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Diss Factsheets

Physical & Chemical properties

Auto flammability

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Administrative data

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Endpoint:
relative self-ignition temperature (solids)
Type of information:
experimental study
Adequacy of study:
key study
Study period:
03.11.1994
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Qualifier:
according to guideline
Guideline:
EU Method A.16 (Relative Self-Ignition Temperature for Solids)
Deviations:
no
GLP compliance:
yes
Relative self-ignition temperature:
> 403 °C

 No self-ignition was recorede up to the end temperature of 403 °C.

Endpoint:
auto-ignition temperature (liquids)
Type of information:
experimental study
Adequacy of study:
key study
Study period:
21.07.2015 - 24.07.2015
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Qualifier:
according to guideline
Guideline:
EU Method A.15 (Auto-Ignition Temperature (Liquids and Gases))
GLP compliance:
yes (incl. QA statement)
Remarks:
Hess. Ministerium für Umwelt, Energie, Landwirtschaft und Verbranchcrschutz, Mainzer Straße 80, D65189 Wiesbaden
Auto-ignition temperature:
430 °C
Atm. press.:
>= 1 001 - <= 1 009.3 hPa

Individual results

The test item was a solidified melt. Therefore it was liquefied at 80 °C before the measurements.

Preliminary test

Table 1 shows the results of the preliminary tests. Temperatures where self-ignition was detected are marked with +; temperatures where no self-ignition was detected are marked within the below table. The amount of test item tested at each measurement is indicated as numbers of portions (i.e. drops).

Table 1: Results from the preliminary test

Preliminary test

T/°C

5

-

--

203

5

-

--

253

5

-

--

303

5

-

--

353

5

-

--

403

5

-

--

453

5

-

--

503

5

+

0

473

5

+

0

barometric pressure: 1008.0 hPa

 

The lowest self-ignition temperature of the test item was determined to be 473 °C in the preliminary test.

Main tests

In Table 2 to Table 5 the results of the main test are shown. Temperatures where self-ignition was detected are marked with +; temperatures where no self-ignition was detected are marked within the below table. The amount of test item tested at each measurement is indicated as numbers of portions (i.e. drops).

Results from the test series

Main test series

Auto-iqnition temperature / °C

1stmain test (5 K steps)

433

1stmain test (2 K steps)

437

2ndmain test (2 K steps)

437

3rdmain test (2 K steps)

432

The lowest auto-ignition temperature of the test item was determined to be 432 °C in the main test. Due to safety reasons and according to the guidelines the lowest measured temperature at which an ignition was observed was rounded to the next lower number divisible by 5, giving a value of 430 °C.

Description of key information

The test substance (pure) is classified within the definition of the Directive as not highly flammable. No self-ignition was recorede up to the end temperature of 403 °C.

The auto-ignition temperature of the test item (technical substance) according to the auto-ignition test conditions in the Method A. 15. was 430 °C.

Key value for chemical safety assessment

Additional information