Registration Dossier
Registration Dossier
Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.
The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.
Use of this information is subject to copyright laws and may require the permission of the owner of the information, as described in the ECHA Legal Notice.
EC number: 277-759-1 | CAS number: 74196-16-0
Oxidising properties
Administrative data
- Endpoint:
- oxidising solids
- Type of information:
- experimental study
- Adequacy of study:
- key study
- Reliability:
- 1 (reliable without restriction)
- Rationale for reliability incl. deficiencies:
- guideline study
- Remarks:
- according to UN Manual of Tests and Criteria, Rev. 6 (2015)
Data source
Reference
- Reference Type:
- study report
- Title:
- Unnamed
- Year:
- 2 017
- Report date:
- 2017
Materials and methods
Test guideline
- Qualifier:
- according to guideline
- Guideline:
- UN Manual of Tests and Criteria: Test O.1 (Test for oxidizing solids)
- Version / remarks:
- Rev. 6 (2015)
Test material
- Reference substance name:
- Trisodium bis[4-amino-3-[(2-hydroxy-3,5-dinitrophenyl)azo]naphthalene-1-sulphonato(3-)]chromate(3-)
- EC Number:
- 277-759-1
- EC Name:
- Trisodium bis[4-amino-3-[(2-hydroxy-3,5-dinitrophenyl)azo]naphthalene-1-sulphonato(3-)]chromate(3-)
- Cas Number:
- 74196-16-0
- Molecular formula:
- C32H16CrN10O16S2.3Na
- IUPAC Name:
- trisodium bis[4-amino-3-[(2-hydroxy-3,5-dinitrophenyl)azo]naphthalene-1-sulphonato(3-)]chromate(3-)
- Reference substance name:
- Sodium sulphate
- EC Number:
- 231-820-9
- EC Name:
- Sodium sulphate
- Cas Number:
- 7757-82-6
- Molecular formula:
- H2O4S.2Na
- IUPAC Name:
- disodium sulfate
Constituent 1
additive 1
Results and discussion
Test results (Oxidising solids)open allclose all
- Sample tested:
- 1:1 sample-to-cellulose ratio
- Parameter:
- mean burning time
- Result:
- > 180 s
- Sample tested:
- 4:1 sample-to-cellulose ratio
- Parameter:
- mean burning time
- Result:
- > 180 s
- Sample tested:
- reference: 3:7 mixture potassium bromate + cellulose
- Parameter:
- mean burning time
- Result:
- 115 s
Any other information on results incl. tables
The reference item potassium bromate (Alfa Aesar, lot 10191952, 99.7 %) contained a residual moisture of < 0.1 wt %, determined by drying the substance at 65°C until constant weight. The fraction from 150 µm to 300 µm obtained after sieving was used.
Cellulose powder (Technocel 75, lot G03001614) exhibited already a parcticle size of < 90 µm, mean fibre length of appr. 60 µm and was therefore not sieved. It was dried at 105°C until constant weight (residual moisture was determined to be 6.2 wt.-%).
The test item was sieved and the fraction < 500 µm was used for the test.
Applicant's summary and conclusion
- Interpretation of results:
- GHS criteria not met
- Conclusions:
- The burning time of the mixtures of the test item with cellulose (4:1 and 1:1) was greater than the burning time of the reference mixture of potassium bromate and cellulose (3:7). Based on the test results the test item does not have to be classified as oxidizing solid.
- Executive summary:
The objective of this study was the determination of the oxidizing properties of the test item according to the
Recommendations on the TRANSPORT OF DANGEROUS GOODS: Manual of Tests and Criteria, 6thedition, New York and Geneva, 2015: Part III, Division 5.1, Section 34, Test O.1
The burning time of the mixtures of the test item with cellulose (4:1 and 1:1) was greater than the burning time of the reference mixture of potassium bromate and cellulose (3:7). Based on the test results the test item does not have to be classified as oxidizing solid.
Thus, the test item has not to be classified as oxidizing solid according to Regulation (EC) 1272/2008.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
