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The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.
Diss Factsheets
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EC number: 241-677-4 | CAS number: 17689-77-9
- Life Cycle description
- Uses advised against
- Endpoint summary
- Appearance / physical state / colour
- Melting point / freezing point
- Boiling point
- Density
- Particle size distribution (Granulometry)
- Vapour pressure
- Partition coefficient
- Water solubility
- Solubility in organic solvents / fat solubility
- Surface tension
- Flash point
- Auto flammability
- Flammability
- Explosiveness
- Oxidising properties
- Oxidation reduction potential
- Stability in organic solvents and identity of relevant degradation products
- Storage stability and reactivity towards container material
- Stability: thermal, sunlight, metals
- pH
- Dissociation constant
- Viscosity
- Additional physico-chemical information
- Additional physico-chemical properties of nanomaterials
- Nanomaterial agglomeration / aggregation
- Nanomaterial crystalline phase
- Nanomaterial crystallite and grain size
- Nanomaterial aspect ratio / shape
- Nanomaterial specific surface area
- Nanomaterial Zeta potential
- Nanomaterial surface chemistry
- Nanomaterial dustiness
- Nanomaterial porosity
- Nanomaterial pour density
- Nanomaterial photocatalytic activity
- Nanomaterial radical formation potential
- Nanomaterial catalytic activity
- Endpoint summary
- Stability
- Biodegradation
- Bioaccumulation
- Transport and distribution
- Environmental data
- Additional information on environmental fate and behaviour
- Ecotoxicological Summary
- Aquatic toxicity
- Endpoint summary
- Short-term toxicity to fish
- Long-term toxicity to fish
- Short-term toxicity to aquatic invertebrates
- Long-term toxicity to aquatic invertebrates
- Toxicity to aquatic algae and cyanobacteria
- Toxicity to aquatic plants other than algae
- Toxicity to microorganisms
- Endocrine disrupter testing in aquatic vertebrates – in vivo
- Toxicity to other aquatic organisms
- Sediment toxicity
- Terrestrial toxicity
- Biological effects monitoring
- Biotransformation and kinetics
- Additional ecotoxological information
- Toxicological Summary
- Toxicokinetics, metabolism and distribution
- Acute Toxicity
- Irritation / corrosion
- Sensitisation
- Repeated dose toxicity
- Genetic toxicity
- Carcinogenicity
- Toxicity to reproduction
- Specific investigations
- Exposure related observations in humans
- Toxic effects on livestock and pets
- Additional toxicological data
Guidance on Safe Use
Administrative data
First-aid measures
General information:
Take persons to a safe place. Observe self-protection for first aid. Always seek medical advice in the event of contact with this
substance.
After inhalation
Keep the patient calm. If unconscious place in stable sideways position. Protect against loss of body heat. If breathing stops,
administer artificial respiration. Seek medical advice immediately and clearly identify substance.
After contact with the skin
Remove contaminated clothes at once. Wash off with plenty of water or water and soap immediately for 10-15 minutes. In serious
cases, use emergency shower immediately. Seek medical advice immediately and clearly identify substance.
After contact with the eyes
Rinse immediately with plenty of water for 10-15 minutes. Keep eyelids well open to rinse the whole eye surface and eyelids with
water. Seek medical advice immediately and clearly identify substance. Continue to bathe eyes during transport to medical
practitioner.
After swallowing
If conscious, give several small portions of water to drink. Do not induce vomiting. Seek medical advice immediately and clearly
identify substance.
Advice for the physician
After inhalation: treat as early as possible using cortisone spray. Medical checks necessary up to a latency period of at least 24
hours. In the event of 1st degree burns use corticoid-externa. In the case of 2nd degree burns, use symptomatic treatment.
Fire-fighting measures
Suitable extinguishing media
water mist , extinguishing powder , alcohol-resistant foam , carbon dioxide , sand .
Extinguishing media which must not be used for safety reasons
water spray , water jet .
Special exposure hazards arising from the substance or preparation itself, combustion products, resulting gases
Hazardous combustion products: corrosive substances .
Special protective equipment for fire fighting
Use respiratory protection independent of recirculated air. Use tightly fitting chemical protection suit (see section Exposure controls and personal protection equipment).
Accidental release measures
Personal precautions
Wear personal protection equipment (see section 8). Task force: Use tightly fitting chemical protection suit (see section 8). Keep
unprotected persons away. Avoid contact with eyes and skin. Avoid inhaling mists and vapours. If material is released indicate
risk of slipping.
Environmental precautions
Prevent material from entering surface waters, drains or sewers and soil. Contain any fluid that runs out using suitable material
(e.g. earth).
Methods for cleaning up
Do not flush away with water. For small amounts: Absorb with liquid, mainly acid binding material and dispose of according to
local/state/federal regulation. Contain larger amounts and pump up into suitable containers. Exhaust vapours.
Further information:
Eliminate all sources of ignition.
Handling and storage
Handling
Precautions for safe handling:
Ensure adequate ventilation. Keep away from incompatible substances in accordance with section 10.2. Spilled substance
increases risk of slipping.
Precautions against fire and explosion:
Flammable vapors may accumulate and form explosive mixtures with air in containers, process vessels, including partial, empty
and uncleaned containers and vessels, or other enclosed spaces. Keep away from sources of ignition and do not smoke. Take
precautionary measures against electrostatic charging. Cool endangered containers with water.
Storage
Conditions for storage rooms and vessels:
none known
Advice for storage of incompatible materials:
not applicable
Further information for storage:
Protect against moisture. Keep container tightly closed and store in a cool, well ventilated place. Do not store in open air.
Minimum temperature allowed during storage and transportation: 0 °C
Transport information
Land transport (UN RTDG/ADR/RID)
- UN number:
- 3265
Shipping information
- Proper shipping name and description:
- Ätzender saurer organischer flüssiger Stoff, n.a.g.
- Chemical name:
- Triacetoxyethylsilan
- Language:
- German
- Labels:
- 8; corrosive substances
SpecialProvisionsopen allclose all
Inland waterway transport (UN RTDG/ADN(R))
- UN number:
- 3265
Shipping information
- Proper shipping name and description:
- Ätzender saurer organischer flüssiger Stoff, n.a.g.
- Chemical name:
- Triacetoxyethylsilan
- Language:
- German
- Labels:
- 8; corrosive substances
Remarksopen allclose all
Marine transport (UN RTDG/IMDG)
- UN number:
- 3265
Shipping information
- Proper shipping name and description:
- Corrosive liquid, acidic, organic, n.o.s.
- Chemical name:
- Triacetoxyethylsilane
- Labels:
- 8; corrosives substances
Remarksopen allclose all
Air transport (UN RTDG/ICAO/IATA)
- UN number:
- 3265
Shipping information
- Proper shipping name and description:
- Corrosive liquid, acidic, organic, n.o.s.
- Chemical name:
- Triacetoxyethylsilane
- Labels:
- 8; corrosives substances
Remarksopen allclose all
SpecialProvisionsopen allclose all
Exposure controls / personal protection
Exposure limits
-
Exposure limited and controlled
Exposure in the work place limited and controlled
General protection and hygiene measures:
Avoid contact with eyes and skin. Do not breathe vapours. Do not eat, drink or smoke when handling.
Personal protection equipment
Respiratory protection
In case of long or strong exposure: gas mask filter ABEK .
Hand protection
protective gloves made of fluorinated rubber . Gloves suitable for up to 60 minutes' use.
Eye protection
tight fitting protective goggles . Provide work station with eye bathing equipment. Do not wear contact lenses.
Skin protection
protective clothing .
Exposure to the environment limited and controlled
Prevent material from entering surface waters, drains or sewers and soil.
Further information for system design and engineering measures
Observe information in section Handling and storage.
Stability and reactivity
General information:
If stored and handled in accordance with standard industrial practices no hazardous reactions are known.
Conditions to avoid moisture .
Materials to avoid
Reacts violently with: water , basic substances and alcohols . Reaction causes the formation of: acetic acid .
Hazardous decomposition products
By hydrolysis: acetic acid .
Disposal considerations
Material
Recommendation:
Dispose of according to regulations by incineration in a special waste incinerator. Observe local/state/federal regulations.
Uncleaned packaging
Recommendation:
Completely discharge containers (no tear drops, no powder rest, scraped carefully). Containers may be recycled or re-used.
Observe local/state/federal regulations.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.