Registration Dossier

Guidance on Safe Use

Guidance on Safe Use

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Administrative data

First-aid measures

· After inhalation Supply fresh air; consult doctor in case of symptoms.
· After skin contact
Immediately wash with water and soap and rinse thoroughly.
If skin irritation continues, consult a doctor.
· After eye contact
Rinse opened eye for several minutes under running water. If symptoms persist, consult doctor.
· After swallowing In case of persistent symptoms consult doctor.

Fire-fighting measures

· Suitable extinguishing agents
Product itself it does not burn, extinguishing measures to suit surroundings.
· Special hazards caused by the material, its products of combustion or resulting gases:
Can be released in case of fire :
hydrogen fluoride
· Protective equipment: Do not inhale explosion gases or combustion gases.

Accidental release measures

· Person-related safety precautions: Wear protective clothing.
· Measures for environmental protection: avoid further disposal
· Measures for cleaning/collecting: Dispose of contaminated material as waste according to item 13. Ensure adequate ventilation. Wear protective clothes

Handling and storage

Handling
· Information for safe handling: Ventilation and acid resistant equipment required
· Information about protection against explosions and fires: No special measures required.
· Storage
· Requirements to be met by storerooms and containers: No special requirements.
· Information about storage in one common storage facility: Not required.
· Further information about storage conditions:
Keep container tightly sealed.
Storage: ventilated, cool and dry

Transport information

Land transport (ADR/RID)

UN number:
2923 CORROSIVE SOLID, TOXIC, N.O.S. (TIN DIFLUORIDE)
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Class:
8(6.1)
Classification code:
CT2
Packaging group:
III
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Marine transport (IMDG)

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Air transport ICAO/IATA

UN number:
2923
Proper shipping name and description:
corrosive solid, toxic, n.o.s. (Tin difluoride)
Chemical name:
tin difluoride
Class:
8(6.1)
Packaging group:
III
Labels:
8, 6.1
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Exposure controls / personal protection

Occupational exposure controls
The Personal Protective Equipment must be in accordance with EN standards:respirator EN 136, 140, 149; safety glasses EN 166; protective suit: EN 340, 463, 468, 943-1, 943-2; gloves EN 374, safety shoes EN-ISO 20345.
Do not breathe dust.
Wash hands before breaks and at the end of workday.
Take off all contaminated clothing immediately.

Environmental exposure controls
Handle in accordance with local environmental regulations and good industrial practices.

Engineering measures
Use with local exhaust ventilation.
acid resisting floor
Emergency sprinkling nozzle

Personal protective equipment:
Respiratory protection:
Remarks: In the case of dust or aerosol formation use respirator with an approved filter.
Hand protection:
Glove material: Natural Latex
Break through time: > 480 min
Glove thickness: 0,6 mm
Lapren®706
Gloves must be inspected prior to use.
Replace when worn.
Safety glasses with side-shields
Skin and body protection:
Protective suit

Stability and reactivity

Reactivity
no data available

Chemical stability

Thermal sensitivity: No decomposition if used as directed.

Possibility of hazardous reactions
Hazardous decomposition products formed under fire conditions.
Decomposes when moist.

Conditions to avoid
Protect from atmospheric moisture and water.
Protect from exposure to air/oxygen.

Incompatible materials
Incompatible with oxidizing agents.

Hazardous decomposition products
Hydrogen fluoride under influence of strong acids/fire
No decomposition if stored normally.

Disposal considerations

Waste treatment methods

Product:
Dispose according to legal requirements.

Packaging:
Legal requirements are to be considered in regard of reuse or disposal of used packaging materials

Further information:
Provisions relating to waste:
EC Directive 2006/12/EC; 2008/98/EEC
Regulation No. 1013/2006