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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Ecotoxicological information

Toxicity to soil microorganisms

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Administrative data

Link to relevant study record(s)

Reference
Endpoint:
toxicity to soil microorganisms
Type of information:
experimental study
Adequacy of study:
weight of evidence
Reliability:
2 (reliable with restrictions)
Rationale for reliability incl. deficiencies:
other: Recent review of published work on fluoride ions.
Qualifier:
no guideline followed
Principles of method if other than guideline:
The EU RAR summarises the results of a number of relevant studies
GLP compliance:
no
Specific details on test material used for the study:
Details on properties of test surrogate or analogue material (migrated information):
Not relevant
Analytical monitoring:
not specified
Details on sampling:
No details of sampling given in review.
Vehicle:
no
Details on preparation and application of test substrate:
No details on preparation and application of test substance given in the review.
Test organisms (inoculum):
soil
Total exposure duration:
63 d
Test temperature:
Not stated
Moisture:
Not stated.
Details on test conditions:
No further details given in review
Nominal and measured concentrations:
not stated
Reference substance (positive control):
no
Duration:
24 d
Dose descriptor:
NOEC
Effect conc.:
3 000 mg/kg soil dw
Nominal / measured:
nominal
Conc. based on:
test mat.
Remarks:
F-
Basis for effect:
other: Dehydrogenase inhibition
Remarks on result:
other: sodium fluoride
Duration:
63 d
Dose descriptor:
NOEC
Effect conc.:
340 mg/kg soil dw
Nominal / measured:
nominal
Conc. based on:
test mat.
Remarks:
F-
Basis for effect:
other: NH4-minerilisation
Remarks on result:
other: potassium fluoride
Duration:
63 d
Dose descriptor:
NOEC
Effect conc.:
106 mg/kg soil dw
Nominal / measured:
nominal
Conc. based on:
test mat.
Remarks:
F-
Basis for effect:
other: NO3-mineralisation
Remarks on result:
other: potassium fluoride
Duration:
63 d
Dose descriptor:
NOEC
Effect conc.:
1 060 mg/kg soil dw
Nominal / measured:
nominal
Conc. based on:
test mat.
Remarks:
F-
Basis for effect:
other: P-mineralisation
Remarks on result:
other: potassium fluoride
Details on results:
The NOEC values detailed in the report range from 106 to 3000 mg F-/kg dw. The 63 day experiments were carried out in a micro-ecosystem containing poplar litter (30% o.m) and the isopod Porcellio scaber Latr. Nitrification was found to be the most sensitive in the micro-ecosystem test.
Executive summary:

The EU RAR reports NOEC values from 106 to 3000 mg F-/kg. The 63 day experiments were carried out in a micro-ecosystem containing poplar litter (30% o.m) and the isopod Porcellio scaber. Nitrification was found to be the most sensitive endpoint investigated in the micro-ecosystem test.

For conservative reasons the lowest NOEC, i.e., 106 mg F-/Kg dw will be used for the risk assessment.

Applying the conversion factor from F- to hexafluorosilicic acid, the NOEC corresponds to 133.6 mg hexafluorosilicic acid/kg.

Description of key information

NOEC: 133.6 mg hexafluorosilicic acid/kg.

Key value for chemical safety assessment

Long-term EC10 or NOEC for soil microorganisms:
133.6 mg/kg soil dw

Additional information

The EU RAR reports NOEC values from 106 to 3000 mg F-/kg. The 63 day experiments were carried out in a micro-ecosystem containing poplar litter (30% o.m) and the isopodPorcellio scaber.Nitrification was found to be the most sensitive endpoint investigated in the micro-ecosystem test.

For conservative reasons the lowest NOEC, i.e., 106 mg F-/Kg dw will be used for the risk assessment.

Applying the conversion factor from F- to hexafluorosilicic acid, the NOEC corresponds to 133.6 mg hexafluorosilicic acid/kg.