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Diss Factsheets

Physical & Chemical properties

Melting point / freezing point

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Administrative data

Endpoint:
melting point/freezing point
Type of information:
experimental study
Adequacy of study:
key study
Reliability:
2 (reliable with restrictions)
Rationale for reliability incl. deficiencies:
comparable to guideline study with acceptable restrictions

Data source

Reference
Reference Type:
publication
Title:
Phase Transitions in the Alkali C 1 - n. C 4 Alkanoates
Author:
P. Ferloni, M. Sanesi, and P. Franzosini
Year:
1975
Bibliographic source:
Z. Naturforsch. 30a (1975) 1447–1454.

Materials and methods

Principles of method if other than guideline:
- Principle of test: Measurement of Phase transition temperatures and enthalpies/heat capacity
- Short description of test conditions: For each salt 3 to 11 samples were DSC analyzed in the range from ~ 110 K up to the melt region, using sealed Al containers. A Wayne-Kerr autobalance precision bridge Mod. B 331 Mk II (frequency: 1592 Hz; conductance range: E - 10 - E-2 Ohm-1 ) in connection with a Gould Brush 500 XY plotter was used to continuously record the conductance of solid samples (in the form of pellets compressed between Ag electrodes) as a function of temperature.
- Parameters analysed / observed: Transition temperatures
GLP compliance:
no
Type of method:
differential scanning calorimetry

Test material

Constituent 1
Chemical structure
Reference substance name:
Potassium propionate
EC Number:
206-323-5
EC Name:
Potassium propionate
Cas Number:
327-62-8
Molecular formula:
C3H6O2.K
IUPAC Name:
potassium propionate
Test material form:
solid: particulate/powder

Results and discussion

Melting / freezing pointopen allclose all
Key result
Melting / freezing pt.:
638 K
Remarks on result:
other: The atmospheric pressure and a decomposition temperaure were not reported
Key result
Melting / freezing pt.:
364 °C
Remarks on result:
other: the atmospheric pressure and a decomposition temperature were not reported

Applicant's summary and conclusion

Conclusions:
Based on the results presented in the publication of Ferloni et al (1975) Potassium Propionate has a melting temperature of approximately 364 °C (as calulated from the respective value in Kelvin: 638 K). Other phase trasnsitions (solid to solid) already occurred at 352 K and 258 K, corresponding to 78,85 and -15.5 °C, respectively.
Executive summary:

Based on the results presented in the publication of Ferloni et al (1975) Potassium Propionate has a melting temperature of approximately 364 °C (as calulated from the respective value in Kelvin: 638 K). Other phase transitions (solid to solid) already occurred at 352 K and 258 K, corresponding to 78,85 and -15.5 °C, respectively.


Melting Point: 364°C


The study is considered acceptable and satifies the information requirements according to OECD TG 102.