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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Environmental fate & pathways

Endpoint summary

Administrative data

Description of key information

Additional information

The multiconstituent substance is a reaction mass of inorganic an organic acids. The substance itself constains considerable amounts of water (46.2%) that cannot be removed without changing the identity of the substance itself. The constituent sulfuric acid has a strong affinity to water. Therefore it is very difficult to concentrate sulfuric acid. The system water/sulfuric acid is an azeotrope. If heating of the substance is enhanced to remove more water, it is to be expected that H2SO4 will be lost from the substance. Therefore it is not possible to reduce the water content to 20% without changing the composition. Furthermore we cannot exclude any decomposition reactions of the benzene sulfonic acids by high heat.

The substance is imported as aqueous solution. Since the substance is used in all cases as aqueous solution as imported, it was decided to use the aqueous solution for the tests necessary für the information requirements according to the tonnage band 1 - 10 t/a standard requirements (REACH Regulation) for the endpoint "Biodegradation: Annex VII; 9.2.1.1".

 

The first reason for this procedure is that the substance is only used as aqueous solution, so that the situation of the use of the substance is more realistic for the environment. The second reason is that it makes no sense to concentrate the aqueous solution of the substance prior the above mentioned tests in order to dissolve it again in water to perform the tests.

 

The ready biodegradation of the test substance was investigated in a study conducted according to OECD Guidelines for Testing of Chemicals No. 301A, “Ready Biodegradability; die away Test”, referenced as method C.4-A of Commission Directive 92/69/EEC, using predominantly domestic activated sludge microorganisms as inoculum. The biodegradation rate was determined by measurement of DOC consumption. This study is regarded as reliable without restriction and satisfies the guideline requirements for ready biodegradation. The test material attained <1% degradation after 28 days and proved not to be readily biodegradable under the stringent test conditions.