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Physical & Chemical properties

Vapour pressure

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Reference
Endpoint:
vapour pressure
Type of information:
experimental study
Adequacy of study:
key study
Study period:
June 1997
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
other: Well conducted GLP study according to EU guideline.
Qualifier:
according to guideline
Guideline:
EU Method A.4 (Vapour Pressure)
GLP compliance:
yes (incl. QA statement)
Type of method:
effusion method: vapour pressure balance
Temp.:
25 °C
Vapour pressure:
4.1 Pa
Transition / decomposition:
no

A plot of Log10(vapour pressure (Pa)) versus reciprocal temperature (1/T(K)) gives the following statistical data using an unweighted least squares treatment. See attachment.

Slope                                 -6710.907

 

Standard deviation in slope 1659.746

 

Intercept                               23.117

 

Standard deviation in intercept 5.565

The results obtained indicate the following vapour pressure relationship.

Log10(Vp(Pa)) =-6710.907 / temp(K)+ 23.117.

The above yields a vapour pressure (Pa) at 298.15 K with a common logarithm of 0.608 which is equivalent to a vapour pressure of 4.1 Pa.

Conclusions:
The vapour pressure of 3,6,9-Triethyl-3,6,9-trimethyl-1,4,7-triperoxonane in 55% Petroleum distillates is 4.1 Pa at 25°C.
Executive summary:

The vapour pressure of the product is measured. So it is not determined if the vapour pressure is caused by 3,6,9-Triethyl-3,6,9-trimethyl-1,4,7-triperoxonane or Petroleum distillates or both.

The vapour pressure of 3,6,9-Triethyl-3,6,9-trimethyl-1,4,7-triperoxonane in 55% Petroleum distillates is 4.1 Pa at 25°C.

Description of key information

The vapour pressure of 3,6,9-Triethyl-3,6,9-trimethyl-1,4,7-triperoxonane  in 55% Petroleum distillates is 4.1 Pa at 25°C.

Key value for chemical safety assessment

Vapour pressure:
4.1 Pa
at the temperature of:
25 °C

Additional information

The vapour pressure of the product is measured. So it is not determined if the vapour pressure is caused by 3,6,9-Triethyl-3,6,9-trimethyl-1,4,7-triperoxonane or Petroleum distillates or both.