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Diss Factsheets

Physical & Chemical properties

Flash point

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Endpoint:
flash point
Type of information:
experimental study
Adequacy of study:
supporting study
Reliability:
4 (not assignable)
Rationale for reliability incl. deficiencies:
documentation insufficient for assessment
Qualifier:
according to guideline
Guideline:
ISO No., other: DIN 51755
GLP compliance:
not specified
Type of method:
closed cup
Flash point:
10 °C
Atm. press.:
1 013 hPa

The pressure 1013 hPa is assumed since the pressure should be corrected to 1013 hPa by the system.

Conclusions:
A flash point value of 10°C is reported in secondary literature (MSDS). The original reference was not available for review and no further information is available. The reliability of this result is not assignable.
Endpoint:
flash point of flammable liquids
Type of information:
experimental study
Adequacy of study:
key study
Study period:
09-Feb-2015
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Qualifier:
according to guideline
Guideline:
EU Method A.9 (Flash-Point)
Version / remarks:
1.6.3.2
Qualifier:
according to guideline
Guideline:
ISO 13736:1997 (Petroleum products and other liquids - Determination of flash point - Abel closed cup method)
Version / remarks:
1997
GLP compliance:
no
Type of method:
closed cup
Flash point:
1 °C
Atm. press.:
1 013 hPa

Results

 

Test series

Measured value (°C)

Corrected value (°C) *

1

0.1

1.3

2

0.1

1.3

Mean value

1.5 °C

* The mean value is calculated from test 1 and 2 and rounded to +/- 0.5 °C

Determination of the corrected flash-point:

TC = T0+ 0.25 x (101.3 – p)

 

TC = corrected flash point to the standard atmospheric pressure (101.3 kPa)

T0 = measured flash point at actual atmospheric pressure

p = actual atmospheric pressure [kPa]

Conclusions:
A flash point value of 1.0 °C at 1013 hPa was determined in a reliable study conducted according to an appropriate test protocol. It was not compliant with GLP.
Endpoint:
flash point of flammable liquids
Type of information:
experimental study
Adequacy of study:
key study
Study period:
16-Feb -2015
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Qualifier:
according to guideline
Guideline:
EU Method A.9 (Flash-Point)
Version / remarks:
1.6.3.1
Qualifier:
according to guideline
Guideline:
ISO 1523 (Determination of flash point - Closed cup equilibrium method)
Version / remarks:
2002
GLP compliance:
no
Type of method:
equilibrium method closed cup
Flash point:
1.5 °C
Atm. press.:
1 013 hPa

Results

 

Test series

Density at 20 °C (g/cm3)

Relative density D204*

1

0.1

1.3

2

0.1

1.3

Mean value

1.5

 

Determination of the corrected flash-point:

TC = T0 + 0.25 x (101.3 – p)

 

TC = corrected flash point to the standard atmospheric pressure (101.3 kPa)

T0 = measured flash point at actual atmospheric pressure

p = actual atmospheric pressure [kPa]

Conclusions:
A flash point value of 1.5 °C at 1013 hPa was determined in a reliable study conducted according to an appropriate test protocol. It was not compliant with GLP.

Description of key information

Diethoxy(methyl)silane: 1.0°C at 1013 hPa (Abel closed cup method, EU Method A.9.)

Key value for chemical safety assessment

Flash point at 101 325 Pa:
1 °C

Additional information

A flash point of 1.0°C at 1013 hPa was determined for the test substance according to EU Method A.9 (Abel closed cup method). This is supported by a measured value of 1.5 °C at 1013 hPa (closed cup equilibrium method).