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EC number: 213-316-0 | CAS number: 936-52-7
- Life Cycle description
- Uses advised against
- Endpoint summary
- Appearance / physical state / colour
- Melting point / freezing point
- Boiling point
- Density
- Particle size distribution (Granulometry)
- Vapour pressure
- Partition coefficient
- Water solubility
- Solubility in organic solvents / fat solubility
- Surface tension
- Flash point
- Auto flammability
- Flammability
- Explosiveness
- Oxidising properties
- Oxidation reduction potential
- Stability in organic solvents and identity of relevant degradation products
- Storage stability and reactivity towards container material
- Stability: thermal, sunlight, metals
- pH
- Dissociation constant
- Viscosity
- Additional physico-chemical information
- Additional physico-chemical properties of nanomaterials
- Nanomaterial agglomeration / aggregation
- Nanomaterial crystalline phase
- Nanomaterial crystallite and grain size
- Nanomaterial aspect ratio / shape
- Nanomaterial specific surface area
- Nanomaterial Zeta potential
- Nanomaterial surface chemistry
- Nanomaterial dustiness
- Nanomaterial porosity
- Nanomaterial pour density
- Nanomaterial photocatalytic activity
- Nanomaterial radical formation potential
- Nanomaterial catalytic activity
- Endpoint summary
- Stability
- Biodegradation
- Bioaccumulation
- Transport and distribution
- Environmental data
- Additional information on environmental fate and behaviour
- Ecotoxicological Summary
- Aquatic toxicity
- Endpoint summary
- Short-term toxicity to fish
- Long-term toxicity to fish
- Short-term toxicity to aquatic invertebrates
- Long-term toxicity to aquatic invertebrates
- Toxicity to aquatic algae and cyanobacteria
- Toxicity to aquatic plants other than algae
- Toxicity to microorganisms
- Endocrine disrupter testing in aquatic vertebrates – in vivo
- Toxicity to other aquatic organisms
- Sediment toxicity
- Terrestrial toxicity
- Biological effects monitoring
- Biotransformation and kinetics
- Additional ecotoxological information
- Toxicological Summary
- Toxicokinetics, metabolism and distribution
- Acute Toxicity
- Irritation / corrosion
- Sensitisation
- Repeated dose toxicity
- Genetic toxicity
- Carcinogenicity
- Toxicity to reproduction
- Specific investigations
- Exposure related observations in humans
- Toxic effects on livestock and pets
- Additional toxicological data
Administrative data
First-aid measures
1. Description of first aid measures
General notes
Do not leave affected person unattended. Remove victim out of the danger area. Keep affected person warm, still and covered.
Take off immediately all contaminated clothing. In all cases of doubt, or when symptoms persist, seek medical advice. In case
of unconsciousness place person in the recovery position. Never give anything by mouth.
Following inhalation
If breathing is irregular or stopped, immediately seek medical assistance and start first aid actions. In case of respiratory tract irritation,
consult a physician. Provide fresh air.
Following skin contact
Wash with plenty of soap and water.
Following eye contact
Remove contact lenses, if present and easy to do. Continue rinsing. Irrigate copiously with clean, fresh water for at least 10
minutes, holding the eyelids apart.
Following ingestion
Rinse mouth with water (only if the person is conscious). Do NOT induce vomiting.
2. Most important symptoms and effects, both acute and delayed
Symptoms and effects are not known to date.
3. Indication of any immediate medical attention and special treatment needed
none
Fire-fighting measures
1. Extinguishing media
Suitable extinguishing media
Water spray, Foam, Dry extinguishing powder, Carbon dioxide (CO2)
Unsuitable extinguishing media
Water jet
2. Special hazards arising from the substance or mixture
The exposure of containers to heat leads to an increase in pressure with a risk of bursting and subsequent explosion. Develops
corrosive and irritant vapours. May form explosive mixtures with air at elevated ambient temperatures. May
be corrosive to metals-> Formation of Hydrogen ->may form an explosive mixture with air. The vapours may be invisible and
are heavier than air. They spread on the ground and can intrude into sewers and cellars.
Hazardous combustion products
Carbon monoxide (CO), Carbon dioxide (CO2), Nitrous gases
3. Advice for firefighters
Keep containers cool with water spray. In case of fire and/or explosion do not breathe fumes. Co-ordinate firefighting measures
to the fire surroundings. Do not allow firefighting water to enter drains or water courses. Collect contaminated firefighting water
separately. Fight fire with normal precautions from a reasonable distance. Precipitate combustion gases with water spray if possible.
Wear self-contained breathing apparatus.
Accidental release measures
1. Personal precautions, protective equipment and emergency procedures
For non-emergency personnel
Remove persons to safety.
For emergency responders
Wear breathing apparatus if exposed to vapours/dust/spray/gases.
2. Environmental precautions
Keep away from drains, surface and ground water. Retain contaminated washing water and dispose of it.
3. Methods and material for containment and cleaning up
Advice on how to contain a spill
Covering of drains
Advice on how to clean up a spill
Wipe up with absorbent material (e.g. cloth, fleece). Collect spillage: sawdust, kieselgur (diatomite), sand, universal binder
Appropriate containment techniques
Use of adsorbent materials.
Other information relating to spills and releases
Place in appropriate containers for disposal. Ventilate affected area.
4. Reference to other sections: Hazardous combustion products: see section "Firefighting measures". Personal protective equipment: see section "Exposure controls/personal protection". Incompatible materials: see section "Stability and reactivity". Disposal considerations: see section "Disposal considerations"
Handling and storage
This substance is handled under Strictly Controlled Conditions in accordance with REACH regulation Article 18(4) for transported isolated intermediates. Site documentation to support safe handling arrangements including the selection of engineering, administrative and personal protective equipment controls in accordance with risk-based management systems is available at each Manufacturing site. Written confirmation of application of Strictly Controlled Conditions has been received from affected Distributor and Downstream Manufacturer/User of the Registrant's intermediate.
1. Precautions for safe handling
Recommendations
- measures to prevent fire as well as aerosol and dust generation
Use local and general ventilation. Avoidance of ignition sources. Keep away from sources of ignition - No smoking. Take precautionary
measures against static discharge. Use only in well-ventilated areas. Due to danger of explosion, prevent leakage of
vapours into cellars, flues and ditches. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/
lighting/equipment. Use only non-sparking tools.
- specific notes/details
Places which are not ventilated, e.g. unventilated below ground level areas such as trenches, conduits and shafts, are particularly
prone to the presence of flammable substances or mixtures. Vapours are heavier than air, spread along floors and form explosive
mixtures with air. Vapours may form explosive mixtures with air.
Advice on general occupational hygiene
Wash hands after use. Do not eat, drink and smoke in work areas. Remove contaminated clothing and protective equipment before
entering eating areas. Never keep food or drink in the vicinity of chemicals. Never place chemicals in containers that are
normally used for food or drink. Keep away from food, drink and animal feedingstuffs.
2. Conditions for safe storage, including any incompatibilities
Managing of associated risks
- explosive atmospheres
Keep container tightly closed and in a well-ventilated place. Use local and general ventilation. Keep cool. Protect from sunlight.
- flammability hazards
Keep away from sources of ignition - No smoking. Keep away from heat, hot surfaces, sparks, open flames and other ignition
sources. No smoking. Take precautionary measures against static discharge. Protect from sunlight.
- incompatible substances or mixtures
Protect from moisture.
- ventilation requirements
Use local and general ventilation. Ground/bond container and receiving equipment.
- packaging compatibilities
Only packagings which are approved (e.g. acc. to ADR) may be used.
3. Specific end use(s)
No information available.
Transport information
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Marine transport (UN RTDG/IMDG)
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Exposure controls / personal protection
This substance is handled under Strictly Controlled Conditions in accordance with REACH regulation Article 18(4) for transported isolated intermediates. Site documentation to support safe handling arrangements including the selection of engineering, administrative and personal protective equipment controls in accordance with risk-based management systems is available at each Manufacturing site. Written confirmation of application of Strictly Controlled Conditions has been received from affected Distributor and Downstream Manufacturer/User of the Registrant's intermediate.
1. Control Parameters
Control parameters, national occupational exposure limit values (workplace exposure limits) as well as information on control parameters of possible hydrolysis products, impurities and/or additives hydrolysis products are provided in the safety data sheet.
2. Exposure controls
Appropriate engineering controls
Local and general ventilation.
Individual protection measures (personal protective equipment)
Eye/face protection
Splash goggles.
Skin protection
- hand protection
Wear suitable gloves. Chemical protection gloves are suitable, which are tested according to EN 374. Check leak-tightness/impermeability
prior to use. In the case of wanting to use the gloves again, clean them before taking off and air them well. For special
purposes, it is recommended to check the resistance to chemicals of the protective gloves mentioned above together with
the supplier of these gloves.
- type of material NBR: acrylonitrile-butadiene rubber
- material thickness 0,38 mm (splash protection)
- breakthrough times of the glove material >30 minutes (permeation: level 2) (splash protection)
- other protection measures
For special purposes, it is recommended to check the resistance to chemicals of the protective gloves mentioned above together
with the supplier of these gloves. In the case of wanting to use the gloves again, clean them before taking off and air them
well.
Take recovery periods for skin regeneration. Preventive skin protection (barrier creams/ointments) is recommended. Wash
hands thoroughly after handling. Protective clothing against liquid chemicals. Footwear protecting against chemicals.
Respiratory protection
In case of inadequate ventilation wear respiratory protection.
Environmental exposure controls
Use appropriate container to avoid environmental contamination. Keep away from drains, surface and ground water.
Stability and reactivity
1. Reactivity
Concerning incompatibility: see below "Conditions to avoid" and "Incompatible materials". The mixture contains reactive substance(s). Risk of ignition.
If heated:
Risk of ignition
2. Chemical stability
See below "Conditions to avoid".
3. Possibility of hazardous reactions
Acids, Bases, Oxidiser -> Heat
4. Conditions to avoid
Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Protect from moisture.
Hints to prevent fire or explosion
Use explosion-proof electrical/ventilating/lighting/equipment. Use only non-sparking tools. Take precautionary measures
against static discharge.
5. Incompatible materials
Acids, Bases, Oxidisers
6. Hazardous decomposition products
Hazardous combustion products: see section "firefighting measures".
Disposal considerations
Waste treatment methods
Waste treatment-relevant information
Dispose of contents/container in accordance with local/regional/national/international regulations.
Sewage disposal-relevant information
Do not empty into drains. Avoid release to the environment. Refer to special instructions/safety data sheets.
Waste treatment of containers/packagings
It is a dangerous waste; only packagings which are approved (e.g. acc. to ADR) may be used. Completely emptied packages
can be recycled. Handle contaminated packages in the same way as the substance itself.
Remarks
Please consider the relevant national or regional provisions. Waste shall be separated into the categories that can be handled
separately by the local or national waste management facilities.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.