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Diss Factsheets

Physical & Chemical properties

Flash point

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Administrative data

Link to relevant study record(s)

Reference
Endpoint:
flash point of flammable liquids
Type of information:
experimental study
Adequacy of study:
key study
Study period:
Test dates: November 3, 2008 to January 8, 2009
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Remarks:
The study was conducted according to an internationally recognised method, and under GLP. The substance is adequately identified. Therefore full validation applies.
Qualifier:
according to guideline
Guideline:
EU Method A.9 (Flash-Point)
GLP compliance:
yes (incl. QA statement)
Remarks:
GIPC; effective 16 July 2008 (validity 18 months)
Type of method:
equilibrium method closed cup
Flash point apparatus:
Setaflash apparatus
Dynamic viscosity of test material:
no data
Specific details on test material used for the study:
Storage conditions: Room temperature protected from direct sun light.
Key result
Flash point:
93 °C
Atm. press.:
ca. 1 atm

In a first test, the temperature was increased by successive steps of +5.0 °C, using 2 mL of sample. Flashing occurred at 95°C.

The procedure was reproduced in duplicate using a new 2.0 mL sample for each replicate test, and the temperature was regularly increased by successive steps of 0.5 °C. Flashing occurred at 93.0°C in both cases.

Mean Flash Point = 93.0 +/-0.0°C.

Interpretation of results:
Category 4 (combustible liquids) based on GHS criteria
Remarks:
EU-CLP criteria not met
Conclusions:
The flash point of the test substance is above the classification threshold of 60 °C (NOT classified for CLP criteria), but at the classification threshold of 93 °C (GHS criteria). Therefore, the test substance is classified as flammable liquid in cat.4 according to GHS criteria.
Executive summary:

The flash point of the test substance was determined under GLP according to EU A.9 guideline, using a closed cup method with Setaflash apparatus.

After a screening determination, two main runs were performed, and found identical.

The flash point of the test substance was determined to be 93°C.

Description of key information

The substance is NOT classified as flammable liquid according to CLP Regulation criteria.

It is classified as Flammable Liquid in cat.4 according to UN GHS.

Key value for chemical safety assessment

Flash point at 101 325 Pa:
93 °C

Additional information

A fully reliable experimental study, conducted according to a recognized EU method and under GLP, is available. Therefore it is considered as a key study, and the result is retained as key data.

(see IU Section 4.13 for justification of non-classification)