Registration Dossier
Registration Dossier
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The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.
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EC number: 203-854-4 | CAS number: 111-29-5
Guidance on Safe Use
Guidance on Safe Use
Administrative data
First-aid measures
Description of first aid measures
General indications: IF exposed or concerned: Get medical advice/attention. The first responders must always wear appropriate personal protective equipment (see SECTION 8.2).
Contact with the eyes: Rinse cautiously with water for several minutes, holding the eyelids open. If eye irritation occurs, call a doctor.
Contact with the skin: Take off immediately all contaminated clothing. Wash with plenty of water and soap. If skin irritation/eruption occurs, call a doctor.
Inhalation: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Give oxygen and call a doctor, if you feel unwell. If breathing has stopped, administer artificial respiration (by trained personnel).
Ingestion: Rinse mouth with water. Do not induce vomiting, unless recommended by a doctor. Never give anything by mouth if the person is not conscious. If you feel unwell, call a POISON CENTER.
General indications: IF exposed or concerned: Get medical advice/attention. The first responders must always wear appropriate personal protective equipment (see SECTION 8.2).
Contact with the eyes: Rinse cautiously with water for several minutes, holding the eyelids open. If eye irritation occurs, call a doctor.
Contact with the skin: Take off immediately all contaminated clothing. Wash with plenty of water and soap. If skin irritation/eruption occurs, call a doctor.
Inhalation: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Give oxygen and call a doctor, if you feel unwell. If breathing has stopped, administer artificial respiration (by trained personnel).
Ingestion: Rinse mouth with water. Do not induce vomiting, unless recommended by a doctor. Never give anything by mouth if the person is not conscious. If you feel unwell, call a POISON CENTER.
Fire-fighting measures
Extinguishing media
Suitable: Use extinguishing media appropriate to the source of the fire and the surrounding area (e.g. water spray, carbon dioxide, dry chemical powder or foam).
Unsuitable: Direct water jet.
Special hazards arising from the substance or mixture
The substance is not flammable.
Advice for firefighters
Evacuate and isolate the area until complete fire extinction, by limiting access only to trained personnel. Firefighters must always wear appropriate protective equipment: positive pressure self-contained breathing apparatus; fireproof clothing; fireproof gloves; firefighter’s boots. Ensure adequate ventilation. Avoid breathing gases/vapours and contact with eyes, skin and clothing. Stay upwind. Remove containers if it can be done without risk. Alternatively, cool the recipients exposed to fire with water spray. Prevent the contaminated extinguishing water flowing into drains or waterways.
Suitable: Use extinguishing media appropriate to the source of the fire and the surrounding area (e.g. water spray, carbon dioxide, dry chemical powder or foam).
Unsuitable: Direct water jet.
Special hazards arising from the substance or mixture
The substance is not flammable.
Advice for firefighters
Evacuate and isolate the area until complete fire extinction, by limiting access only to trained personnel. Firefighters must always wear appropriate protective equipment: positive pressure self-contained breathing apparatus; fireproof clothing; fireproof gloves; firefighter’s boots. Ensure adequate ventilation. Avoid breathing gases/vapours and contact with eyes, skin and clothing. Stay upwind. Remove containers if it can be done without risk. Alternatively, cool the recipients exposed to fire with water spray. Prevent the contaminated extinguishing water flowing into drains or waterways.
Accidental release measures
Personal precautions, protective equipment, and procedures in case of emergency
In case of relevant spillage, alert the emergency personnel. Isolate the area until complete dispersion of the substance and restrict the access only to trained personnel. Ensure adequate ventilation. Avoid breathing dust/mist/vapours and contact with eyes and skin. Wear appropriate personal protective equipment.
Environmental precautions
Prevent the substance from leaking into the environment and run off into drains, surface waters and groundwater. Alert competent authorities if large amounts into drains or watercourses.
Methods and material for containment and cleaning up
Adsorb with an inert material. Collect with mechanical means and transfer in a properly labeled container. Dispose of in accordance with local and national legislation. Clean surface thoroughly in order to remove residual contamination.
In case of relevant spillage, alert the emergency personnel. Isolate the area until complete dispersion of the substance and restrict the access only to trained personnel. Ensure adequate ventilation. Avoid breathing dust/mist/vapours and contact with eyes and skin. Wear appropriate personal protective equipment.
Environmental precautions
Prevent the substance from leaking into the environment and run off into drains, surface waters and groundwater. Alert competent authorities if large amounts into drains or watercourses.
Methods and material for containment and cleaning up
Adsorb with an inert material. Collect with mechanical means and transfer in a properly labeled container. Dispose of in accordance with local and national legislation. Clean surface thoroughly in order to remove residual contamination.
Handling and storage
This substance is handled under Strictly Controlled Conditions in accordance with REACH regulation Article 18 (3) for isolated and transported intermediates. Site documentation to support safe handling arrangements including the selection of engineering, administrative and personal protective equipment controls in accordance with risk-based management systems is available at the manufacturing site.
Transport information
Land transport (UN RTDG/ADR/RID)
- UN number:
- Not applicable
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Inland waterway transport (UN RTDG/ADN(R))
- UN number:
- Not applicable
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Marine transport (UN RTDG/IMDG)
- UN number:
- Not applicable
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Air transport (UN RTDG/ICAO/IATA)
- UN number:
- Not applicable
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Exposure controls / personal protection
This substance is handled under Strictly Controlled Conditions in accordance with REACH regulation Article 18 (3) for isolated and transported intermediates. Site documentation to support safe handling arrangements including the selection of engineering, administrative and personal protective equipment controls in accordance with risk-based management systems is available at the manufacturing site.
Control parameters
The substance has no occupational exposure limit values.
Exposure controls
Skin protection: Wear protective clothing with long sleeve.
Hand protection: Wear work gloves impervious to chemicals made of nitrile rubber.
Eye protection: Wear appropriate safety glasses with side shields.
Respiratory protection: In the case of vapour formation, wear a respirator with an approved filter.
Technical and hygienic measures: Provide local exhaust ventilation suction or other devices to maintain the levels of particles in the air below the recommended exposure limits. Equip the plant with exhaust hoods or equivalent dust collection devices. Equip with emergency showers and eyewash device the areas in which handling and storage of the product takes place. Do not eat, drink, or smoke during use. Wash hands and other exposed areas after use. Wash periodically clothes and personal protective equipment to remove contaminants. Handle in accordance with good industrial hygiene and safety practices.
Control parameters
The substance has no occupational exposure limit values.
Exposure controls
Skin protection: Wear protective clothing with long sleeve.
Hand protection: Wear work gloves impervious to chemicals made of nitrile rubber.
Eye protection: Wear appropriate safety glasses with side shields.
Respiratory protection: In the case of vapour formation, wear a respirator with an approved filter.
Technical and hygienic measures: Provide local exhaust ventilation suction or other devices to maintain the levels of particles in the air below the recommended exposure limits. Equip the plant with exhaust hoods or equivalent dust collection devices. Equip with emergency showers and eyewash device the areas in which handling and storage of the product takes place. Do not eat, drink, or smoke during use. Wash hands and other exposed areas after use. Wash periodically clothes and personal protective equipment to remove contaminants. Handle in accordance with good industrial hygiene and safety practices.
Stability and reactivity
Reactivity: The substance is not reactive under recommended conditions of use.
Chemical stability: The substance is stable under recommended conditions of use and storage.
Possibility of hazardous reactions: The possibility of hazardous reactions is not expected under recommended conditions of use and storage.
10.4. Conditions to avoid: Avoid exposure to moisture and direct sunlight. Keep away from heat/sparks/open flames.
Incompatible materials: Strong acids and strong oxidizing agents.
Hazardous decomposition products: Not expected.
Chemical stability: The substance is stable under recommended conditions of use and storage.
Possibility of hazardous reactions: The possibility of hazardous reactions is not expected under recommended conditions of use and storage.
10.4. Conditions to avoid: Avoid exposure to moisture and direct sunlight. Keep away from heat/sparks/open flames.
Incompatible materials: Strong acids and strong oxidizing agents.
Hazardous decomposition products: Not expected.
Disposal considerations
Waste treatment methods
Incinerate in suitable incineration plant, observing local authority regulations. A waste code in accordance with the European waste catalog (EWC) cannot be specified, due to dependence on the usage.
Contaminated packaging
Contaminated packaging should be emptied as far as possible; then it can be passed on for recycling after being thoroughly cleaned.
Incinerate in suitable incineration plant, observing local authority regulations. A waste code in accordance with the European waste catalog (EWC) cannot be specified, due to dependence on the usage.
Contaminated packaging
Contaminated packaging should be emptied as far as possible; then it can be passed on for recycling after being thoroughly cleaned.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
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