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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

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Administrative data

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Description of key information

Key value for chemical safety assessment

Henry's law constant (H) (in Pa m³/mol):
0.014
at the temperature of:
20 °C

Additional information

Volatilisation of organic compounds from surface waters is generally estimated by the Henry’s law constant. The Henry’s law constant for the diamines C16-18 is calculated from the ratio of the vapour pressure (Pa) and the CMC (mol/m3) as determined at pH 7. The vapour pressure of N-C12-14-alkyldiamino propane (90640-43-0) of 0.0015 Pa is used for the calculation of the Henry’s law constant for all the three technical mixtures of diamines C16-18 as a worst-case.

 

Table 13b: Henry’s law constants for diamines C16-18 (Pa.m3/mol)

diamine

VP (Pa)

CMC (mg/L)

MW (g/mol)

H (Pa.m3/mol)

N-9-octa-decenyl-, (Z)-

propane-1,3-diamine

(7173-62-8)

0.0015

36

324.60 (C18=)

1.35 * 10-2

N-hydrogenatedC16-18-alkyl-(evennumbered)propane-1,3-diamine

(68603-64-5)

36

326.61 (C18)

1.36 * 10-2

 

Considering the low values, volatilisation at environmental conditions is expected to be negligible. For the model calculations, the highest value of 1.36 * 10-2 Pa.m3/mol is used as a worst-case.