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Diss Factsheets

Physical & Chemical properties

Auto flammability

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Endpoint:
auto-ignition temperature (liquids)
Type of information:
experimental study
Adequacy of study:
weight of evidence
Study period:
20/02/2007
Reliability:
4 (not assignable)
Rationale for reliability incl. deficiencies:
documentation insufficient for assessment
Remarks:
No information is provided on the method used. The substance identification is not complete (purity/composition missing). Therefore validation cannot be granted.
Qualifier:
no guideline followed
Principles of method if other than guideline:
No information is provided on the method used, however, an automated AIT apparatus was used, and description of results is given as for EU A15 (temperature, atmospheric pressure, volume injected, time lag before ignition)
GLP compliance:
no
Key result
Auto-ignition temperature:
240 °C
Atm. press.:
ca. 977 mBar

Measured Auto-Ignition Temperature (+/-5°C): 240°C

Atmospheric pressure: 977 mbar

Volume injected: 200 µL

Time lag before ignition: 80 sec

Executive summary:

The Auto-Iginition Temperature of the test substance was determined with an automated apparatus. No guideline is specified, but the method is supposed similar to EU A.15.

The AIT has been determined to be 240°C, at 977 mbar.

Endpoint:
auto-ignition temperature (liquids)
Type of information:
experimental study
Adequacy of study:
weight of evidence
Study period:
14/11/1995
Reliability:
4 (not assignable)
Rationale for reliability incl. deficiencies:
documentation insufficient for assessment
Remarks:
No information is provided on the method used. The substance identification is not complete (batch N° and purity/composition missing). Therefore validation cannot be granted.
Qualifier:
no guideline followed
Principles of method if other than guideline:
No information is provided on the method used, however, an automated AIT apparatus was used, and description of results is given as for EU A15 (temperature, atmospheric pressure, volume injected, time lag before ignition)
GLP compliance:
no
Key result
Auto-ignition temperature:
290 °C
Atm. press.:
985 mBar

Atmospheric pressure: 985 mbar

 Measured AIT (+/-2.5°C)  Volume injected (µL)  Time lag before ignition (sec)
 288  250  -
 290  300  13
 294  300  11
 299  300  9
 305  300  10
 311  300  7
Executive summary:

The Auto-Iginition Temperature of the test substance was determined with an automated apparatus. No guideline is specified, but the method is supposed similar to EU A.15.

The AIT has been determined to be 290°C, at 985 mbar.

Description of key information

AIT between 240 and 290°C, depending on purity.

Key value for chemical safety assessment

Autoflammability / Self-ignition temperature at 101 325 Pa:
240 °C

Additional information

Two experimental studies are available. Documentation on test method and sample composition is not sufficient to assess reliability, however the method is supposed to be similar to EU A15, and test substances supposed to be of different purity. The result for the raw grade is 240°C, and the result for the refined grade is 290°C, which is quite consistent. For safety purpose, the lower result is retained as key value.