Registration Dossier

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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Physical & Chemical properties

Endpoint summary

Administrative data

Description of key information

Perkadox PM-W75 is an organic peroxide type D with a SADT of 90°C. Flammability is an intrinsic hazard in this class.

 Bis(4 -methylbenzoyl)peroxide is a powder (water damped solid white powder, 72%).  

The melting point of bis(4-methylbenzoyl)peroxide is 134.8°C and the substance decomposes immediately after the melting process. The reported melting point is above the SADT.

The relative density of bis(4-methylbenzoyl)peroxide is 1.22 at 20°C.

The calculated vapour pressure of bis(4-methylbenzoyl)peroxide is 0.0012 Pa at 25°C.

The partition coefficient of bis(4-methylbenzoyl)peroxide is log Pow = 4.7.

The water solubility of bis(4-methylbenzoyl)peroxide at 20°C is 0.043mg/L.

The fat solubility of bis(4-methylbenzoyl)peroxide in standard fat HB 307 is 680 ± 50mg/100g, at 37.0 ± 0.5°C.

 

The endpoint summaries of the following properties of Bis(4 -methylbenzoyl)peroxide are waived:

Boiling point: The substance decomposes just after melting, before boiling. Moreover, bis(4 -methylbenzoyl)peroxide is classified as a Type D peroxide with a SADT of90 ºC.

Surface tension: Bis(4 -methylbenzoyl)peroxide should not be regarded as a surface active material.

Flash point: The study is technically not feasible.

Flammability: Bis(4-methylbenzoyl)peroxide is classified as a peroxide Type D with a SADT of 90 ºC. Flammability is an intrinsic hazard in this class.

Explosive properties:Substance has no explosive properties and has no oxidizing properties. It is not classified as Organic Peroxide Type B (Reference: CLP regulations 2.15.2.2 and UN Recommendations on the Transport of Dangerous Goods, 16th revised edition, Section 2.5.3.2.4).

Oxidizing properties:This test is not applicable. In the CLP regulations, organic peroxides are not oxidizers. They are classified in a distinct hazard class (Also, see ECHA guidance on the application of the CLP criteria, Section 2.14)

Additional information