Registration Dossier

Administrative data

First-aid measures

Contact With Skin: Wash off with plenty of water. Remove contaminated clothing
Contact With Eyes: rinse out with plenty of water with the eyelid held wide open. Call in ophthamologist.
After inhalation: Remove patient to fresh air, consult doctor if feeling unwell
After Ingestion: Immediately make victim drink water (two glasses at the most). Seek medical advice
Special Advice/Note To Physician:
Persons developing serious hypersensitivity reactions must receive immediate medical attention.

Fire-fighting measures

Suitable extinguishing Media: water, CO2, foam, dry powder extinguishers
Special Exposure Hazards: Combustible, Explosive decomposition possible on heating. Development of hazardous combustion gases or vapors possible in the event of fire.
It emits toxic fumes under fire conditions or when heated to decomposition. The following may develop: nitrogen oxides, hydrogen fluoride.
Special protective equippement for fire fighting:
Do not stay in dangerous zone without self-contained breathing apparatus. In order to avoid contact with skin, keep a safe distance and wear suitable protective clothing.
Protective equipment: wear a self-contained breathing apparatus and full protective gear.
Other information:
Cool container with spray water from safe distance. Contain escaping vapors with water. Prevent fire-fighting water from entering surface water or groundwater

Accidental release measures

Person-related precautionary measures:
Avoid substance contact. Avoid generatin of dusts; do not inhale dusts. Ensure supply of fresch air in enclosed rooms.

Environmental-protection measures:
Do not allow to enter sewage systems; risk of explosion!

Procedures for cleaning/absorption:
Take up dry. Forward for disposal. Clean up affected area.

Handling and storage

This substance is handled under Strictly Controlled Conditions in accordance with REACH regulation Article 18(4) for transported isolated intermediates. In case the substance is transported to other sites for further processing, the substance should be handled at these sites under the Strictly Controlled Conditions as specified in REACH regulation Article 18(4). Site documentation to support safe handling arrangements including the selection of engineering, administrative and personal protective equipment controls in accordance with risk-based management systems is available at each Manufacturing site.

Written confirmation of application of Strictly Controlled Conditions has been received from every affected Distributor and Downstream Manufacturer/ User of the Registrant's intermediate.

Usage/Handling Precautions:
- follow good industrial hygiene practice in handling
Storage Conditions/Precautions:
- keep in cool place (safe storage and transport up to 70°C (amounts > 100kg), up to 120°C for amounts < 100 kg)
- keep container tightly closed
- keep container in a dry place
- keep away from heat, sparks and flame
Ambient Storage Pressure: Atm.
Observe national regulations

Transport information

Land transport (ADR/RID)

UN number:
UN 1325
Shippingopen allclose all
Class:
ADR 4.1, II
Packaging group:
II Use only soft packaging (e.g. plastic bottle), do not use metal
Labels:
Flammable solid, organic
SpecialProvisionsopen allclose all

Inland waterway transport (ADN(R))

UN number:
not tested
Shippingopen allclose all
Packaging group:
II Use only soft packaging (e.g. plastic bottle), do not use metal
Labels:
Flammable solid
Remarksopen allclose all

Marine transport (IMDG)

UN number:
UN 1325
Proper shipping name and description:
Flammable solid organics, N. O. S.
Chemical name:
1H-Benzotriazolium, 1-[bis(dimethylamino)methylene]-, 3-oxide, tetrafluoroborate(1-)
Packaging group:
II Use only soft packaging (e.g. plastic bottle), do not use metal
Labels:
Flammable solid organics
Remarksopen allclose all

Air transport ICAO/IATA

UN number:
UN 1325
Proper shipping name and description:
Flammable solid organics, N. O. S.
Chemical name:
(O-(1H-Benzotriazol-1-yl)-N,N,N',N',-tetramethyluronium tetrafluoroborate
Class:
4.1,II
Packaging group:
II Use only soft packaging (e.g. plastic bottle), do not use metal
Labels:
Flammable solid
Remarksopen allclose all
SpecialProvisionsopen allclose all

Exposure controls / personal protection

Personal Protective Equipment:

- Hand Protection:
material: nitrile rubber, 0,11 mmm, breakthrough time: >480 min.

- Eye Protection: Chemical safety goggles

- Respiratory Protection: required when dusts are generated. Filter P2 (acc. to DIN 3181) for solid and liquid particles of harmful substances.

This substance is handled under Strictly Controlled Conditions in accordance with REACH regulation Article 18(4) for transported isolated intermediates. In case the substance is transported to other sites for further processing, the substance should be handled at these sites under the Strictly Controlled Conditions as specified in REACH regulation Article 18(4). Site documentation to support safe handling arrangements including the selection of engineering, administrative and personal protective equipment controls in accordance with risk-based management systems is available at each Manufacturing site.

Written confirmation of application of Strictly Controlled Conditions has been received from every affected Distributor and Downstream Manufacturer/ User of the Registrant's intermediate.

Stability and reactivity

Conditions/Materials to Avoid:
Material is stable from a safety point of view.
Avoid contact of TBTU with acids and bases, which certain conditions can react
violently with the material.
Avoid contact with any source of ignition.
Hazardous Decomposition Products:
It may emit toxic fumes under fire conditions or when heated to decomposition: nitrogen oxides, hydrogen fluoride, carbon monoxide
and other.

Disposal considerations

Disposal Methods:
- Dispose of waste in accordance with all applicable Federal, State and local laws.
- Do not expose empty containers to heat, sparks or open flame.