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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

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Diss Factsheets

Environmental fate & pathways

Hydrolysis

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Administrative data

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Reference
Endpoint:
hydrolysis
Data waiving:
study scientifically not necessary / other information available
Justification for data waiving:
other:

Description of key information

Hydrolysis (HEBMP-xNa): not hydrolytically unstable

Key value for chemical safety assessment

Additional information

The requirement to test the substance for hydrolysis was waived as the substance is not susceptible to hydrolytic degradation.

In solution, HEBMP-xNa undergoes a reversible internal condensation reaction to form a pH-dependent equilibrium mixture with the cyclised structure 4-(phosphonomethyl) -2-hydroxy-2-oxo-1,4,2-oxaza-phosphorinane (c-HEBMP) and water. The precise proportion of the two is dependent on pH, temperature, and time, and under acidic or neutral conditions, the proportion of c-HEBMP in the multi-constituent substance may reach proportions as high as 60% w/w.           

The acid and sodium salts in the HEBMP category are freely soluble in water. The HEBMP anion can be considered fully dissociated from its sodium cation when in dilute solution. Under any given conditions, the degree of ionisation of the HEBMP species is determined by the pH of the solution. At a specific pH, the degree of ionisation is the same regardless of whether the starting material was HEBMP-H, HEBMP-xNa, or another salt of HEBMP.

 

Therefore, when a salt of HEBMP is introduced into test media or the environment, the following is present (separately):

  1. HEBMP is present as HEBMP-H or one of its ionised forms. The degree of ionisation depends upon the pH of the mediaand not whether HEBMP-xNa salt, HEBMP-H (acid form), or another salt was used for dosing.
  2. Disassociated sodium cations. The amount of sodium present depends on which salt was added.
  3. It should also be noted that divalent and trivalent cations would preferentially replace the potassium ions. These would include calcium (Ca2+), magnesium (Mg2+) and iron (Fe3+).