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Diss Factsheets

Environmental fate & pathways

Additional information on environmental fate and behaviour

Currently viewing:

Administrative data

Endpoint:
additional information on environmental fate and behaviour
Type of information:
experimental study
Adequacy of study:
key study
Study period:
2022
Reliability:
1 (reliable without restriction)

Data source

Reference
Reference Type:
study report
Title:
Unnamed
Year:
2022
Report date:
2022

Materials and methods

Test guideline
Qualifier:
according to guideline
Guideline:
other: OECD 29 Guidance Document on Transformation/Dissolution of Metals and Metal Compounds in Aqueous Media.
Version / remarks:
July 2001
GLP compliance:
yes

Test material

Constituent 1
Chemical structure
Reference substance name:
Tellurium dioxide
EC Number:
231-193-1
EC Name:
Tellurium dioxide
Cas Number:
7446-07-3
Molecular formula:
O2Te
IUPAC Name:
tellurium dioxide
Constituent 2
Reference substance name:
oxotellan oxide
IUPAC Name:
oxotellan oxide
Test material form:
solid: particulate/powder
Details on test material:
- Name of test material (as cited in study report): Tellurium dioxide
- Substance type: inorganic

Referenceopen allclose all

Constituent 1
Reference substance name:
Disodium tetraoxotellurate
EC Number:
233-259-5
EC Name:
Disodium tetraoxotellurate
Cas Number:
10101-83-4
Molecular formula:
Na2TeO4
IUPAC Name:
disodium tetraoxotellurate
Test material form:
solid
Constituent 1
Chemical structure
Reference substance name:
sodium tellurite
Cas Number:
10102-20-2
Molecular formula:
Na2O3Te
IUPAC Name:
sodium tellurite
Specific details on test material used for the study:
sodium tellurate (VI) and sodium tellurite (IV) have been used as standards to identify dissolved tellurium species

Results and discussion

Any other information on results incl. tables

For the test at nominal pH 6 at a loading of 100 mg/L Tellurium dioxide, average dissolved concentrations of:
• 0.383 ± 0.125 mg/L Tetotal (CVoverall = 33 %; N = 9),
• 0.389 ± 0.129 mg/L Te(IV) (CVoverall = 33 %; N = 9),
• <0.002 mg/L Te(VI) (N = 9),
were found at the 24 hours endpoint.
Based on the tellurium content in the test item and the average dissolved concentrations in the test solutions:
• a release of tellurium of 0.48 % of the content,
• a release of tellurium(IV) of 0.49 % of the content,
• a release of tellurium(VI) of <0.003 % of the content,
could be calculated at the 24 hours endpoint in test medium at pH 6.
For the test at nominal pH 8 at a loading of 100 mg/L Tellurium dioxide, average dissolved concentrations of:


• 1.80 ± 0.23 mg/L Tetotal (CVoverall = 13 %; N = 9),
• 1.79 ± 0.24 mg/L Te(IV) (CVoverall = 13 %; N = 9),
• 0.002 ± 0.001 mg/L Te(VI) (CVoverall = 24 %; N = 9),
were found at the 24 hours endpoint.
Based on the tellurium content in the test item and the average dissolved concentrations in the test solutions:
• a release of tellurium of 2.3 % of the content,
• a release of tellurium(IV) of 2.2 % of the content,
• a release of tellurium(VI) of 0.003 % of the content,
could be calculated at the 24 hours endpoint in test medium at pH 8.

Applicant's summary and conclusion

Conclusions:
During this study on Tellurium dioxide at a loading of 100 mg/L, it was shown that:
• For total tellurium, an average concentration of 0.383 mg/L Tetotal (CVoverall = 33 %; N = 9) was measured at pH 6 (i.e. 0.48 % total tellurium release) and 1.80 mg/L Tetotal (CVoverall = 13 %; N = 9) at pH 8 (i.e. 2.3 % total tellurium release),
• For tellurium(IV), an average concentration of 0.389 mg/L Te(IV) (CVoverall = 33 %; N = 9) was measured at pH 6 (i.e. 0.49 % tellurium(IV) release) and 1.79 mg/L Te(IV) (CVoverall = 13 %; N = 9) at pH 8 (i.e. 2.2 % tellurium(IV) release),
• For tellurium(VI), an average concentration of <0.002 mg/L Te(VI) (N = 9) was measured at pH 6 (i.e. <0.003 % tellurium(VI) release) and 0.002 mg/L Te(VI) (CVoverall = 24 %; N = 9) at pH 8 (i.e. 0.003 % tellurium(VI) release),
after 24 hours of exposure to the test medium at pH 6 and 8, respectively.
Based on the rounded results of the dissolved element concentrations, we may conclude that nominal “pH 8” is the pH where the highest dissolved tellurium concentrations, available as Te(IV), were measured. Only traces of Te(VI) could be detected.