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Physical & Chemical properties

Auto flammability

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Reference
Endpoint:
auto-flammability
Type of information:
experimental study
Adequacy of study:
key study
Study period:
The study was conducted between 11 April 2014 and 23 April 2014.
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
other: GLP guideline study.
Qualifier:
according to guideline
Guideline:
EU Method A.15 (Auto-Ignition Temperature (Liquids and Gases))
Deviations:
no
GLP compliance:
yes (incl. QA statement)
Specific details on test material used for the study:
Batch: PE00083052
Auto-ignition temperature:
288 °C
Atm. press.:
100.5 - 101.5 kPa
Remarks on result:
other:

Results of the auto-ignition temperature determination are shown in the following table.

 

Test temperature (°C)

Test volume (µL)

Ignition delay (s)

Observations

200 (clean flask)

70

>300

No ignition. Grey fumes were emitted

250 (clean flask)

70

>300

No ignition. Grey fumes were emitted

300 (clean flask)

70

>300

No ignition. Grey fumes were emitted

350

70

3

A yellow flame. Grey fumes were emitted.

340

70

4

A yellow flame. Grey fumes were emitted.

320

70

9

A yellow flame. Grey fumes were emitted.

316 (clean flask)

70

10

A yellow flame. Grey fumes were emitted.

310 (clean flask)

70

>300

No ignition

314 (clean flask)

70

15

A yellow flame. Grey fumes were emitted.

312 (clean flask)

70

>300

No ignition. Grey fumes were emitted

312 (clean flask)

200

10

A yellow flame. Grey fumes were emitted.

310 (clean flask)

200

9

A yellow flame. Grey fumes were emitted.

306 (clean flask)

200

11

A yellow flame. Grey fumes were emitted.

304 (clean flask)

200

14

A yellow flame. Grey fumes were emitted.

300 (clean flask)

200

10

A yellow flame. Grey fumes were emitted.

296

200

16

A yellow flame. Grey fumes were emitted.

294 (clean flask)

200

16

A yellow flame. Grey fumes were emitted.

290

200

>300

No ignition. Grey fumes were emitted.

292 (clean flask)

200

21

A yellow flame. Grey fumes were emitted.

290 (clean flask)

200

20

A yellow flame. Grey fumes were emitted.

288 (clean flask)

200

18

A yellow flame. Grey fumes were emitted.

286 (clean flask)

200

>300

No ignition. Grey fumes were emitted.

286 (clean flask)

400

>300

No ignition. Grey fumes were emitted.

286 (clean flask)

600

>300

No ignition. Grey fumes were emitted.

286 (clean flask)

800

>300

No ignition. Grey fumes were emitted.

286 (clean flask)

1000

>300

No ignition. Grey fumes were emitted.

 

Room temperature: 20°C

Atmospheric pressure: 100.5 to 101.5 kPa

Conclusions:
The test material has been determined to have an auto-ignition temperature of 288 ± 5 °C.
Executive summary:

The auto-ignition temperature (liquids and gases) was 288 ± 5 °C using a procedure designed to be compatible with Method A15 Auto-Ignition Temperature (Liquids and Gases) of Commission Regulation (EC) No. 440/2008 of 30 May 2008.

Description of key information

The auto-ignition temperature (liquids and gases) was 288 ± 5 °C using a procedure designed to be compatible with Method A15 Auto-Ignition Temperature (Liquids and Gases) of Commission Regulation (EC) No. 440/2008 of 30 May 2008.

Key value for chemical safety assessment

Autoflammability / Self-ignition temperature at 101 325 Pa:
288 °C

Additional information

The auto-ignition temperature of the test substance was 288 ± 5 °C at 100.5 to 101.5 kPa according to Method A15 Auto-Ignition Temperature (Liquids and Gases) of Commission Regulation (EC) No. 440/2008 of 30 May 2008.