Registration Dossier

Guidance on Safe Use

Guidance on Safe Use

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Administrative data

First-aid measures

Description of first aid measures

In case of inhalation: Move victim to fresh air. Seek medical treatment in case of troubles.
Following skin contact: Immediately wipe affected skin area with paper towel or cloth.
Immediately clean with water and soap followed by thorough rinsing.
In case of skin irritation, consult a physician.
After eye contact: Immediately flush eyes with plenty of flowing water for 10 to 15 minutes holding eyelids
apart. Subsequently consult an ophthalmologist.
After swallowing: Rinse mouth with water.
Never give an unconscious person anything through the mouth.
Consult physician immediately.

Most important symptoms and effects, both acute and delayed

May cause slight irritation to mucous membranes, skin and eyes.
Higher doses may have a narcotic effect.

Indication of any immediate medical attention and special treatment needed
Treat symptomatically.

Fire-fighting measures

Extinguishing media

Suitable extinguishing media::
Foam, extinguishing powder, carbon dioxide

Special hazards arising from the substance or mixture

Highly flammable liquid and vapour. With air, vapours form potentially explosive mixtures,
which are heavier than air. Vapours may proceed on the ground over great distances and
cause fire and backflashes.
In case of fire may be liberated: carbon monoxide and carbon dioxide.

Advice for firefighters

Special protective equipment for firefighters:
Wear self-contained positive pressure breathing apparatus and full firefighting protective
clothing.
Additional information: Hazchem-Code: •3YE
Heating will lead to pressure increase: Danger of bursting and explosion. Use fine water
spray to cool endangered containers.
Move undamaged containers from immediate hazard area if it can be done safely.
In case of major fire and large quantities: Evacuate area. Fight fire remotely due to the
risk of explosion.
Do not allow fire water to penetrate into surface or ground water.
Fire residuals and contaminated extinguishing water must be disposed of in accordance
with the regulations of the local authorities.

Accidental release measures

Personal precautions, protective equipment and emergency procedures

Do not breathe vapours. Avoid contact with the substance.
In case of leakage, eliminate all ignition sources. Provide adequate ventilation.
Wear appropriate protective equipment. Keep unprotected people away.
Cordon off downwind area at risk and warn inhabitants.

Environmental precautions

Do not allow to enter into ground-water, surface water or drains. Danger of explosion!
In case of release, notify competent authorities.

Methods and material for containment and cleaning up

Isolate leaked material using non-flammable absorption agent (e.g. sand, earth, vermiculit,
diatomaceous earth) and collect it for disposal in appropriate containers in accordance
with the local regulations (see section 13). Thoroughly clean surrounding area.
In case of greater quantities: Collect mechanically (use only explosion-proof equipment
when pumping out).
Vapours form potentially explosive mixtures with air. Heavier than air, they proceed at floor
level and may backflash over great distances when ignited.

Additional information: Use explosion-proof equipment and non-sparking tools/utensils.
Take precautionary measures against static discharges.

Handling and storage

Precautions for safe handling

Advices on safe handling: Provide adequate ventilation, and local exhaust as needed. Do not breathe vapours.
Avoid contact with skin and eyes. Wear appropriate protective equipment.
Guarantee sufficient ventilation during and after use, in order to prevent vapour
accumulation.
Precautions against fire and explosion:
Keep away from sources of ignition - No smoking.
Take precautionary measures against static discharges.
Use only explosion-protected equipment/instruments. Do not weld.
In partially filled containers explosive mixtures may form.

7.2 Conditions for safe storage, including any incompatibilities

Requirements for storerooms and containers:
Keep container tightly closed in a cool, well-ventilated place.
Keep away from heat sources, sparks and open flames.
Protect from humidity and water.
Store containers in upright position. Do not drop, drag or bang the container.
Handle empty containers with care. Incineration may cause explosion.
Do not re-use the empty container. Do not weld.
Keep out of the reach of children.

Transport information

Land transport (ADR/RID)

UN number:
1993
Proper shipping name and description:
FLAMMABLE LIQUID, N.O.S. (Dimethoxydimethylsilane)
Chemical name:
Dimethoxydimethylsilane
Class:
3
Packaging group:
II
Labels:
3
Remarks:
Warning board: ADR/RID: Kemmler-number 33, UN number UN 1993
Hazard label: 3
Special provisions: 274 601 640D
Limited quantities: 1 L
EQ: E2
Contaminated packaging - Instructions: P001 - IBC02 - R001
Special provisions for packing together: MP19
Portable tanks - Instructions: T7
Portable tanks - Special provisions: TP1 TP8 TP28
Tank coding: LGBF
Tunnel restriction code: D/E

Inland waterway transport (ADN(R))

UN number:
1993
Proper shipping name and description:
FLAMMABLE LIQUID, N.O.S. (Dimethoxydimethylsilane)
Chemical name:
Dimethoxydimethylsilane
Class:
3
Packaging group:
II
Remarksopen allclose all

Marine transport (IMDG)

UN number:
1993
Proper shipping name and description:
FLAMMABLE LIQUID, N.O.S. (Dimethoxydimethylsilane)
Chemical name:
Dimethoxydimethylsilane
Class:
3
Packaging group:
II
EmS code:
F-E, S-E
Remarks
EmS: F-E, S-E
Special provisions: 274
Limited quantities: 1 L
Excepted quantities: E2
Contaminated packaging - Instructions: P001
Contaminated packaging - Provisions: -
IBC - Instructions: IBC02
IBC - Provisions: -
Tank instructions - IMO: -
Tank instructions - UN: T7
Tank instructions - Provisions: TP1, TP8, TP28
Stowage and handling: Category B.
Properties and observations: -
Segregation group: none

Air transport ICAO/IATA

UN number:
1993
Proper shipping name and description:
FLAMMABLE LIQUID, N.O.S. (Dimethoxydimethylsilane)
Chemical name:
Dimethoxydimethylsilane
Class:
3
Packaging group:
II
Remarks
Hazard label: Flamm. liquid
Excepted Quantity Code: E2
Passenger and Cargo Aircraft: Ltd.Qty.: Pack.Instr. Y341 - Max. Net Qty/Pkg. 1 L
Passenger and Cargo Aircraft: Pack.Instr. 353 - Max. Net Qty/Pkg. 5 L
Cargo Aircraft only: Pack.Instr. 364 - Max. Net Qty/Pkg. 60 L
Special provisions: A3
Emergency Response Guide-Code (ERG): 3H
SpecialProvisionsopen allclose all

Exposure controls / personal protection

Exposure controls

Provide for good ventilation or exhaust system or work with completely self-contained
equipment. Explosion protection required.

Personal protection equipment
Occupational exposure controls
Respiratory protection: Respiratory protection must be worn whenever the WEL levels have been exceeded.
Half-mask with filter according to EN 149. The filter class must be suitable for the
maximum contaminant concentration (gas/vapour/aerosol/particulates) that may arise
when handling the product. If the concentration is exceeded, self-contained breathing
apparatus must be used.
Hand protection: Protective gloves according to EN 374.
Glove material:
Nitrile rubber. Layer thickness: 0,4 mm. Breakthrough time: >480 min.
Fluororubber (Viton). Layer thickness: 0,7 mm. Breakthrough time: >480 min.
Observe glove manufacturer's instructions concerning penetrability and breakthrough time.
Eye protection: Tightly sealed goggles according to EN 166.
Body protection: Flame-resistant antistatic protective clothing
General protection and hygiene measures:
Use non-sparking tools. Change contaminated clothing. Keep away from heat sources,
sparks and open flames. Do not breathe vapour. When using do not eat, drink or smoke.
Avoid contact with skin and eyes. Wash hands before breaks and after work. Gargle with
water. Work place should be equipped with a shower and an eye rinsing apparatus.

Stability and reactivity

10.1 Reactivity
Highly flammable liquid and vapour.
Vapours form explosive mixtures with air.
Water-reactive.
10.2 Chemical stability
Stable under recommended storage conditions.
10.3 Possibility of hazardous reactions
No hazardous reactions known.
Heating will lead to pressure increase: Danger of bursting and explosion.
10.4 Conditions to avoid
Protect from humidity and water.
Keep away from heat sources, sparks and open flames.
Protect against direct sunlight.
10.5 Incompatible materials
Water, acids, alkalis.
10.6 Hazardous decomposition products
Methanol.
Thermal breakdown of this product during fire or very high heat condition may evolve the
following hazardous decomposition products: silicon dioxide, traces of incompletely
burned carbon compounds, formaldehyde, carbon monoxide and carbon dioxide.
Thermal decomposition: No data available

Disposal considerations

Waste treatment methods
Product
Waste key number: 07 02 16* = Waste containing hazardous silicones
* = Evidence for disposal must be provided.
Recommendation: Incinerate as hazardous waste according to applicable local, state, and federal regulations.
Contaminated packaging
Waste key number: 15 01 04 = Metallic packaging
Recommendation: Dispose of waste according to applicable legislation.
Handle empty containers with care. Incineration may cause explosion.
Do not re-use the empty container.