Registration Dossier
Registration Dossier
Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.
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EC number: 813-043-2 | CAS number: 60323-96-8
Guidance on Safe Use
Guidance on Safe Use
Administrative data
First-aid measures
Description of first aid measures
Inhalation:
Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention. If necessary, call a poison center or physician. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Ingestion:
Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention. If necessary, call a poison center or physician. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Skin Contact:
Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Continue to rinse for at least 10 minutes. Get medical attention. Wash clothing before reuse. Clean shoes thoroughly before reuse.
Eye contact:
Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention.
Inhalation:
Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention. If necessary, call a poison center or physician. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Ingestion:
Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention. If necessary, call a poison center or physician. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Skin Contact:
Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Continue to rinse for at least 10 minutes. Get medical attention. Wash clothing before reuse. Clean shoes thoroughly before reuse.
Eye contact:
Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention.
Fire-fighting measures
Extinguishing media
Suitable extinguishing media: In case of fire, use water spray (fog), foam, dry chemical or CO2.
Unsuitable extinguishing media: None known.
Special hazards arising from the substance or mixture
Hazards from the substance or mixture : Explosive material with mass explosion hazard. Runoff to sewer may create fire or explosion hazard.
Hazardous thermal decomposition products: No specific data.
Advice for firefighters:
Special protective actions for firefighters:
Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. First move people out of line-of-sight of the scene and away from windows. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. Fight fire from protected location or maximum possible distance. Do not fight fire when it reaches the material. Withdraw from fire and let it burn.
Special protective equipment for fire fighters:
Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Clothing for fire-fighters (including helmets, protective boots and gloves) conforming to European standard EN 469 will provide a basic level of protection for chemical incidents. Fire-fighters' protective clothing will only provide limited protection.
Suitable extinguishing media: In case of fire, use water spray (fog), foam, dry chemical or CO2.
Unsuitable extinguishing media: None known.
Special hazards arising from the substance or mixture
Hazards from the substance or mixture : Explosive material with mass explosion hazard. Runoff to sewer may create fire or explosion hazard.
Hazardous thermal decomposition products: No specific data.
Advice for firefighters:
Special protective actions for firefighters:
Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. First move people out of line-of-sight of the scene and away from windows. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. Fight fire from protected location or maximum possible distance. Do not fight fire when it reaches the material. Withdraw from fire and let it burn.
Special protective equipment for fire fighters:
Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Clothing for fire-fighters (including helmets, protective boots and gloves) conforming to European standard EN 469 will provide a basic level of protection for chemical incidents. Fire-fighters' protective clothing will only provide limited protection.
Accidental release measures
Personal precautions, protective equipment and emergency procedures
For non -emergency personnel:
Accidental releases pose a serious fire or explosion hazard. Immediately contact emergency personnel. No action shall be taken involving any personal risk or without suitable training. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilt material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. Evacuate surrounding areas.
Environmental precautions:
Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air).
Methods and material for containment and cleaning up
Small spill : Move containers from spill area. Use spark-proof tools and explosion-proof
equipment. Avoid dust generation. Using a vacuum with HEPA filter will reduce dust dispersal. Place spilled material in a designated, labeled waste container. Dispose of via a licensed waste disposal contractor.
Large spill: Move containers from spill area. Prevent entry into sewers, water courses, basements or confined areas. Use spark-proof tools and explosion-proof equipment. Approach the release from upwind. Avoid dust generation. Do not dry sweep. Vacuum dust with equipment fitted with a HEPA filter and place in a closed, labeled waste container. Dispose of via a licensed waste disposal contractor.
For non -emergency personnel:
Accidental releases pose a serious fire or explosion hazard. Immediately contact emergency personnel. No action shall be taken involving any personal risk or without suitable training. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilt material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. Evacuate surrounding areas.
Environmental precautions:
Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air).
Methods and material for containment and cleaning up
Small spill : Move containers from spill area. Use spark-proof tools and explosion-proof
equipment. Avoid dust generation. Using a vacuum with HEPA filter will reduce dust dispersal. Place spilled material in a designated, labeled waste container. Dispose of via a licensed waste disposal contractor.
Large spill: Move containers from spill area. Prevent entry into sewers, water courses, basements or confined areas. Use spark-proof tools and explosion-proof equipment. Approach the release from upwind. Avoid dust generation. Do not dry sweep. Vacuum dust with equipment fitted with a HEPA filter and place in a closed, labeled waste container. Dispose of via a licensed waste disposal contractor.
Handling and storage
Precautions for safe handling
Protective measures : Put on appropriate personal protective equipment . Do not ingest.
Avoid contact with eyes, skin and clothing. Avoid shock and friction. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Empty containers retain product residue and can be hazardous. The product is registered with strictly controlled conditions as defined in Article 17(3) or 18(4) of regulation (EC) no. 1907/2006 (REACH Regulation) and must therefore be handled as such. Refer to the industry guidance prepared by Concawe/Cefic/EFCG for advice on the confirmation of strictly controlled conditions.
Advice on general occupational hygiene :
Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas.
Conditions for safe storage, including any incompatibilities
Conditions for safe storage, including any incompatibilities :
Store in accordance with local regulations. Store in a segregated and approved area. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials and food and drink. Store locked up. Eliminate all ignition sources. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabelled containers. Use appropriate containment to avoid environmental contamination.
Seveso Directive - Reporting thresholds (in tonnes) Danger criteria
Category Notification and MAPP threshold Safety report threshold
P1a: Explosives (All except Division 1.4) 10 50
Specific end use(s)
Remarks : Explosion hazard.
Protective measures : Put on appropriate personal protective equipment . Do not ingest.
Avoid contact with eyes, skin and clothing. Avoid shock and friction. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Empty containers retain product residue and can be hazardous. The product is registered with strictly controlled conditions as defined in Article 17(3) or 18(4) of regulation (EC) no. 1907/2006 (REACH Regulation) and must therefore be handled as such. Refer to the industry guidance prepared by Concawe/Cefic/EFCG for advice on the confirmation of strictly controlled conditions.
Advice on general occupational hygiene :
Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas.
Conditions for safe storage, including any incompatibilities
Conditions for safe storage, including any incompatibilities :
Store in accordance with local regulations. Store in a segregated and approved area. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials and food and drink. Store locked up. Eliminate all ignition sources. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabelled containers. Use appropriate containment to avoid environmental contamination.
Seveso Directive - Reporting thresholds (in tonnes) Danger criteria
Category Notification and MAPP threshold Safety report threshold
P1a: Explosives (All except Division 1.4) 10 50
Specific end use(s)
Remarks : Explosion hazard.
Transport information
Land transport (UN RTDG/ADR/RID)
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Inland waterway transport (UN RTDG/ADN(R))
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Marine transport (UN RTDG/IMDG)
- UN number:
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- Proper shipping name and description:
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Air transport (UN RTDG/ICAO/IATA)
- UN number:
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- Proper shipping name and description:
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Exposure controls / personal protection
Control parameters
Exposure limit values: Not available.
Recommended monitoring procedures:
If this product contains ingredients with exposure limits, personal, workplace atmosphere or biological monitoring may be required to determine the effectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective equipment. Reference should be made to monitoring standards, such as the following: European Standard EN 689 (Workplace atmospheres - Guidance for the assessment of exposure by inhalation to chemical agents for comparison with limit values and measurement strategy) European Standard EN 14042 (Workplace atmospheres - Guide for the application and use of procedures for the assessment of exposure to chemical and biological agents) European Standard EN 482 (Workplace atmospheres - General requirements for the performance of procedures for the measurement of chemical agents) Reference to national guidance documents for methods for the determination of hazardous substances will also be required.
Exposure controls
Appropriate engineering controls:
Use only with adequate ventilation. Engineering controls may be required to control the primary or secondary risks associated with this product. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. Use explosion-proof ventilation equipment. In cases of accident and where waste is generated, procedural and/or control technologies shall be used to minimise emissions and the resulting exposure during purification or cleaning and maintenance procedures. Procedural and control technologies shall be used that minimise emission and any resulting exposure. The substance shall be rigorously contained by technical means during its whole lifecycle including manufacture, purification, cleaning and maintenance of equipment, sampling, analysis, loading and unloading of equipment or vessels, waste disposal or purification and storage.
Individual protection measures
Hygiene measures :
Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.
Eye/face protection : Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles. Recommended: safety glasses with side-shields
Skin protection
Hand protection :
Chemical-resistant, impervious gloves complying with an approved standard should
be worn at all times when handling chemical products if product contact cannot be excluded. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. After contamination with product change the gloves immediately and dispose of them according to relevant national and local regulations.
Recommended: (< 1 hour) Polyvinyl chloride - PVC , Rubber gloves.
Other skin protection : Personal protective equipment for the body should be selected based on the task
being performed and the risks involved and should be approved by a specialist before handling this product.
Recommended: Wear protective clothing.
Respiratory protection : If exposure cannot be ruled out, e.g. during product transfer, sampling or maintenance, a well-fitting respiratory mask conforming to standards or well-fitting respiratory device conforming to standards must be worn. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Recommended: Full mask with type ABEK-P2 filter
Environmental exposure : In some cases, special waste water treatment, fume scrubbers, filters or
controls engineering modifications to the process equipment will be necessary to reduce
emissions to acceptable levels
Exposure limit values: Not available.
Recommended monitoring procedures:
If this product contains ingredients with exposure limits, personal, workplace atmosphere or biological monitoring may be required to determine the effectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective equipment. Reference should be made to monitoring standards, such as the following: European Standard EN 689 (Workplace atmospheres - Guidance for the assessment of exposure by inhalation to chemical agents for comparison with limit values and measurement strategy) European Standard EN 14042 (Workplace atmospheres - Guide for the application and use of procedures for the assessment of exposure to chemical and biological agents) European Standard EN 482 (Workplace atmospheres - General requirements for the performance of procedures for the measurement of chemical agents) Reference to national guidance documents for methods for the determination of hazardous substances will also be required.
Exposure controls
Appropriate engineering controls:
Use only with adequate ventilation. Engineering controls may be required to control the primary or secondary risks associated with this product. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. Use explosion-proof ventilation equipment. In cases of accident and where waste is generated, procedural and/or control technologies shall be used to minimise emissions and the resulting exposure during purification or cleaning and maintenance procedures. Procedural and control technologies shall be used that minimise emission and any resulting exposure. The substance shall be rigorously contained by technical means during its whole lifecycle including manufacture, purification, cleaning and maintenance of equipment, sampling, analysis, loading and unloading of equipment or vessels, waste disposal or purification and storage.
Individual protection measures
Hygiene measures :
Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.
Eye/face protection : Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles. Recommended: safety glasses with side-shields
Skin protection
Hand protection :
Chemical-resistant, impervious gloves complying with an approved standard should
be worn at all times when handling chemical products if product contact cannot be excluded. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. After contamination with product change the gloves immediately and dispose of them according to relevant national and local regulations.
Recommended: (< 1 hour) Polyvinyl chloride - PVC , Rubber gloves.
Other skin protection : Personal protective equipment for the body should be selected based on the task
being performed and the risks involved and should be approved by a specialist before handling this product.
Recommended: Wear protective clothing.
Respiratory protection : If exposure cannot be ruled out, e.g. during product transfer, sampling or maintenance, a well-fitting respiratory mask conforming to standards or well-fitting respiratory device conforming to standards must be worn. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Recommended: Full mask with type ABEK-P2 filter
Environmental exposure : In some cases, special waste water treatment, fume scrubbers, filters or
controls engineering modifications to the process equipment will be necessary to reduce
emissions to acceptable levels
Stability and reactivity
Possibility of hazardous reactions : Hazardous reactions or instability may occur under certain conditions of storage or use. C
Conditions may include the following:
shock
friction
high temperature
Reactions may include the following:
risk of explosion
Conditions to avoid : Dust explosion test in the modified Hartmann tube: Capable of causing a dust explosion
Avoid dust formation. . Take precautionary measures against static discharges. Do not allow to dry out.
Keep away from: Strong oxidiser risk of explosion
Incompatible materials : No specific data.
Hazardous decomposition products: Under normal conditions of storage and use, hazardous decomposition products should not be produced.
Conditions may include the following:
shock
friction
high temperature
Reactions may include the following:
risk of explosion
Conditions to avoid : Dust explosion test in the modified Hartmann tube: Capable of causing a dust explosion
Avoid dust formation. . Take precautionary measures against static discharges. Do not allow to dry out.
Keep away from: Strong oxidiser risk of explosion
Incompatible materials : No specific data.
Hazardous decomposition products: Under normal conditions of storage and use, hazardous decomposition products should not be produced.
Disposal considerations
Waste treatment methods
Product
Methods of disposal: The generation of waste should be avoided or minimised wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Hazardous waste: The classification of the product may meet the criteria for a hazardous waste.
Packaging
Methods of disposal: The generation of waste should be avoided or minimised wherever possible. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible.
Special precautions: This material and its container must be disposed of in a safe way. Care should be
taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers.
Product
Methods of disposal: The generation of waste should be avoided or minimised wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Hazardous waste: The classification of the product may meet the criteria for a hazardous waste.
Packaging
Methods of disposal: The generation of waste should be avoided or minimised wherever possible. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible.
Special precautions: This material and its container must be disposed of in a safe way. Care should be
taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
