety glasses

Body protection:

Use particle-proof protective suit.

Selection of personal protective suits depending on amount and concentration of hazardous material and on possible exposition at the working place.

Protection against thermal hazards:

No specific measures required

Limitation and supervision of exposure into the environment:

Avoid spillage of product into the environment.

If possible use this material only in closed systems and devices. In case of open plant systems (sampling devices, filling and discharging, cleansing works etc.) use local exhaust and collecting trays. Follow emission limit values. Measures in case of unwanted emissions should be established.

Risk management measures:

General protective and hygienic measures have to be observed.

Employees who use this material/formulation must be trained and demonstrably instructed about possible risks for man and environment.

Measures for prevention of hazards in case of unwanted leakage (LOPC) shall be implemented.

Stability and reactivity

Thermal decomposition / conditions to be avoided:

No decomposition if used according to specifications.

Sensitive to water: Hygroscopic

Possibility of hazardous reactions:

The possibility of formation of explosive dust/air mixtures under certain

conditions should be principally considered during handling and processing.

Incompatible materials:

Strong oxidising agents

Bases

Hazardous decomposition products:

Nitrogen oxides

Hydrogen chloride (HCl)

Carbon monoxide and carbon dioxide

Disposal considerations

Waste treatment methods:

Recommendation:

Must not be disposed together with household garbage.

Do not allow product to reach sewage system.

Must be specially treated adhering to official regulations.

If possible recovery or recycling.

Uncleaned packaging:

Recommendation:

Empty contaminated packagings thoroughly. They may be recycled after thorough and proper cleaning.

Contaminated containers or containers with residual amounts must be treated as hazardous wastes.

Appropriate disposal:

Empty container completely.

Storage in a safe place after emptying.

Biological waste water treatment:

Discharge into waste water channels and biological treatment plants

only after clearance with the operating company and in accordance with local Authority approval.