Registration Dossier
Registration Dossier
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EC number: 214-093-2 | CAS number: 1079-66-9
Guidance on Safe Use
Administrative data
First-aid measures
Description of first aid measures
First aid personnel should pay attention to their own safety. If the patient is likely to become unconscious, place and transport in stable sideways position (recovery position). Immediately remove contaminated clothing.
If inhaled:
Keep patient calm, remove to fresh air, seek medical attention. Immediately administer a corticosteroid from a controlled/metered dose inhaler.
On skin contact:
Immediately wash thoroughly with plenty of water, apply sterile dressings, consult a skin specialist.
On contact with eyes:
Immediately wash affected eyes for at least 15 minutes under running water with eyelids held open, consult an eye specialist.
On ingestion:
Do not induce vomiting. Immediately rinse mouth and then drink 200-300 ml of water, seek medical attention.
Most important symptoms and effects, both acute and delayed
Symptoms: The most important known symptoms and effects are described in the labelling (see section 2 of MSDS) and/or in section 11 of MSDS.
Indication of any immediate medical attention and special treatment needed
Treatment: Treat according to symptoms (decontamination, vital functions), no known specific antidote.
Fire-fighting measures
Extinguishing media
Suitable extinguishing media:
dry powder, carbon dioxide
Unsuitable extinguishing media for safety reasons:
water
Special hazards arising from the substance or mixture
Hydrogen chloride, nitrogen oxides, carbon oxides, harmful vapours
The substances/groups of substances mentioned can be released in case of fire. Evolution of fumes/fog. Under certain conditions in case of fire other hazardous combustion products may be generated.
Advice for fire-fighters
Special protective equipment:
Wear self-contained breathing apparatus and chemical-protective clothing.
Further information:
The degree of risk is governed by the burning substance and the fire conditions. Contaminated extinguishing water must be disposed of in accordance with official regulations.
Accidental release measures
Personal precautions, protective equipment and emergency procedures
Use personal protective clothing. Information regarding personal protective measures see, section "Exposure controls/personal protection". Keep unprotected persons away. Ensure adequate ventilation. Breathing protection required. Avoid contact with the skin, eyes and clothing.
Environmental precautions
Contain contaminated water/firefighting water. Do not discharge into drains/surface waters/groundwater.
Methods and material for containment and cleaning up
For large amounts: Pump off product.
For residues: Pick up with suitable absorbent material. Dispose of absorbed material in accordance with regulations.
Reference to other sections
Information regarding exposure controls/personal protection and disposal considerations can be found in section "Exposure controls/personal protection" and "Disposal considerations".
Handling and storage
Precautions for safe handling
Ensure thorough ventilation of stores and work areas. Product should be worked up in closed equipment as far as possible. Do not mix with water. Avoid inhalation of mists/vapours.
Conditions for safe storage, including any incompatibilities
Suitable materials for containers: Steel with polyethylene liner
Unsuitable materials for containers: Aluminium
Further information on storage conditions: Keep container tightly closed and in a cool place.
Specific end use(s)
For the relevant identified use(s) listed in Section 1 of MSDS the advice mentioned in this section is to be observed.
Transport information
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Marine transport (UN RTDG/IMDG)
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Exposure controls / personal protection
Control parameters
Components with occupational exposure limits
No occupational exposure limits known.
DNEL
No DNELs have been derived.
Exposure controls
Personal protective equipment
Respiratory protection:
Suitable respiratory protection for higher concentrations or long-term effect: Combination filter for gases/vapours of organic, inorganic, acid inorganic and alkaline compounds (e.g. EN 14387 Type ABEK).
Hand protection:
Chemical resistant protective gloves (EN 374)
Suitable materials also with prolonged, direct contact (Recommended: Protective index 6, corresponding > 480 minutes of permeation time according to EN 374):
fluoroelastomer (FKM) - 0.7 mm coating thickness
Suitable materials for short-term contact (recommended: At least protective index 2, corresponding > 30 minutes of permeation time according to EN 374)
butyl rubber (butyl) - 0.7 mm coating thickness
nitrile rubber (NBR) - 0.4 mm coating thickness
polyvinylchloride (PVC) - 0.7 mm coating thickness
chloroprene rubber (CR) - 0.5 mm coating thickness
Supplementary note: The specifications are based on tests, literature data and information of glove manufacturers or are derived from similar substances by analogy. Due to many conditions (e.g. temperature) it must be considered, that the practical usage of a chemical-protective glove in practice may be much shorter than the permeation time determined through testing.
Manufacturer's directions for use should be observed because of great diversity of types.
Eye protection:
Tightly fitting safety goggles (cage goggles) (e.g. EN 166) and face shield.
Body protection:
Body protection must be chosen based on level of activity and exposure., acid- resp. lye-proof apron, e.g. of rubber (f.e. according to EN 14605), protection boots, f.e. of rubber (e.g. according to EN 20346), acid-proof chemical protection suit (f.e. according to EN 14605)
General safety and hygiene measures
Avoid contact with the skin, eyes and clothing. Do not breathe vapour/spray. The substance was registered as a transported isolated intermediate. The manufacturer/importer has received the confirmation by the user that the substance is used under strictly controlled conditions in accordance with art. 18 of the REACH regulation (EC) No 1907/2006. No eating, drinking, smoking or tobacco use at the place of work. Store work clothing separately.
Environmental exposure controls
For information regarding environmental exposure controls, see Section "Accidental release measures".
Stability and reactivity
Reactivity
Corrosion to metals:
Corrosive effect on metals.
Reactions with water/air: Reaction with: water
Flammable gases: no
Toxic gases: yes
Which toxic gases: hydrogen chloride (HCl)
Corrosive gases: yes
Which corrosive gases: hydrogen chloride (HCl)
Smoke or fog: yes
Type of smoke or fog: Hydrochloric acid
Peroxides: no
Which Peroxides:
Reaction with: air
Flammable gases: no
Toxic gases: no
Corrosive gases: no
Smoke or fog: no
Peroxides: no
Formation of flammable gases: Remarks: Forms no flammable gases in the presence of water.
Method: Manual of tests and criteria. Test N.5 (United Nations Recommendations on the Transport of Dangerous Goods).
Chemical stability
The product is stable if stored and handled as prescribed/indicated.
Possibility of hazardous reactions
Develops hydrochloric acid (HCl) on contact with water.
Conditions to avoid
Avoid all sources of ignition: heat, sparks, open flame. Avoid electro-static discharge.
Incompatible materials
Substances to avoid:
water, strong oxidizing agents, strong bases, alkali metals
Hazardous decomposition products
Hazardous decomposition products:
No hazardous decomposition products if stored and handled as prescribed/indicated.
Disposal considerations
Waste treatment methods
Incinerate in suitable incineration plant, observing local authority regulations.
Contaminated packaging:
Contaminated packaging should be emptied as far as possible; then it can be passed on for recycling after being thoroughly cleaned.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
