Registration Dossier
Registration Dossier
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EC number: 203-402-6 | CAS number: 106-48-9
Guidance on Safe Use
Guidance on Safe Use
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Administrative data
First-aid measures
Inhalation:
Move exposed person to fresh air. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self contained breathing apparatus. Keep person warm and at rest. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Ingestion :
Wash out mouth with water. Move exposed person to fresh air. Keep person warm and at rest. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Skin contact:
Wash the skin immediately with plenty of soap and water; cleaning immediately with polyethyleneglycol 400 and washing subsequently with plenty of soap and water would be more effective. Get medical attention.
CONTACT WITH THE HOT MELT: Cooling immediately with plenty of water. Do not remove product crusts which may have formed neither forcibly nor by applying any solvents to the skin involved. In order to obtain medical care for possible burns and for a smooth
cleansing of the skin, seek medical advice immediately. Wash out mouth with water. Move exposed person to fresh air. Keep person warm and at rest. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low
so that vomit does not enter the lungs. Get medical attention. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Eye contact:
Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention.
Notes to physician:
Therapeutic measures: Basic aid, decontamination, symptomatic treatment. Treat with a corticoid metered aerosol depending on the amount inhaled.
Move exposed person to fresh air. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self contained breathing apparatus. Keep person warm and at rest. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Ingestion :
Wash out mouth with water. Move exposed person to fresh air. Keep person warm and at rest. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Skin contact:
Wash the skin immediately with plenty of soap and water; cleaning immediately with polyethyleneglycol 400 and washing subsequently with plenty of soap and water would be more effective. Get medical attention.
CONTACT WITH THE HOT MELT: Cooling immediately with plenty of water. Do not remove product crusts which may have formed neither forcibly nor by applying any solvents to the skin involved. In order to obtain medical care for possible burns and for a smooth
cleansing of the skin, seek medical advice immediately. Wash out mouth with water. Move exposed person to fresh air. Keep person warm and at rest. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low
so that vomit does not enter the lungs. Get medical attention. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Eye contact:
Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention.
Notes to physician:
Therapeutic measures: Basic aid, decontamination, symptomatic treatment. Treat with a corticoid metered aerosol depending on the amount inhaled.
Fire-fighting measures
Suitable extinguishing media:
In case of fire, use water spray (fog), foam, dry chemical or CO2.
Unsuitable extinguishingmedia:
None known.
Special hazards arising from the substance or mixture
Hazards from the substance or mixture: No specific fire or explosion hazard.
Hazardous combustion products:
Decomposition products may include the following materials:
- carbon oxides
- halogenated compounds
Advice for firefighters
Special precautions for firefighters:
Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. This material is toxic to aquatic organisms. Fire water contaminated with this material must be contained and prevented from being discharged to any waterway, sewer or drain.
Special protective equipment for fire-fighters:
Fire-fighters should wear appropriate protective equipment and selfcontained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Remark: Do not release runoff from fire to drains or watercourses
In case of fire, use water spray (fog), foam, dry chemical or CO2.
Unsuitable extinguishingmedia:
None known.
Special hazards arising from the substance or mixture
Hazards from the substance or mixture: No specific fire or explosion hazard.
Hazardous combustion products:
Decomposition products may include the following materials:
- carbon oxides
- halogenated compounds
Advice for firefighters
Special precautions for firefighters:
Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. This material is toxic to aquatic organisms. Fire water contaminated with this material must be contained and prevented from being discharged to any waterway, sewer or drain.
Special protective equipment for fire-fighters:
Fire-fighters should wear appropriate protective equipment and selfcontained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Remark: Do not release runoff from fire to drains or watercourses
Accidental release measures
Personal precautions, protective equipment and emergency procedures:
No action shall be taken involving any personal risk or without suitable training. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilt material. Provide adequate ventilation. Put on appropriate personal protective equipment.
Environmental precautions:
Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil
or air). Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Methods and materials for containment and cleaning up
Small spill:
Move containers from spill area. Vacuum or sweep up material and place in a designated, labelled waste container. Dispose of via a licensed waste disposal contractor.
Large spill:
Move containers from spill area. Prevent entry into sewers, water courses, basements or confined areas. Vacuum or sweep up material and place in a designated, labelled waste container. Dispose of via a licensed waste disposal contractor.
No action shall be taken involving any personal risk or without suitable training. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilt material. Provide adequate ventilation. Put on appropriate personal protective equipment.
Environmental precautions:
Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil
or air). Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Methods and materials for containment and cleaning up
Small spill:
Move containers from spill area. Vacuum or sweep up material and place in a designated, labelled waste container. Dispose of via a licensed waste disposal contractor.
Large spill:
Move containers from spill area. Prevent entry into sewers, water courses, basements or confined areas. Vacuum or sweep up material and place in a designated, labelled waste container. Dispose of via a licensed waste disposal contractor.
Handling and storage
Precautions for safe handling:
Put on appropriate personal protective equipment. Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Do not ingest. Avoid contact with eyes, skin and clothing. Avoid release to the environment. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Empty containers retain product residue and can be hazardous.
Conditions for safe storage, including any incompatibilities:
Store in accordance with local regulations. Store in a dry place Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabelled containers. Use appropriate containment to avoid environmental contamination.
Put on appropriate personal protective equipment. Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Do not ingest. Avoid contact with eyes, skin and clothing. Avoid release to the environment. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Empty containers retain product residue and can be hazardous.
Conditions for safe storage, including any incompatibilities:
Store in accordance with local regulations. Store in a dry place Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabelled containers. Use appropriate containment to avoid environmental contamination.
Transport information
Land transport (UN RTDG/ADR/RID)
- UN number:
- UN2020
Shipping information
- Proper shipping name and description:
- CHLOROPHENOLS, SOLID, molten
- Chemical name:
- 4-chlorophenol
- Language:
- English
- Labels:
- - 6.1: cross bones
- dead fish
Special provisions / remarks
- Special provisions:
- Hazard identification number: 60
Inland waterway transport (UN RTDG/ADN(R))
- UN number:
- UN2020
Shipping information
- Proper shipping name and description:
- CHLOROPHENOLS, SOLID, molten
- Chemical name:
- 4-chlorophenol
- Language:
- English
- Labels:
- - 6.1: cross bones
- dead fish
Special provisions / remarks
- Remarks:
- Hazard identification number: 60
Marine transport (UN RTDG/IMDG)
- UN number:
- UN2020
Shipping information
- Proper shipping name and description:
- CHLOROPHENOLS, SOLID, molten
- Chemical name:
- 4-chlorophenol
- Labels:
- - 6.1: cross bones
- dead fish
Remarksopen allclose all
Air transport (UN RTDG/ICAO/IATA)
- UN number:
- -
Shipping information
- Proper shipping name and description:
- -
- Chemical name:
- -
- Labels:
- -
Special provisions / remarks
- Remarks:
- Special precautions for user/Additional information: Shipping forbidden
Additional transport information
Additional information
- Special provisions / remarks / other:
- ADR/RID
Hazard identification number: 60
ADN/ADR
Hazard identification number: 60
Exposure controls / personal protection
1. Technical protection measures
Use only with adequate ventilation. If user operations generate dust, fumes, gas, vapour or mist, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits.
2. Organisational protection measures
Recommended monitoring procedures:
If this product contains ingredients with exposure limits, personal, workplace atmosphere or biological monitoring may be required to determine the effectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective equipment. Reference should be made to European Standard EN 689 for methods for the assessment of exposure by inhalation to chemical agents and national guidance documents for methods for the determination of hazardous substances.
3. Hand protection
Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. After contamination with product change the gloves immediately and dispose of them according to relevant national and local regulations
Recommended: (< 1 hour) Viton® , Polyvinyl chloride - PVC , Nitrile rubber – NBR.
4. Feet protection
- not reported
5. Body protection
Skin protection:
Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.
Recommended: Chemical-resistant protective suit
6. Eye protection
Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts.
Recommended: Tightly fitting safety goggles, face protection shield
7. Respiratory protection
Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator.
Recommended: Full mask with type ABEK-P2 filter . Wear breathing apparatus with separate air supply (compressed air respirator, tube apparatus) at higher concentrations.
8. Hygiene measures
Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.
Environmental exposure controls:
Technical measures
Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.
Use only with adequate ventilation. If user operations generate dust, fumes, gas, vapour or mist, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits.
2. Organisational protection measures
Recommended monitoring procedures:
If this product contains ingredients with exposure limits, personal, workplace atmosphere or biological monitoring may be required to determine the effectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective equipment. Reference should be made to European Standard EN 689 for methods for the assessment of exposure by inhalation to chemical agents and national guidance documents for methods for the determination of hazardous substances.
3. Hand protection
Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. After contamination with product change the gloves immediately and dispose of them according to relevant national and local regulations
Recommended: (< 1 hour) Viton® , Polyvinyl chloride - PVC , Nitrile rubber – NBR.
4. Feet protection
- not reported
5. Body protection
Skin protection:
Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.
Recommended: Chemical-resistant protective suit
6. Eye protection
Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts.
Recommended: Tightly fitting safety goggles, face protection shield
7. Respiratory protection
Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator.
Recommended: Full mask with type ABEK-P2 filter . Wear breathing apparatus with separate air supply (compressed air respirator, tube apparatus) at higher concentrations.
8. Hygiene measures
Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.
Environmental exposure controls:
Technical measures
Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.
Stability and reactivity
Reactivity: No specific test data related to reactivity available for this product or its ingredients.
Chemical stability: The product is stable.
Possibility of hazardous reactions: Under normal conditions of storage and use, hazardous reactions will not occur.
Conditions to avoid: Materials to avoid: Acid chloride, acid anhydride , oxidising agents.
Hazardous decomposition products: Carbon monoxide, carbon dioxide, hydrogen chloride.
Incompatible materials: No specific data.
Hazardous decomposition products: Under normal conditions of storage and use, hazardous decomposition products should not be produced.
Chemical stability: The product is stable.
Possibility of hazardous reactions: Under normal conditions of storage and use, hazardous reactions will not occur.
Conditions to avoid: Materials to avoid: Acid chloride, acid anhydride , oxidising agents.
Hazardous decomposition products: Carbon monoxide, carbon dioxide, hydrogen chloride.
Incompatible materials: No specific data.
Hazardous decomposition products: Under normal conditions of storage and use, hazardous decomposition products should not be produced.
Disposal considerations
Waste treatment methods
Product:
Methods of disposal:
Examine possibilities for re-utilisation. Product residues and uncleaned empty containers should be packaged, sealed, labelled, and disposed of or recycled according to relevant national and local regulations. Where large quantities are concerned, consult the supplier. When uncleaned empty containers are passed on, the recipient must be warned of any possible hazard that may be caused by residues. For disposal within the EC, the appropriate code according to the European Waste List (EWL) should be used. It is among the tasks of the polluter to assign the waste to waste codes specific to industrial sectors and processes according to the European Waste List (EWL).
Hazardous waste:
The classification of the product may meet the criteria for a hazardous waste.
Packaging
Methods of disposal:
The generation of waste should be avoided or minimised wherever possible. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible.
Special precautions:
This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Avoid dispersal of spilt material and run off and contact with soil, waterways, drains and sewers.
Product:
Methods of disposal:
Examine possibilities for re-utilisation. Product residues and uncleaned empty containers should be packaged, sealed, labelled, and disposed of or recycled according to relevant national and local regulations. Where large quantities are concerned, consult the supplier. When uncleaned empty containers are passed on, the recipient must be warned of any possible hazard that may be caused by residues. For disposal within the EC, the appropriate code according to the European Waste List (EWL) should be used. It is among the tasks of the polluter to assign the waste to waste codes specific to industrial sectors and processes according to the European Waste List (EWL).
Hazardous waste:
The classification of the product may meet the criteria for a hazardous waste.
Packaging
Methods of disposal:
The generation of waste should be avoided or minimised wherever possible. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible.
Special precautions:
This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Avoid dispersal of spilt material and run off and contact with soil, waterways, drains and sewers.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
