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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Administrative data

Endpoint:
explosiveness
Type of information:
experimental study
Adequacy of study:
key study
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
other: Guideline study

Data source

Reference
Reference Type:
study report
Title:
Unnamed
Year:
2012
Report date:
2012

Materials and methods

Test guideline
Qualifier:
no guideline followed
Principles of method if other than guideline:
The thermal stability was determined by differential thermal analysis DSC.
GLP compliance:
no

Test material

Constituent 1
Chemical structure
Reference substance name:
(S)-pyrrolidine-2-carboxamide
EC Number:
231-397-0
EC Name:
(S)-pyrrolidine-2-carboxamide
Cas Number:
7531-52-4
Molecular formula:
C5H10N2O
IUPAC Name:
(S)-pyrrolidine-2-carboxamide

Results and discussion

Small-scale preliminary tests
Parameter:
other: Explosive under influence of flame
Remarks:
migrated information
Remarks on result:
negative (not further specified)

Any other information on results incl. tables

The DSC results (scan with 4 °C/min):

Thermal signal range (°C):

Endo: 81 – 114, 102; Engergy (kJ/kg): -176

Exo: 132 – 239, 188; Engergy (kJ/kg): 35

The determination of the thermal stability of the test substance by DSC (Differential Scanning Calorimetry) showed that between 30 °C and 400 °C the exothermal decomposition energy is about 35 kJ/kg and therefore below the limit of 500 kJ/kg for exclusion given in the Regulation (EC) No. 1272/2008 (CLP) of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures, Chapter 2.1.4.3.(c).

According to the chemical structure and the list of reactive groups that could have explosive properties (Bretherick´s Handbook of Reactive Chemical Hazards, Butterworths, 4thedition) it can be excluded that the test substance has explosive properties.

Applicant's summary and conclusion