Cyclohexane, oxidized, aq. ext.

Guidance on Safe Use

First-aid measures

General information

Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves.  Take off contaminated clothikng and shoes immediately.  Keep victim warm.  In case of shortness of breath, give oxygen.  In the case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

Inhalation:

Move to fresh air.  Call a physician if symptoms develop or persist.

Skin contact:

In case of contact, immediatly flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.  Get medical attention immediatly.  Wash clothing separetly before reuse.

Eye contact:

Immediately flush eyes with plenty of water for at least 15 minutes.  Remove contact lenses, if present and easy to do.  Get medical attention immediately.

Ingestion:

Have victim rinse thoroughly with water.  Never give anyting by mouth to a victim who is unconscious or is having convulsions.  If swallowed, do NOT induce vomiting.  If vomiting occurs naturally, have victim lean forward to reduce risk of aspiration.  Get medical attention immediately.

Most important symptoms and effects, both acute and delayed

Eyes: Corrosive to the eyes and may cause severe damage including blindness.  Symptoms may include stinging, tearing, redness, swelling, and blurred vision.

Skin:  Symptoms may incluse redness, drying of skin, itching, and pain.

Inhalation: Inhalation may provoke the follwoing symptoms: cough, discomfort and difficulty in breathing.

Ingestion: Ingestion of this product may cause nausea, vomiting and diarrhoea.

Fire-fighting measures

General fire hazards:Not availalbe.

Extinguishing media

Suitable extinguishing media

Dry chemica, CO2, water spray or regular foam.

Unsuitable extinguishing media

Do not use a solid water stream as it may scatter and spread fire.

Special hazards arising from the substance or mixture

Fire may produce irritating, corrosive and/or toxic gases.

Advice for firefighters

Special protective equipment for firefighters:

Wear full protective clothing, including helmet, self-contained positive pressure or pressure demand breathing apparatus, protective clothing and face mask.

Special firefighting procedures:

Fight fire from maximum distance or use unmanned hose holders or monitor nozzles.

Accidental release measures

Personal precautions, protective equipment and emergency procedures

For non-emergency personnel:  Do not touch or walk through spilled material.

For emergency responders: Keep unnecessary personell away.  Do not touch damaged containers or spilled materials unless wearing approprite protective clothing.  Ventilate closed spaces before entering.  Keep upwind of the spilled material and isolate exposure.

Environmental precautions

Prevent entry into waterways, sewers, basements or confined areas.  Do not flush into surface water or sanitary sewer system.

Methods and material for containment and cleaning up

Stop the flow of material, if this is without risk.  Prevent entry into waterways, sewers, basements or confined areas.  Clean up in accordance with all applicable regulations.

Handling and storage

Precautions for safe handling

Avoid contact with skin and eyes.  Do not empty into drains.  Follow all SDS/label precautions even after continer is emptied because they may retain product residues.

Conditions for safe storage, including any incompatibilities

Store in corrosive resistant container with a resistant inliner.

Specific end use(s): Not availalbe.

Transport information

Land transport (UN RTDG/ADR/RID)

UN number:

UN3265

Shipping information

Proper shipping name and description:

Corrosive liquid, acidic, organic, n.o.s.

Chemical name:

CYCLOHEXANE, OXIDIZED, AQ. EXT.

Language:

English

Labels:

8

SpecialProvisions

Inland waterway transport (UN RTDG/ADN(R))

UN number:

UN3265

Shipping information

Proper shipping name and description:

Corrosive Liquid, Organic, N.o.s.

Chemical name:

CYCLOHEXANE, OXIDIZED, AQ. EXT.

Language:

English

Labels:

8

Special provisions / remarks

Remarks:

Special precautions for user: Not available.

Marine transport (UN RTDG/IMDG)

UN number:

UN3265

Shipping information

Proper shipping name and description:

Corroive liquid, acidic, organic, n.o.s

Chemical name:

CYCLOHEXANE, OXIDIZED, AQ. EXT

Labels:

8

Special provisions / remarks

Remarks:

Special precautions for user: Not available.
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
No information availalbe.

Air transport (UN RTDG/ICAO/IATA)

UN number:

UN3265

Shipping information

Proper shipping name and description:

Corrosive liquid, acidic, organic, n.o.s

Chemical name:

CYCLOHEXANE, OXIDIZED, AQ. EXT.

Labels:

8

Special provisions / remarks

Remarks:

Special precautions for user: Not availalbe.

SpecialProvisions

Exposure controls / personal protection

Control parameters

Occupational exposure limits: No exposure limits noted for the ingredient(s).

Biological limit values: No biological exposure limits noted for the ingredient(s).

Recommended monitoring procedures: Not availalbe.

Dermal DNEL for acute systemic effects: 38mg/kg bw/day.

Inhalation DNEL for acute system effects: 264 mg/m3.

Dermal DNEL for acute local effects: No-threshold.

Inhalation DNEL for acute local efects: 2mg/m3.

Dermal DNEL for long term local effects: No-threshold.

Inhalation DNEL for long term local effects: 1 mg/m3.

Dermal DNEL for long term systemic effects: 38 mg/kg bw/day.

Inhalation DNEL for long term systemic effects: 264 mg/kg bw/day.

Exposure controls

Appropriate engineering controls: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels.

Individual protection measures, such as personal protective equipment

General information: Wear suitable protective equipment.

Eye/face protection: Wear chemical goggles and face shild.

Skin protection: Hand protection chemical resistant gloves.  Thickness: 0.5 mm. Permeation rate: >480 min.

Request information on glove permeation properties from the glove supplier.

Other: Where contact is likely, wear chemical-resistant gloves, a chemical suit, rubber boots, and chemical safety goggles plus a face shild.

Respiratory protection: Respirator with combination filter for vapour/particulate (EN 141).

Thermal hazards: When material is heated, wear glovbes to protect against thermal burns.

Hygiene measures: Avoid contact with the skin and the eyes.  When using, do not eat, drink or smoke.  Wash hands before breaks and immediately after handling the product.  Launder contaminated clothing before reuse.

Environmental exposure controls: Contain spills and prevent releases and observe national regulations on emissions.

Stability and reactivity

Reactivity: Not availalble.

Chemical stability: Stable at normal conditions.

Possibility of hazardou reactions: Not expected to occur.

Conditions to avoid: Not available.

Incompatible materials: May be corrosive to metals.  Strong acids, alkalies and oxidizing agents.  Amines.

Hazardous decomposition products: Not available.

Disposal considerations

Waste treatment methods

Residual waste: Empty containers or liners may retain some product residues.  This material and its container must be disposed of in a safe manner (see: Disposal instructions).

Contaminated packaging: Do not re-use empty containers.  Empty containers shoudl be taken to an approved waste handling site for recycling or disposal.

EU waste code: Waste codes should be assigned by the user based on the application for which the product was used.

Disposal methods/information: Dispose in accordance with all applicable regulations.  Do not allow this material to drain into sewers/water supplies.  Do not contaminate ponds, waterways or ditches with chemical or used container.