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Reference
Endpoint:
relative self-ignition temperature (solids)
Type of information:
experimental study
Adequacy of study:
key study
Study period:
from 2020-12-16 to 2020-12-17
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Reason / purpose for cross-reference:
reference to same study
Qualifier:
according to guideline
Guideline:
other: VDI guideline 2263, Part 1, 1990: Test Methods for the Determination of the Safety Characteristic of Dusts, 1.4.1 Test according to Grewer
Version / remarks:
1990
Deviations:
no
GLP compliance:
yes (incl. QA statement)
Key result
Remarks on result:
no self ignition observed under the test conditions

In the investigation of self-ignition in the Grewer Oven for the pure test item an endothermic effect was detected in the temperature range of approx. 230 – 260 °C. No exothermic process was detected up to the test end temperature of approx. 410 °C. A black residue remained in the wire basket after the test.


For the test item in mixture with Kieselguhr an exothermic effect was observed starting at a temperature of 245 °C, which led to a maximum temperature of approx. 535 °C (approx. 200 °C above the corresponding temperature of the reference material). A grey residue remained in the wire basket after the test.





















Experiment



Onset self- ignition / °C



Maximum temperature / °C



Pure test item



-



-



Test item in mixture with Kieselguhr (1:1)



245



535



The pure test item indicated no self-ignition at atmospheric pressure.

Conclusions:
The test item indicated no self-ignition up to approximately 410 °C.
Executive summary:

A study was conducted to determine the self-ignition of the test item according to VDI 2263 Sheet 1 Grewer Oven (1990). In the investigation of self-ignition in the Grewer Oven for the pure test item an endothermic effect was detected in the temperature range of approx. 230 – 260 °C. No exothermic process was detected up to the test end temperature of approx. 410 °C. A black residue remained in the wire basket after the test. The pure test item indicated no self-ignition at atmospheric pressure.

Description of key information

The test item indicated no self-ignition up to approximately 410 °C (reference 4.12-1).

Key value for chemical safety assessment

Additional information

A study was conducted to determine the self-ignition of the test item according to VDI 2263 Sheet 1 Grewer Oven (1990). In the investigation of self-ignition in the Grewer Oven for the pure test item an endothermic effect was detected in the temperature range of approx. 230 – 260 °C. No exothermic process was detected up to the test end temperature of approx. 410 °C. A black residue remained in the wire basket after the test. The pure test item indicated no self-ignition at atmospheric pressure.