Registration Dossier
Registration Dossier
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Diss Factsheets
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EC number: 700-280-0 | CAS number: 1869-24-5
- Life Cycle description
- Uses advised against
- Endpoint summary
- Appearance / physical state / colour
- Melting point / freezing point
- Boiling point
- Density
- Particle size distribution (Granulometry)
- Vapour pressure
- Partition coefficient
- Water solubility
- Solubility in organic solvents / fat solubility
- Surface tension
- Flash point
- Auto flammability
- Flammability
- Explosiveness
- Oxidising properties
- Oxidation reduction potential
- Stability in organic solvents and identity of relevant degradation products
- Storage stability and reactivity towards container material
- Stability: thermal, sunlight, metals
- pH
- Dissociation constant
- Viscosity
- Additional physico-chemical information
- Additional physico-chemical properties of nanomaterials
- Nanomaterial agglomeration / aggregation
- Nanomaterial crystalline phase
- Nanomaterial crystallite and grain size
- Nanomaterial aspect ratio / shape
- Nanomaterial specific surface area
- Nanomaterial Zeta potential
- Nanomaterial surface chemistry
- Nanomaterial dustiness
- Nanomaterial porosity
- Nanomaterial pour density
- Nanomaterial photocatalytic activity
- Nanomaterial radical formation potential
- Nanomaterial catalytic activity
- Endpoint summary
- Stability
- Biodegradation
- Bioaccumulation
- Transport and distribution
- Environmental data
- Additional information on environmental fate and behaviour
- Ecotoxicological Summary
- Aquatic toxicity
- Endpoint summary
- Short-term toxicity to fish
- Long-term toxicity to fish
- Short-term toxicity to aquatic invertebrates
- Long-term toxicity to aquatic invertebrates
- Toxicity to aquatic algae and cyanobacteria
- Toxicity to aquatic plants other than algae
- Toxicity to microorganisms
- Endocrine disrupter testing in aquatic vertebrates – in vivo
- Toxicity to other aquatic organisms
- Sediment toxicity
- Terrestrial toxicity
- Biological effects monitoring
- Biotransformation and kinetics
- Additional ecotoxological information
- Toxicological Summary
- Toxicokinetics, metabolism and distribution
- Acute Toxicity
- Irritation / corrosion
- Sensitisation
- Repeated dose toxicity
- Genetic toxicity
- Carcinogenicity
- Toxicity to reproduction
- Specific investigations
- Exposure related observations in humans
- Toxic effects on livestock and pets
- Additional toxicological data
Guidance on Safe Use
Administrative data
First-aid measures
Inhalation: Move exposed person to fresh air. Keep person warm and at rest. If
not breathing, if breathing is irregular or if respiratory arrest occurs,
provide artificial respiration or oxygen by trained personnel. Get
medical attention if symptoms occur. If unconscious, place in
recovery position and get medical attention immediately. Maintain an
open airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Ingestion: Wash out mouth with water. Move exposed person to fresh air.
Keep person warm and at rest. If material has been swallowed and
the exposed person is conscious, give small quantities of water to
drink. Stop if the exposed person feels sick as vomiting may be
dangerous. Do not induce vomiting unless directed to do so by
medical personnel. If vomiting occurs, the head should be kept low
so that vomit does not enter the lungs. Get medical attention if
symptoms occur. Never give anything by mouth to an unconscious
person. If unconscious, place in recovery position and get medical
attention immediately. Maintain an open airway. Loosen tight
clothing such as a collar, tie, belt or waistband.
Skin contact: Wash skin immediately with plenty of water and soap. Subsequent
cleansing with polyethyleneglycol 400, then again with water and
soap. Remove contaminated clothing and shoes. Get medical
attention if irritation occurs. Wash clothing before reuse. Clean shoes
thoroughly before reuse.
Eye contact: Immediately flush eyes with plenty of water, occasionally lifting the
upper and lower eyelids. Check for and remove any contact lenses.
Continue to rinse for at least 10 minutes. Get medical attention if occurs.
Notes to physician: Basic aid, decontamination, symptomatic treatment.
Fire-fighting measures
Suitable extinguishing media: In case of fire, use water spray (fog), foam, dry chemical or CO2.
Unsuitable extinguishing: None known.
Hazards from the substance or mixture: No specific fire or explosion hazard.
Hazardous combustion products: No specific data.
Advice for firefighters
Special precautions for firefighters: Promptly isolate the scene by removing all persons from the vicinity
of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training.
Special protective equipment for fire-fighters: Fire-fighters should wear appropriate protective equipment and selfcontained
breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Remark : Cool closed containers exposed to fire with water. Do not release runoff from fire to drains or watercourses.
Accidental release measures
Personal precautions, protective equipment and emergency procedures: No action shall be taken involving any personal risk or without
suitable training. Keep unnecessary and unprotected personnel from
entering. Provide adequate ventilation. Put on appropriate personal protective equipment. Hazard of slipping on spilt product.
Environmental precautions: Avoid dispersal of spilt material and runoff and contact with soil,
waterways, drains and sewers. Inform the relevant authorities if the
product has caused environmental pollution (sewers, waterways, soil or air).
Methods and materials for containment and cleaning up
Small spill: Move containers from spill area. Vacuum or sweep up material and
place in a designated, labelled waste container. Dispose of via a
licensed waste disposal contractor.
Large spill : Move containers from spill area. Prevent entry into sewers, water
courses, basements or confined areas. Vacuum or sweep up
material and place in a designated, labelled waste container.
Dispose of via a licensed waste disposal contractor.
Handling and storage
Manufacture and use of this chemical intermediate takes place under strictly controlled conditions, as described in Art. 17/18 REACH. The substance is rigorously contained during manufacturing and use and appropriate risk management measures including PPE (i.g. during charging or sampling) are applied. Occupational exposure is reduced to a minimum and well controlled by measurements. A management system covering all general aspects of a chemical production is in place, especially cleaning and maintenance of plants and equipment. An authorisation scheme based on instructions covering the whole process ensures that only trained and authorised staff handles the substance.
Precautions for safe handling: Put on appropriate personal protective equipment.
Eating, drinking and smoking should be prohibited in areas where this
material is handled, stored and processed. Workers should wash
hands and face before eating, drinking and smoking. Do not ingest.
Avoid contact with eyes, skin and clothing. Keep in the original
container or an approved alternative made from a compatible
material, kept tightly closed when not in use. Empty containers retain product residue and can be hazardous.
The product is registered with strictly controlled
conditions as defined in Article 17(3) or 18(4) of regulation (EC) no.
1907/2006 (REACH Regulation) and must therefore be handled as
such. Refer to the industry guidance prepared by Concawe/Cefic/
EFCG for advice on the confirmation of strictly controlled conditions.
Conditions for safe storage, including any incompatibilities: Store in accordance with local regulations. Store in original container
protected from direct sunlight in a dry, cool and well-ventilated area,
away from incompatible materials and food and
drink. Keep container tightly closed and sealed until ready for use.
Containers that have been opened must be carefully resealed and
kept upright to prevent leakage. Do not store in unlabelled
containers. Use appropriate containment to avoid environmental contamination.
Remarks: Take precautionary measures against electrostatic discharges. Avoid
the formation of dust, if necessary siphoning the product off locally.
Transport information
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Marine transport (UN RTDG/IMDG)
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Exposure controls / personal protection
Control parameters
Exposure limit values : Not available.
Recommended monitoring procedures: If this product contains ingredients with exposure limits, personal,
workplace atmosphere or biological monitoring may be required to
determine the effectiveness of the ventilation or other control
measures and/or the necessity to use respiratory protective
equipment. Reference should be made to European Standard EN
689 for methods for the assessment of exposure by inhalation to
chemical agents and national guidance documents for methods for
the determination of hazardous substances.
Exposure controls
Risk management measures
Occupational exposure controls
Technical measures: The substance shall be rigorously contained by technical means
during its whole lifecycle including manufacture, purification,
cleaning and maintenance of equipment, sampling, analysis,
loading and unloading of equipment or vessels, waste disposal or
purification and storage. Procedural and control technologies shall
be used that minimise emission and any resulting exposure. In
cases of accident and where waste is generated, procedural and/
or control technologies shall be used to minimise emissions and
the resulting exposure during purification or cleaning and
maintenance procedures.
Organisational measures: Only properly trained personnel shall handle the
substance. In the case of cleaning and maintenance works,
special procedures such as purging and washing shall be applied
before the system is opened and entered.
Personal protection measures
Respiratory protection
If exposure cannot be ruled out, e.g. during product transfer,
sampling or maintenance, a well-fitting respiratory mask
conforming to standards or well-fitting respiratory device
conforming to standards must be worn. Respirator selection must
be based on known or anticipated exposure levels, the hazards of
the product and the safe working limits of the selected respirator.
Recommended: In case of dust formation particle filter P2.
Hand protection: Chemical-resistant, impervious gloves complying with an approved
standard should be worn at all times when handling chemical
products if product contact cannot be excluded. After
contamination with product change the gloves immediately and
dispose of them according to relevant national and local
regulations
Recommended: (< 1 hour) Fluorinated rubber, Polyvinyl chloride -
PVC or Rubber gloves.
Eye protection: Safety eyewear complying with an approved standard should be
used to avoid exposure to liquid splashes, mists, gases or dusts.
Recommended: safety glasses with side-shields
Skin protection :
Wear protective clothing. Personal protective equipment for the
body should be selected based on the task being performed and
the risks involved and should be approved by a specialist before
handling this product.
Recommended: Wear protective clothing.
Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical
products, before eating, smoking and using the lavatory and at the
end of the working period. Appropriate techniques should be used to
remove potentially contaminated clothing. Wash contaminated
clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Environmental exposure controls:
Technical measures : Emissions from ventilation or work process equipment should be
checked to ensure they comply with the requirements of
environmental protection legislation. In some cases, fume
scrubbers, filters or engineering modifications to the process
equipment will be necessary to reduce emissions to acceptable levels.
Stability and reactivity
Reactivity: No specific test data related to reactivity available for this product or its ingredients.
Chemical stability The product is stable.
Possibility of hazardous reactions: Under normal conditions of storage and use, hazardous reactions will not occur.
Conditions to avoid: In the case of dusty organic products the possibility of a dust
explosion should always be considered.
Incompatible materials : No specific data.
Hazardous decomposition products: Under normal conditions of storage and use, hazardous
decomposition products should not be produced.
Disposal considerations
Product
Methods of disposal:
Examine possibilities for re-utilisation. Product residues and
uncleaned empty containers should be packaged, sealed, labelled,
and disposed of or recycled according to relevant national and local
regulations. Where large quantities are concerned, consult the
supplier. When uncleaned empty containers are passed on, the
recipient must be warned of any possible hazard that may be caused
by residues. For disposal within the EC, the appropriate code
according to the European Waste List (EWL) should be used. It is
among the tasks of the polluter to assign the waste to waste codes
specific to industrial sectors and processes according to the
European Waste List (EWL).
Hazardous waste :
The classification of the product may meet the criteria for a hazardous waste.
Packaging
Methods of disposal: The generation of waste should be avoided or minimised wherever
possible. Waste packaging should be recycled. Incineration or
landfill should only be considered when recycling is not feasible.
Special precautions: This material and its container must be disposed of in a safe way.
Care should be taken when handling emptied containers that have
not been cleaned or rinsed out. Empty containers or liners may
retain some product residues. Avoid dispersal of spilt material and
runoff and contact with soil, waterways, drains and sewers.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.