Registration Dossier

Administrative data

First-aid measures

Move victim to fresh air. If unconscious, place in a safe position, do not give anything by mouth, and call a physician.
In case of doubts or if symptoms persist, consult a physician, showing him safety data sheet, container or label.
After inhalation: Remove to fresh air, if not breathing give artificial respiration, if breathing is difficult, give oxygen. Call a physician.
After contact with skin: Remove contaminated clothing and shoes. Immediately wash skin with soap and large amounts of water. (for example with safety shower). Call a physician.
After contact with eyes: Flush the eyes immediately with plenty of water for at least 15 minutes by separating eyelids with fingers (for example with the eye-wash station). Call a physician.
After ingestion: Wash out mouth with water provided that person is conscious. Call a physician.

Fire-fighting measures

Suitable extinguishing media: carbon dioxide, dry powders, foam
Unsuitable extinguishing media: water
Special hazards arising from the substance - dust with air may produce explosive mixture. In case of fire, toxic gases or fumes may form. In case of fire do not breath in emitting gases, undertake action to prevent electric charge formation.
The fire-fighters should use breathing apparatus with independent air circulation and with antichemical equipment. The clothes of the fire-fighting action participants should be heat-resistant.

Accidental release measures

Avoid contact with skin, eyes, breathing dust. Use personal protection. Ensure a suitable ventilation system. Protect from contact with ignition sources. Prevent disposal directly to the aqueous environment and soil. Sweep up material as much as possible and place it in a labelled disposal bag/container. After removal wash the contaminated place with plenty of water and ventilate.

Handling and storage

General rules of occupational safety and hygiene should be followed. Avoid breathing dust. Do not allow for a contact with eyes, skin, clothing. Avoid prolonged or repeated exposure. Ensure a suitable ventilation system. Protect from contact with ignition sources.
Wash hands carefully after the contact with the substance. Do not eat or drink or smoke in the workplace. Separate the working clothes from the normal clothes.
Store in closed, original containers, protect from water and light.
Protect from high temperature and strong oxidizing agents, strong bases, potassium, sodium, alcohols and metals.
Secure measures to avoid contact with humidity or water.
In the storage area do not eat nor drink, do not smoke, do not use open fire or sparkling equipment.

Transport information

Land transport (ADR/RID)

UN number:
2692
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Class:
8
Packaging group:
I
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Marine transport (IMDG)

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Exposure controls / personal protection

General rules of occupational safety and hygiene should be followed. All necessary technical means of precaution should be applied in order not to allow the product to spread in the environment. Wash hands carefully after the contact with the substance. Do not eat or drink or smoke in the work place.
Separate the working clothes from the normal clothes.
Personal protection measures have to be in compliance with requirements from the Directive 89/686/WE (with later corrigendum). Employer is obliged to ensure proper protection means adequate to the activities conducted by the employees and which meet the quality requirements, are maintained and cleaned.
Hands protection: safety gloves
Gloves material should be impermeable and resistant to the product. The selection of the material should be done basing on the data: breakthrough time, penetration rate and degradation. Moreover the selection of the proper gloves should take into account also the quality characteristics and the producer. The information about the breakthrough time should be received from the producer and followed by the users.
Skin protection: protective suit and boots.
Eye protection: safety goggles
Respiratory protection: gas mask with multi-gas absorber.

Stability and reactivity

Product is stabile provided that it is used and stored appropriately. Reacts with water violently. Protect from high temperature and strong oxidizing agents, strong bases, potassium, sodium, alcohols and metals. Secure measures to avoid contact with humidity or water.

Disposal considerations

Incineration - wastes formed at manufacturer/user site should be mixed with a combustible solvent and burnt in a chemical incinerator equipped with an afterburner and scrubber according to current site manufacturing/using regulations.
The release of substance to industrial sewerage system should be conducted in accordance with international, national, regional, state or local environmental control regulations and laws.
Packaging after product should be directed to the licensed disposal company.