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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Administrative data

Endpoint:
auto-ignition temperature (liquids)
Type of information:
experimental study
Adequacy of study:
key study
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study

Data source

Reference
Reference Type:
study report
Title:
Unnamed
Year:
2013
Report date:
2013

Materials and methods

Test guideline
Qualifier:
according to guideline
Guideline:
EU Method A.15 (Auto-Ignition Temperature (Liquids and Gases))
Version / remarks:
EN 14522
Principles of method if other than guideline:
EN 14522
GLP compliance:
yes (incl. QA statement)

Test material

Constituent 1
Chemical structure
Reference substance name:
Chlorodiphenylphosphine
EC Number:
214-093-2
EC Name:
Chlorodiphenylphosphine
Cas Number:
1079-66-9
Molecular formula:
C12H10ClP
IUPAC Name:
diphenylphosphinous chloride
Test material form:
liquid

Results and discussion

Auto-ignition temperature (liquids / gases)
Key result
Auto-ignition temperature:
250 °C
Atm. press.:
1 013.25 hPa
Remarks on result:
other: Correction performed according to EN 14522.

Any other information on results incl. tables

Results:
Test run no. lowest ternperature
[°C]
quantity of sample
[ml]
 ignition delay time
[s]
1 st test series 349 0.04  5
2 nd test series 301 0.04 1
3 rd test series 254 0.08 1
4 th test series 289 0.04  1
5 th test series 314 0.08  1

The tests were performed at an atmospheric pressure of 1001 mbar - 1018 mbar.

From these test runs a corrected* auto-ignition-temperature of 250 °C results.

* Correction performed according to EN 14522.

Remarks

The sample was handled under nitrogen during the test series.

Applicant's summary and conclusion

Conclusions:
The auto-ignition temperature of the substance is 250 °C at 1013.25 hPa.
Executive summary:

The auto-ignition temperature of the substance is 250 °C at 1013.25 hPa.