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Physical & Chemical properties

Auto flammability

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Reference
Endpoint:
auto-ignition temperature (liquids)
Type of information:
experimental study
Adequacy of study:
key study
Study period:
2021-04-19 - 2021-05-04
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Qualifier:
according to guideline
Guideline:
EU Method A.15 (Auto-Ignition Temperature (Liquids and Gases))
Version / remarks:
European Commission Regulation (EC) No. 440/2008
Deviations:
no
GLP compliance:
no
Key result
Auto-ignition temperature:
240 °C
Atm. press.:
1 014.7 hPa

Preliminary test


The following table shows the results of the preliminary test. Temperatures where auto-ignition was detected are marked with +; temperatures where no auto-ignition was detected are marked with – in the table below. The amount of test item tested at each measurement is indicated as numbers of portions (i.e. drops). The results are summarized in Table 1.


 


Table 1: Auto-ignition temperature (preliminary test) at 1014.7 hPa
















































T / °C



portions



+ / -



Time lag / s



203



5



-



-



253



5



-



-



303



5



+



5



273



5



+



22



263



5



+



38



258



5



+



70



 


The lowest auto-ignition temperature of the test item was determined to be 258 °C in the preliminary test.


 


Main test


The following tables show the results of the main tests. Temperatures where auto-ignition was detected are marked with +; temperatures where no auto-ignition was detected are marked with – in the tables below. The amount of test item tested at each measurement is indicated as numbers of portions (i.e. drops). The results of the main test are compiled in Table 2.


 


Table 2: Auto-ignition temperature (summary).































Main test series



Auto-ignition temperature / °C



Time lag /s



1st main test (5 K)



248



150



1st main test (2 K)



244



200



2nd main test (2 K)



244



255



3rd main test (2 K)



244



255



 


The lowest auto-ignition temperature of the test item was determined to be 244 °C in the main test. Due to safety reasons and according to the guidelines the lowest measured temperature at which an ignition was observed was rounded to the next lower number divisible by 5, giving a value of 240 °C.

Conclusions:
The auto-ignition temperature of the test item was determined to be 240 °C.
Executive summary:

The auto-ignition temperature was measured according to the testing guideline for auto-igition test conditions in the sense of the European Commission Regulation (EC) No.440/2008, Method A.15. The lowest auto-ignition temperature of the test item was determined to be 244 °C in the main test. Due to safety reasons and according to the guidelines the lowest measured temperature at which an ignition was observed was rounded to the next lower number divisible by 5, giving a value of 240 °C.

Description of key information

The auto-ignition temperature of the test item was determined to be 240 °C (reference 4.12-1).

Key value for chemical safety assessment

Autoflammability / Self-ignition temperature at 101 325 Pa:
240 °C

Additional information

The auto-ignition temperature was measured according to the testing guideline for auto-igition test conditions in the sense of the European Commission Regulation (EC) No.440/2008, Method A.15. The lowest auto-ignition temperature of the test item was determined to be 244 °C in the main test. Due to safety reasons and according to the guidelines the lowest measured temperature at which an ignition was observed was rounded to the next lower number divisible by 5, giving a value of 240 °C.