Registration Dossier
Registration Dossier
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The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.
Diss Factsheets
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EC number: 202-196-5 | CAS number: 92-84-2
- Life Cycle description
- Uses advised against
- Endpoint summary
- Appearance / physical state / colour
- Melting point / freezing point
- Boiling point
- Density
- Particle size distribution (Granulometry)
- Vapour pressure
- Partition coefficient
- Water solubility
- Solubility in organic solvents / fat solubility
- Surface tension
- Flash point
- Auto flammability
- Flammability
- Explosiveness
- Oxidising properties
- Oxidation reduction potential
- Stability in organic solvents and identity of relevant degradation products
- Storage stability and reactivity towards container material
- Stability: thermal, sunlight, metals
- pH
- Dissociation constant
- Viscosity
- Additional physico-chemical information
- Additional physico-chemical properties of nanomaterials
- Nanomaterial agglomeration / aggregation
- Nanomaterial crystalline phase
- Nanomaterial crystallite and grain size
- Nanomaterial aspect ratio / shape
- Nanomaterial specific surface area
- Nanomaterial Zeta potential
- Nanomaterial surface chemistry
- Nanomaterial dustiness
- Nanomaterial porosity
- Nanomaterial pour density
- Nanomaterial photocatalytic activity
- Nanomaterial radical formation potential
- Nanomaterial catalytic activity
- Endpoint summary
- Stability
- Biodegradation
- Bioaccumulation
- Transport and distribution
- Environmental data
- Additional information on environmental fate and behaviour
- Ecotoxicological Summary
- Aquatic toxicity
- Endpoint summary
- Short-term toxicity to fish
- Long-term toxicity to fish
- Short-term toxicity to aquatic invertebrates
- Long-term toxicity to aquatic invertebrates
- Toxicity to aquatic algae and cyanobacteria
- Toxicity to aquatic plants other than algae
- Toxicity to microorganisms
- Endocrine disrupter testing in aquatic vertebrates – in vivo
- Toxicity to other aquatic organisms
- Sediment toxicity
- Terrestrial toxicity
- Biological effects monitoring
- Biotransformation and kinetics
- Additional ecotoxological information
- Toxicological Summary
- Toxicokinetics, metabolism and distribution
- Acute Toxicity
- Irritation / corrosion
- Sensitisation
- Repeated dose toxicity
- Genetic toxicity
- Carcinogenicity
- Toxicity to reproduction
- Specific investigations
- Exposure related observations in humans
- Toxic effects on livestock and pets
- Additional toxicological data
Guidance on Safe Use
Administrative data
First-aid measures
General information:
- Seek medical advice immediately.
- Ensure that the First Aid Personnel are aware of the product involved, and take precautions to protect themselves (e.g. wear personal protection equipment).
- Remove affected person from danger area, lay him down.
- Remove soiled or soaked clothing immediately.
- Keep warm, calm and covered up.
After inhalation:
- Summon a doctor immediately.
- Remove the casualty into fresh air and keep him calm.
After contact with skin:
- Summon a doctor immediately.
- In case of contact with skin wash off immediately with polyethylene glycol 400, then with plenty of water.
After contact with eyes:
- Summon a doctor immediately.
- In case of contact with the eyes rinse thoroughly with plenty of water or with an eye-cleaning solution.
After ingestion:
- When swallowed seek medical aid immediately and show the physician the packaging or the label of the packaging.
Fire-fighting measures
Suitable extinguishing media:
- Alcohol-resistant foam.
- Dry powder.
- Carbon dioxide.
- Water spray jet.
Extinguishing media that must not be used for safety reasons:
- Full water jet.
Special hazards from the substance itself, its combustion products or from its vapours:
- In case of fires, hazardous combustion gases are formed:
- Carbon monoxide (CO)
- Nitrogen oxides (NOx)
- Carbon dioxide (CO2)
- Sulphur dioxide (SO2)
Special protective equipment for firefighting:
- Do not inhale explosion and/or combustion gases.
- Use self-contained breathing apparatus.
Further information:
- Fire residues and contaminated firefighting water must be disposed of in accordance with the local regulations.
Accidental release measures
Personal precautions:
- Use personal protective clothing.
- Avoid contact with skin and eyes.
- Remove persons to safety.
Environmental precautions:
- Do not allow entry to drains,water courses or soil.
- Contain contaminated water/firefighting water.
- If the product gets into drains, inform the relevant authorities immediately.
Methods for cleaning up/taking up:
- Take up with suitable equipment and if necessary collect in closed containers.
- Avoid raising dust.
- Clean contaminated floors and objects thoroughly, observing environmental regulations.
- When picked up, treat material as prescribed under heading "Disposal".
- Dispose of absorbed material in accordance with the regulations.
- Containers in which spilt substance has been collected must be adequately labelled.
Handling and storage
Advice on safe handling:
- Provide good ventilation of working area (local exhaust ventilation if necessary).
- Avoid the formation and deposition of dust. Use material in a low dusty form (prills, pellets or similar) only.
- Provide exhaust ventilation if dust is formed.
Advice on protection against fire and explosion:
- In principle, with organic products which are -intentionally or unintentionally- in powdered form, the danger of a dust explosion should be kept in mind.
- Take precautionary measures against electrostatic charges - earthing necessary during loading operations.
- Keep away from sources of ignition - refrain from smoking.
- Dust can form an explosive mixture with air.
- Observe the general rules of industrial fire protection
Advice on storage compatibility:
- Do not store or transport together with foodstuffs.
Further information on storage conditions:
- Air- and light sensitive.
- Keep container tightly closed and dry.
Transport information
Land transport (UN RTDG/ADR/RID)
- UN number:
- 3077
Shipping information
- Proper shipping name and description:
- ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
- Chemical name:
- Phenothiazine
- Language:
- English
- Labels:
- 9
SpecialProvisionsopen allclose all
Inland waterway transport (UN RTDG/ADN(R))
- UN number:
- 3077
Shipping information
- Proper shipping name and description:
- ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
- Chemical name:
- Phenothiazine
- Language:
- English
- Labels:
- 9
Remarksopen allclose all
Marine transport (UN RTDG/IMDG)
- UN number:
- 3077
Shipping information
- Proper shipping name and description:
- ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
- Chemical name:
- Phenothiazine
- Labels:
- 9
- Marine pollutant
Remarksopen allclose all
Air transport (UN RTDG/ICAO/IATA)
- UN number:
- 3077
Shipping information
- Proper shipping name and description:
- ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
- Chemical name:
- Phenothiazine
- Labels:
- 9
Remarksopen allclose all
SpecialProvisionsopen allclose all
Exposure controls / personal protection
General protective measures:
Do not inhale dust. Avoid contact with eyes and skin.
Hygiene measures:
Handle in accordance with good industrial hygiene and safety practice. Wearing of closed work clothing is required additionally to the stated personal protection equipment. Avoid contact of the substance. Do not eat, drink or smoke during work time. Remove soiled or soaked clothing immediately and clean thoroughly before using again. Garments that cannot be cleaned must be destroyed (burnt). Keep away from food and drink. Clean hands and face during work intervals and after work Follow the skin protection plan.
Respiratory protection:
No personal respiratory protective equipment normally required. If the occupational exposure limits cannot be met, in exceptional cases suitable respiratory equipment should be worn only for a short period of time. Suitable respiratory equipment: Respirator with a particle filter (EN 143), Half mask with a particle filter P2 (EN 143).
Hand protection:
Choose gloves to protect hands against chemicals depending on the concentration and quantity of the hazardous substance and specific to place of work. Take note of the information given by the producer concerning permeability and break through times, and of special workplace conditions (mechanical strain, duration of contact). Suitable: Protective gloves complying with EN 374. Suitable are nitrile rubber gloves, butyl rubber gloves. With solid dry substances permeation is not to be expected, therefore the breakthrough-time for this protective glove has not been measured. Gloves must be inspected prior to use. Gloves should be discarded and replaced if there is any indication of degradation or chemical breakthrough. Gloves must be rinsed thoroughly after use. In case of preparing or handling of solutions of the substance the properties of the solvent have to be taken into account.
Eye protection:
Tightly fitting safety glasses according to EN 166.
Body protection:
Wear long-armed working cloth. Change working clothes after each workshift. Select clothing according to the amount and concentration of the substance at the working place. Wear as appropriate: Dust impervious protective suit for example, Apron, boots, protective clothing (EN 14605, EN ISO 13982-1, EN 13034). In case of preparing or handling of solutions of the substance the properties of the solvent have to be taken into account.
Stability and reactivity
Thermal decomposition:
- > 250 °C (Heating rate : 10 K/min).
- No decomposition if used as prescribed.
Hazardous reactions:
- When handled and stored appropriately no dangerous reactions are known.
Hazardous decomposition products:
- When handled and stored appropriately no dangerous decomposition products are known.
Disposal considerations
Product:
- Special waste incineration plant, after consultation with operators.
- Observe local authority regulations.
Uncleaned packaging:
- Packaging that cannot be cleaned should be disposed of as product waste.
- For disposal local regulation is binding.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.