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Diss Factsheets

Administrative data

Link to relevant study record(s)

Reference
Endpoint:
oxidising solids
Type of information:
experimental study
Adequacy of study:
key study
Reliability:
2 (reliable with restrictions)
Rationale for reliability incl. deficiencies:
other: Guideline experimental study, not GLP compliant, minor restrictions in design and/or reporting but otherwise adequate for assessment
Qualifier:
according to guideline
Guideline:
other: UN-Test O.1, UN Recommendations on the Transport of Dangerous Goods, Tests and Criteria, fifth revised edition, 2009.
GLP compliance:
no
Contact with:
powdered cellulose
Duration of test (contact time):
min
Sample tested:
1:1 sample-to-cellulose ratio
Parameter:
mean burning time
Result:
>= 38 - <= 48 s
Remarks on result:
other: t1 result. 1:1 ratio of test item:cellulose (% by mass); Mean burning times of test mixture; 43.0 s, n = 5
Sample tested:
4:1 sample-to-cellulose ratio
Parameter:
mean burning time
Result:
>= 6 - <= 8 s
Remarks on result:
other: t2 result. 4:1 ratio of test item:cellulose (% by mass); Mean burning times of test mixture; 6.8 s, n = 5

Platinum-IV-oxihydrate (2.23/190811/01)

The sample was used as delivered. 

Mixture ratio sample : cellulose

[ by mass]

Burning time, t [s]

Mean burning time
[s]

 1:1     48.0  42.0  40.0  38.0  47.0  t1: 43.0   
Violent burn-off with yellow flames and formation of smoke
 4.1     7.0  6.0  6.0  7.0  8.0     t2: 6.8
 Violent burn-off with yellow flames and formation of smoke

 

Reference mixtures (measured 14 September 2011)

Ratios of potassium bromate : Cellulose
[by mass]

Burning time t [s]

Mean burning times
[s]

3:7

143.0

129.0

139.0

145.0

116.0

R1: 134,4

Burn-off with yellow flames

2:3

57.0

62.0

52.0

68.0

69.0

R2: 61.6

Violent burn-off with yellow flames

3:2

19.0

19.0

18.0

18.0

15.0

R3: 17.8

Violent burn-off with yellow flames

 

Interpretation of results:
Category 1 (strong oxidising solids) based on GHS criteria
Conclusions:
On the basis of the test results and according to the criteria specified in the Regulation (EC) No 1272/2008 (CLP-/GHS-Regulation) platinum dioxide is an oxidising solid of Category 1.
Executive summary:

This is a guideline experimental study and is not GLP compliant, but is otherwise adequate for assessment. On the basis of the test results and according to the criteria specified in the Regulation (EC) No 1272/2008 (CLP-/GHS-Regulation) platinum dioxide is an oxidising solid of Category 1.

Description of key information

On the basis of the test results and according to the criteria specified in the Regulation (EC) No 1272/2008 (CLP-/GHS-Regulation) platinum dioxide is an oxidising solid of Category 1.

Key value for chemical safety assessment

Oxidising properties:
yes

Additional information

Michael-Schulz (2011) is a non-GLP study following UN method O.1 and is considered reliable and suitable for use for this endpoint. On the basis of the test results and according to the criteria specified in the Regulation (EC) No 1272/2008 (CLP-/GHS-Regulation) platinum dioxide is an oxidising solid of Category 1.

Justification for classification or non-classification

Based on experimental data, platinum dioxide is classified as an oxidising solid, Category 1.