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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Administrative data

Endpoint:
vapour pressure
Type of information:
experimental study
Adequacy of study:
key study
Study period:
30 September 2009- 6 January 2010
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
other: This study has been performed according to OECD and EC guidelines and according to GLP principles.

Data source

Reference
Reference Type:
study report
Title:
Unnamed
Year:
2010
Report date:
2010

Materials and methods

Test guidelineopen allclose all
Qualifier:
according to guideline
Guideline:
OECD Guideline 104 (Vapour Pressure Curve)
Deviations:
no
Qualifier:
according to guideline
Guideline:
EU Method A.4 (Vapour Pressure)
Deviations:
no
GLP compliance:
yes (incl. QA statement)
Type of method:
effusion method: by loss of weight or by trapping vaporisate

Test material

Constituent 1
Chemical structure
Reference substance name:
Tris(methylphenyl) phosphite
EC Number:
247-119-6
EC Name:
Tris(methylphenyl) phosphite
Cas Number:
25586-42-9
Molecular formula:
C21H21O3P
IUPAC Name:
tris(methylphenyl) phosphite
Details on test material:
- Name of test material (as cited in study report): TTP
- Molecular formula: C21H21PO3
- Molecular weight: 352
- Substance type: Clear colourless liquid
- Physical state: liquid
- Analytical purity:>92,1%
- Impurities: - 7,5% Phosphorochloridous acid, bis-methylphenyl)ester
- 0,4% Cresol
(the initial purity information in the study report (which was 99%) has been corrected with an amendement of the report on 9. Nov 2011)
- Isomers composition: -
- Purity test date: -
- Lot/batch No: HR9C77938
- Expiration date of the lot/batch: 31 March 2010
- Stability under test conditions: Stable
- Storage condition of test material: At room temperature in the dark under nitrogen
- Other: Test substance handling: Reactive to moisture, handle in nitrogen environment in glove box

Results and discussion

Vapour pressure
Temp.:
20 °C
Vapour pressure:
0.524 Pa
Remarks on result:
other: Extrapolation of the curve to 20°C resulted in a value of -4.49 for the log ¿T, 20 of the test substance. Fitting this value in the regression curve, a vapour pressure of 5.24x10-1 Pa = 3.93x10-3 mm Hg was obtained.

Applicant's summary and conclusion

Conclusions:
The isothermal thermogravimetric effusion method was chosen for the determination of the vapour pressure of TTP. The vapour pressure of the test substance at 20°C (293K) was 5.24 x 10-1 Pa = 3.93 x 10-3 mm Hg.