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Physical & Chemical properties

Surface tension

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Reference
Endpoint:
surface tension
Type of information:
experimental study
Adequacy of study:
key study
Study period:
18 Nov 2010 to 19 Nov 2010
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Qualifier:
according to guideline
Guideline:
OECD Guideline 115 (Surface Tension of Aqueous Solutions)
Version / remarks:
Jul 1995
Qualifier:
according to guideline
Guideline:
EU Method A.5 (Surface Tension)
Version / remarks:
Dec 1992
GLP compliance:
yes (incl. QA statement)
Type of method:
ring method
Key result
Surface tension:
63.9 mN/m
Temp.:
20.3 °C
Conc.:
90 other: % of saturated concentration

The calibration factor Φb was determined to be 1.0203 for double distilled water.


Table 1 Determination of the Calibration Factor Using Water
















































Time expired
[hours:min]



Temperature
[°C]



Surface tension [mN/m]



Calibration factor
Φb



measured



mean value calculated from the bold values
σg



00:31



19.7



71.5



71.4



1.0203



00:32



19.7



71.4



00:33



19.7



71.4



00:35



19.7



71.3



00:36



19.7



71.3



00:37



19.7



71.2



with


σo = 72.795 mN/m at 19.7 °C


Φb = σo / σg


Φb = 72.795 / 71.35 = 1.0203


where


Φb = calibration factor


σo = the surface tension of water at the test temperature


σg = measured value of the surface tension of water at the test temperature


 


Table 2 Determination of Surface Tension for the Test substance

























































































Time expired
[hours:min]



Temperature
[°C]



Surface tension [mN/m]



measured
[mN/m]



mean value calculated from the bold values
(σ*)



mean value corrected for calibration
(σ1)



σ1 corrected for Harkins-
Jordan
(σ)



First sample



0:33



20.4



62.8



62.73



64.00



63.43



0:35



20.4



62.8



0:36



20.4



62.7



0:37



20.4



62.7



0:38



20.4



62.7



0:39



20.4



62.7



Second sample



0:32



20.2



63.7



63.67



64.96



64.40



0:33



20.2



63.6



0:34



20.2



63.6



0:35



20.2



63.7



0:36



20.2



63.7



0:37



20.2



63.7



Mean value from both samples: σ = 63.9 mN/m
with
σ* · Φb = σ1
Φb = calibration factor = 1.0203
and
σ1 · Fc = σ
Fc = factor for correction acc. to Harkins-Jordan
= 0.991 for 64.00 mN/m and 0.991 for 64.96 mN/m


 

Conclusions:
The average surface tension of two independent measurements was 63.9 mN/m for a 90 % aqueous solution at 20.3 ± 0.1 °C. The substance is considered not surface active.
Executive summary:

The surface tension of the test substance was determined using the ring method in accordance with OECD TG 115 following GLP principles. The average surface tension of two independent measurements was 63.9 mN/m for a 90% aqueous solution at 20.3 ± 0.1 °C. The substance is considered not surface active.

Description of key information

Surface tension: 63.9 mN/m for a 90% aqueous solution at 20.3 ± 0.1 °C, not surface-active substance, OECD TG 115, ring method, Kühne 2010

Key value for chemical safety assessment

Surface tension:
63.9

Additional information