Registration Dossier
Registration Dossier
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EC number: 224-536-1 | CAS number: 4402-30-6
Guidance on Safe Use
Administrative data
First-aid measures
Remove contaminated clothing.
If inhaled:
Keep patient calm, remove to fresh air. Immediately inhale corticosteroid dose aerosol.
On skin contact:
Immediately wash thoroughly with plenty of water, apply sterile dressings, consult a skin specialist.
On contact with eyes:
Immediately wash affected eyes for at least 15 minutes under running water with eyelids held open, consult an eye specialist.
On ingestion:
Immediately rinse mouth and then drink 200-300 ml of water, seek medical attention.
Most important symptoms and effects, both acute and delayed
Symptoms: The most important known symptoms and effects are described in the labelling. Further symptoms are possible
Indication of any immediate medical attention and special treatment needed
Treatment: Treat according to symptoms (decontamination, vital functions), no known specific antidote.
Fire-fighting measures
Suitable extinguishing media:
water spray, dry powder, foam, carbon dioxide
Special hazards arising from the substance or mixture
nitrogen oxides, carbon oxides
The substances/groups of substances mentioned can be released in case of fire. Under certain conditions in case of fire other hazardous combustion products may be generated.
Advice for fire-fighters
Special protective equipment:
Wear self-contained breathing apparatus and chemical-protective clothing.
Further information:
Dispose of fire debris and contaminated extinguishing water in accordance with official regulations.
Accidental release measures
Personal precautions, protective equipment and emergency procedures
Avoid inhalation. Avoid contact with the skin, eyes and clothing.
Environmental precautions
Do not discharge into drains/surface waters/groundwater.
Methods and material for containment and cleaning up
For small amounts: Pick up with suitable appliance and dispose of.
For large amounts: Pick up with suitable appliance and dispose of.
Clean contaminated floors and objects thoroughly with water and detergents, observing environmental regulations. Collect waste in suitable containers, which can be labeled and sealed. Incinerate or take to a special waste disposal site in accordance with local authority regulations.
Handling and storage
Precautions for safe handling
Ensure thorough ventilation of stores and work areas.
Protection against fire and explosion:
Prevent electrostatic charge - sources of ignition should be kept well clear - fire extinguishers should be kept handy.
Conditions for safe storage, including any incompatibilities
Segregate from acids and acid forming substances.
Further information on storage conditions: Keep container tightly closed and dry. Keep under inert gas.
Transport information
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Marine transport (UN RTDG/IMDG)
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Exposure controls / personal protection
Control parameters
Components with occupational exposure limits
No occupational exposure limits known.
PNEC
freshwater: 0.1 mg/l
marine water: 0.01 mg/l
intermittent release: 1 mg/l
STP: 7.19 mg/l
sediment (freshwater): 1.13 mg/kg
sediment (marine water): 0.113 mg/kg
soil: 0.167 mg/kg
Exposure controls
Personal protective equipment
Respiratory protection:
Respiratory protection in case of vapour/aerosol release. Gas filter for gases/vapours of organic compounds (boiling point >65 °C, e. g. EN 14387 Type A)
Hand protection:
Suitable materials also with prolonged, direct contact (Recommended: Protective index 6, corresponding > 480 minutes of permeation time according to EN 374):
butyl rubber (butyl) - 0.7 mm coating thickness
Suitable materials short-term contact and/or splashes (recommended: At least protective index 2, corresponding > 30 minutes of permeation time according to EN 374)
nitrile rubber (NBR) - 0.4 mm coating thickness
chloroprene rubber (CR) - 0.5 mm coating thickness
polyvinylchloride (PVC) - 0.7 mm coating thickness
Supplementary note: The specifications are based on tests, literature data and information of glove manufacturers or are derived from similar substances by analogy. Due to many conditions (e.g. temperature) it must be considered, that the practical usage of a chemical-protective glove in practice may be much shorter than the permeation time determined through testing.
Manufacturer's directions for use should be observed because of great diversity of types.
Eye protection:
Tightly fitting safety goggles (cage goggles) (e.g. EN 166) and face shield.
General safety and hygiene measures
Handle in accordance with good industrial hygiene and safety practice. Wearing of closed work clothing is required additionally to the stated personal protection equipment. Take off immediately all contaminated clothing. Store work clothing separately.
Stability and reactivity
Reactivity
No hazardous reactions if stored and handled as prescribed/indicated.
Formation of flammable gases:
Forms no flammable gases in the presence of water.
Chemical stability
The product is stable if stored and handled as prescribed/indicated.
Possibility of hazardous reactions
Reacts with acid chlorides. Reacts with acids. Incompatible with acid chlorides and acid anhydrides. Reacts with halogenated compounds. Reacts with oxidizing agents. The progress of reaction is exothermic.
Conditions to avoid
Avoid extreme temperatures.
Incompatible materials
Substances to avoid:
oxidizing agents, acid chlorides, acid anhydrides, acid forming substances, acids
Hazardous decomposition products
Thermal decomposition products:
carbon oxides, nitrogen oxides
Disposal considerations
Waste treatment methods
Incinerate in suitable incineration plant, observing local authority regulations.
A waste code in accordance with the European waste catalog (EWC) cannot be specified, due to dependence on the usage.
The waste code in accordance with the European waste catalog (EWC) must be specified in cooperation with disposal agency/manufacturer/authorities.
Contaminated packaging:
Contaminated packaging should be emptied as far as possible; then it can be passed on for recycling after being thoroughly cleaned.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
