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EC number: 200-654-9 | CAS number: 67-47-0
- Life Cycle description
- Uses advised against
- Endpoint summary
- Appearance / physical state / colour
- Melting point / freezing point
- Boiling point
- Density
- Particle size distribution (Granulometry)
- Vapour pressure
- Partition coefficient
- Water solubility
- Solubility in organic solvents / fat solubility
- Surface tension
- Flash point
- Auto flammability
- Flammability
- Explosiveness
- Oxidising properties
- Oxidation reduction potential
- Stability in organic solvents and identity of relevant degradation products
- Storage stability and reactivity towards container material
- Stability: thermal, sunlight, metals
- pH
- Dissociation constant
- Viscosity
- Additional physico-chemical information
- Additional physico-chemical properties of nanomaterials
- Nanomaterial agglomeration / aggregation
- Nanomaterial crystalline phase
- Nanomaterial crystallite and grain size
- Nanomaterial aspect ratio / shape
- Nanomaterial specific surface area
- Nanomaterial Zeta potential
- Nanomaterial surface chemistry
- Nanomaterial dustiness
- Nanomaterial porosity
- Nanomaterial pour density
- Nanomaterial photocatalytic activity
- Nanomaterial radical formation potential
- Nanomaterial catalytic activity
- Endpoint summary
- Stability
- Biodegradation
- Bioaccumulation
- Transport and distribution
- Environmental data
- Additional information on environmental fate and behaviour
- Ecotoxicological Summary
- Aquatic toxicity
- Endpoint summary
- Short-term toxicity to fish
- Long-term toxicity to fish
- Short-term toxicity to aquatic invertebrates
- Long-term toxicity to aquatic invertebrates
- Toxicity to aquatic algae and cyanobacteria
- Toxicity to aquatic plants other than algae
- Toxicity to microorganisms
- Endocrine disrupter testing in aquatic vertebrates – in vivo
- Toxicity to other aquatic organisms
- Sediment toxicity
- Terrestrial toxicity
- Biological effects monitoring
- Biotransformation and kinetics
- Additional ecotoxological information
- Toxicological Summary
- Toxicokinetics, metabolism and distribution
- Acute Toxicity
- Irritation / corrosion
- Sensitisation
- Repeated dose toxicity
- Genetic toxicity
- Carcinogenicity
- Toxicity to reproduction
- Specific investigations
- Exposure related observations in humans
- Toxic effects on livestock and pets
- Additional toxicological data
Oxidising properties
Administrative data
- Endpoint:
- oxidising solids
- Study period:
- 15 May 2019
- Data waiving:
- study scientifically not necessary / other information available
- Justification for data waiving:
- other:
Data source
Reference
- Reference Type:
- study report
- Title:
- Unnamed
- Year:
- 2 019
Materials and methods
Test guideline
- Qualifier:
- according to guideline
- Guideline:
- UN Manual of Tests and Criteria: Test O.1 (Test for oxidizing solids)
- Version / remarks:
- Recommendations on the TRANSPORT OF DANGEROUS GOODS: Manual of Tests and Criteria, 6th edition, New York and Geneva, 2015
- Deviations:
- no
- GLP compliance:
- yes (incl. QA statement)
Test material
- Reference substance name:
- Reference substance 001
- Cas Number:
- 67-47-0
- Molecular formula:
- C6H6O3
- Reference substance name:
- Fructose
- EC Number:
- 200-333-3
- EC Name:
- Fructose
- Cas Number:
- 57-48-7
- Molecular formula:
- C6H12O6
- IUPAC Name:
- D-fructose
- Reference substance name:
- 1-(furan-2-yl)-2-hydroxyethanone
- Cas Number:
- 17678-19-2
- Molecular formula:
- C6H6O3
- IUPAC Name:
- 1-(furan-2-yl)-2-hydroxyethanone
- Reference substance name:
- Water
- EC Number:
- 231-791-2
- EC Name:
- Water
- Cas Number:
- 7732-18-5
- Molecular formula:
- H2O
- IUPAC Name:
- water
- Reference substance name:
- Sodium formate
- EC Number:
- 205-488-0
- EC Name:
- Sodium formate
- Cas Number:
- 141-53-7
- Molecular formula:
- CH2O2.Na
- IUPAC Name:
- sodium formate
- Reference substance name:
- Sodium nitrate
- EC Number:
- 231-554-3
- EC Name:
- Sodium nitrate
- Cas Number:
- 7631-99-4
- Molecular formula:
- HNO3.Na
- IUPAC Name:
- sodium nitrate
- Reference substance name:
- Glucose
- EC Number:
- 200-075-1
- EC Name:
- Glucose
- Cas Number:
- 50-99-7
- Molecular formula:
- C6H12O6
- IUPAC Name:
- D-glucose
- Reference substance name:
- Sodium acetate
- EC Number:
- 204-823-8
- EC Name:
- Sodium acetate
- Cas Number:
- 127-09-3
- Molecular formula:
- C2H4O2.Na
- IUPAC Name:
- sodium acetate
- Reference substance name:
- 2-furaldehyde
- EC Number:
- 202-627-7
- EC Name:
- 2-furaldehyde
- Cas Number:
- 98-01-1
- Molecular formula:
- C5H4O2
- IUPAC Name:
- 2-furaldehyde
- Reference substance name:
- Sodium 4-oxovalerate
- EC Number:
- 243-378-4
- EC Name:
- Sodium 4-oxovalerate
- Cas Number:
- 19856-23-6
- Molecular formula:
- C5H8O3.Na
- IUPAC Name:
- sodium 4-oxopentanoate
- Reference substance name:
- Formaldehyde
- EC Number:
- 200-001-8
- EC Name:
- Formaldehyde
- Cas Number:
- 50-00-0
- Molecular formula:
- CH2O
- IUPAC Name:
- formaldehyde
- Test material form:
- solid: crystalline
- Details on test material:
- freeze-dried material
Batch: 1808A-RO-C-I1-FD-Chg#3
Appearance Crystal / brown
Storage: Refrigerator (2 - 8 °C)
Expiring date: 31 December 2019
Constituent 1
impurity 1
impurity 2
impurity 3
impurity 4
impurity 5
impurity 6
impurity 7
impurity 8
impurity 9
impurity 10
- Specific details on test material used for the study:
- Storage Conditions: Dry, dark and cooled (2 °C to 8 °C)
Expiry Date: 2019-12-31
Results and discussion
Test results (Oxidising solids)
- Key result
- Remarks on result:
- other: Based on the chemical composition of the product and the chemical structure of the single components present in the test item, it is concluded that the test item has no oxidizing properties.
Any other information on results incl. tables
The main components 5-(Hydroxymethyl)furfural (CAS no. 67-47-0), Fructose (CAS no. 57-48-7), 1-(furan-2-yl)-2-hydroxyethan-1-one (CAS no. 17678-19-2), Glucose (CAS no. 50-99-7) and Sodium formate (CAS no. 141-53-7) contain oxygen chemically only bonded to carbon or hydrogen. For these components oxidizing properties can be excluded.
The test item also contains a small amount Sodium nitrate (CAS no. 7631 -99 -4), which is classified as oxidizing solid in Division 5.1 (Packing Group III) according to UN Recommendations on the TRANSPORT OF DANGEROUS GOODS: Model Regulations Volume I, Rev. 20, New York and Geneva, 2017. Since all other main components do not have oxidizing properties, it can be stated that the small amount of Sodium nitrate will not have an effect on the oxidizing potential of the whole product. The same applies to the other components with a mass fraction below 1 % w/w.
In addition, the test item contains no other components except for water, which is known to have no oxidizing properties.
Based on the fulfillment of the above cited requirements of Appendix 6 for the main components, it can be stated that the test item 5-(Hydroxymethyl)furfural has no oxidizing properties.
Applicant's summary and conclusion
- Interpretation of results:
- GHS criteria not met
- Conclusions:
- Based on the chemical composition of the product and the chemical structure of the single components present in the test item, it is concluded that 5-(Hydroxymethyl)furfural has no oxidizing properties.
Based on the chemical structures, the test item should not be classified by:
UN Transport Regulation: The test item does not have to be classified as oxidizing solid in Division 5.1 according to the UN Transport Regulation.
GHS and EC 1272/2008 (CLP Regulation), Annex 1: 2.14: The test item does not have to be classified as oxidizing solid according to GHS and EC 1272/2008 (CLP Regulation) Annex 1: 2.14. - Executive summary:
Based on the chemical composition of the product and the chemical structure of the single components present in the test item, it is concluded that 5-(Hydroxymethyl)furfural has no oxidizing properties.
Based on the chemical structures, the test item should not be classified by:
UN Transport Regulation: The test item does not have to be classified as oxidizing solid in Division 5.1 according to the UN Transport Regulation.
GHS and EC 1272/2008 (CLP Regulation), Annex 1: 2.14: The test item does not have to be classified as oxidizing solid according to GHS and EC 1272/2008 (CLP Regulation) Annex 1: 2.14.
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